Electrochemical cells with multiple separators, and methods of producing the same
Embodiments described herein relate to electrochemical cells with multiple separators, and methods of producing the same. A method of producing an electrochemical cell can include disposing an anode material onto an anode current collector, disposing a first separator on the anode material, disposing a cathode material onto a cathode current collector, disposing a second separator onto the cathode material, and disposing the first separator on the second separator to form the electrochemical cell. The anode material and/or the cathode material can be a semi-solid electrode material including an active material, a conductive material, and a volume of liquid electrolyte. In some embodiments, less than about 10% by volume of the liquid electrolyte evaporates during the forming of the electrochemical cell. In some embodiments, the method can further include wetting the first separator and/or the second separator with an electrolyte solution prior to coupling the first separator to the second separator.
1. An electrochemical cell, comprising:
a first electrode disposed on a first current collector;
a second electrode disposed on a second current collector;
a first separator disposed on the first electrode;
a second separator disposed on the second electrode; and
an interlayer disposed between the first separator and the second separator, the interlayer including a first layer including a hard carbon material and a second layer different from the first layer, the second layer including a semi-solid electrode, the interlayer configured to inhibit dendrite growth and enable voltage measurement between the first electrode and the interlayer during operation of the electrochemical cell.
2. The electrochemical cell of claim 1 , further comprising:
a first electrode tab extending from the first current collector; and
an interlayer tab extending from the interlayer, the interlayer tab extending beyond the first separator and the second separator.
3. The electrochemical cell of claim 1 , wherein the hard carbon material includes a hard carbon powder.
4. The electrochemical cell of claim 1 , wherein the interlayer is configured to prevent the projection of dendrites through at least one of the first separator or the second separator during operation of the electrochemical cell.
5. The electrochemical cell of claim 1 , wherein the interlayer is configured to react with any dendritic material that has penetrated at least one of the first separator or the second separator such that the dendritic material dissipates, thus preventing a short circuit.
6. The electrochemical cell of claim 1 , wherein the first separator and the second separator are coated on the interlayer.
7. The electrochemical cell of claim 1 , wherein the first electrode comprises an electroactive species, the electroactive species including is at least one of lithium ions, sodium ions or another non-lithium ion.
8. An electrochemical cell, comprising:
a first electrode disposed on a first current collector;
a second electrode disposed on a second current collector;
a first separator disposed on the first electrode;
a second separator disposed on the second electrode;
an interlayer disposed between the first separator and the second separator, the interlayer configured to inhibit dendrite growth during operation of the electrochemical cell, the interlayer including a first layer comprising a semi-solid electrode material and a second layer different from the first layer, the second layer comprising a solid state electrolyte material;
a first electrode tab extending from the first current collector; and
a current collector material disposed between the first layer and the second layer of the interlayer, the current collector material extending from the interlayer, the current collector material extending beyond the first separator and the second separator.
9. The electrochemical cell of claim 8 , further comprising an interlayer tab extending from the interlayer, the interlayer tab including a carbonaceous material.
10. The electrochemical cell of claim 9 , wherein the carbonaceous material includes at least one of graphite, hard carbon, or carbon black.
11. The electrochemical cell of claim 8 , wherein the interlayer includes a lithium intercalation material.
12. The electrochemical cell of claim 8 , wherein the interlayer includes an electron-conductive powder.
13. An electrochemical cell, comprising:
a first electrode disposed on a first current collector;
a second electrode disposed on a second current collector;
a first separator disposed on the first electrode;
a second separator disposed on the second electrode; and
an interlayer disposed between the first separator and the second separator, the interlayer comprising a first layer including a hard carbon material and a second layer different from the first layer, the second layer comprising a cathode material, the interlayer electrically insulated from the first electrode and the second electrode via the first separator and the second separator.
14. The electrochemical cell of claim 1 , wherein at least one of the first separator or the second separator includes a ceramic.
15. The electrochemical cell of claim 2 , wherein the interlayer tab is formed monolithically with the interlayer.
16. The electrochemical cell of claim 1 , wherein the interlayer has a thickness between about 500 nm and about 100 μm.
17. The electrochemical cell of claim 8 , wherein the interlayer includes a binder.
18. The electrochemical cell of claim 8 , wherein the interlayer has a thickness between about 500 nm and about 100 μm.
19. The electrochemical cell of claim 10 , wherein the interlayer includes hard carbon.
20. The electrochemical cell of claim 13 , further comprising:
a first electrode tab extending from the first current collector; and
an interlayer tab extending from the interlayer, the interlayer tab extending beyond the first separator and the second separator.
21. The electrochemical cell of claim 13 , wherein the interlayer is configured to inhibit the projection of dendrites through at least one of the first separator or the second separator during operation of the electrochemical cell.
22. The electrochemical cell of claim 13 , wherein the interlayer is configured to react with any dendritic material that has penetrated at least one of the first separator or the second separator such that the dendritic material dissipates, thus preventing a short circuit.
23. The electrochemical cell of claim 13 , wherein the interlayer has a thickness between about 500 nm and about 100 μm.
24. The electrochemical cell of claim 13 , wherein at least one of the first separator or the second separator includes a ceramic.