IP Library › Granted Patent US 6,902,971
Granted Patent B2
US 6,902,971 · App. 10/624,203 · Granted Jun 7, 2005

Transistor sidewall spacer stress modulation

Assignee: Freescale Semiconductor, Inc.
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Quick Facts
Patent No.
US 6,902,971
App. No.
10/624,203
Granted
Jun 7, 2005
Kind
B2
Abstract

A semiconductor fabrication process and the resulting integrated circuit include forming a gate electrode ( 116 ) over a gate dielectric ( 104 ) over a semiconductor substrate ( 102 ). A spacer film ( 124 ) exhibiting a tensile stress characteristic is deposited over the gate electrode ( 116 ). The stress characteristics of at least a portion of the spacer film is then modulated ( 132, 192 ) and the spacer film ( 124 ) is etched to form sidewall spacers ( 160, 162 ) on the gate electrode sidewalls. The spacer film ( 124 ) is an LPCVD silicon nitride in one embodiment. Modulating ( 132 ) the spacer film ( 124 ) includes implanting Xenon or Germanium into the spacers ( 160 ) at an implant energy sufficient to break at least some of the silicon nitride bonds. The modulation implant ( 132 ) may be performed selectively or non-selectively either before or after etching the spacer film ( 124 ).

Claims (31)

1. A semiconductor fabrication process, comprising:

forming a gate electrode over a gate dielectric over a semiconductor substrate;

thermally depositing, at a temperature in the range of approximately 550 to 750° C., a silicon nitride spacer film over the gate electrode, the deposited spacer film exhibiting a first tensile stress;

modulating a stress characteristic of at least a portion of the spacer film from the first tensile stress to a second tensile stress; and

etching the spacer film to form sidewall spacers laterally disposed on either side of the gate electrode, wherein at least a portion of the sidewall spacers include sidewall spacers exhibiting the second tensile stress.

2. The process of claim 1 , wherein modulating the stress characteristic comprises implanting a species into at least a portion of the spacer film.

3. A semiconductor fabrication process, comprising:

forming a gate electrode over a gate dielectric over a semiconductor substrate;

depositing a spacer film over the gate electrode, the deposited spacer film exhibiting a first tensile stress;

modulating a stress characteristic of at least a portion of the spacer film from the first tensile stress to a second tensile stress; and

etching the spacer film to form sidewall spacers laterally disposed on either side of the gate electrode, wherein at least a portion of the sidewall spacers include sidewall spacers exhibiting the second tensile stress;

wherein modulating the stress characteristic comprises implanting Xenon into at least a portion of the spacer film.

4. The process of claim 3 , wherein implanting Xenon further includes implanting Xenon into portions of the spacer film over p-channel transistors.

5. The process of claim 4 , wherein implanting Xenon still further includes implanting Xenon at an energy of at least 180 keV.

6. The process of claim 4 , wherein implanting Xenon still further includes implanting at an implant angle of approximately 45°.

7. The process of claim 2 , wherein the ion implanting includes implanting Germanium into the spacer film.

8. The process of claim 7 , wherein implanting Germanium further includes implanting Germanium at an energy of at least 80 keV and an implant angle of approximately 10°.

9. A semiconductor fabrication process, comprising:

depositing a silicon nitride spacer film exhibiting a first tensile stress characteristic over a gate electrode and a semiconductor substrate over which the gate electrode is positioned;

etching the spacer film to form silicon nitride spacers on sidewalls of the gate electrode; and

implanting at least some of the sidewall spacers with an implant species selected from Xenon and Germanium using an implant angle of 10° or greater to modulate a stress characteristic of the implanted spacers.

10. The process of claim 9 , wherein depositing silicon nitride still further includes depositing silicon nitride with a thermal CVD process in which the deposition temperature is in the range of approximately 550 to 750° C.

11. The process of claim 9 , wherein implanting at least some of the sidewall spacers still further includes implanting with an implant energy not less than 80 keV.

12. A semiconductor fabrication process, comprising:

depositing a silicon nitride spacer film exhibiting a first tensile stress characteristic over a gate electrode and a semiconductor substrate over which the gate electrode is positioned;

etching the spacer film to form silicon nitride spacers on sidewalls of the gate electrode; and

selectively implanting at least some of the sidewall spacers of n-channel transistors with an Xenon ions at an implant energy of approximately 180 keV and an implant angle of approximately 45° C. to modulate a stress characteristic of the implanted spacers.

13. A semiconductor fabrication process, comprising:

depositing a silicon nitride spacer film over a gate electrode and a semiconductor substrate over which the gate electrode is positioned;

etching the spacer film to form silicon nitride spacers on sidewalls of the gate electrode; and

blanket implanting at least some of the sidewall spacers with Germanium at an implant energy of 80 keV and an implant angle of approximately 10° to modulate a stress characteristic of the implanted spacers.

Assignments (19)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 037486 FRAME 0517. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Dec 10, 2019
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 053547/0421 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 4, 2016
From: FREESCALE SEMICONDUCTOR, INC.
To: NORTH STAR INNOVATIONS INC.
Reel/Frame 037694/0264 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037354/0225 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0553 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037356/0143 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SECURITY AGREEMENT Recorded Jun 18, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030633/0424 →
SECURITY AGREEMENT Recorded May 13, 2010
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 024397/0001 →
SECURITY AGREEMENT Recorded Feb 2, 2007
From: FREESCALE SEMICONDUCTOR, INC.; FREESCALE ACQUISITION CORPORATION; FREESCALE ACQUISITION HOLDINGS CORP.; FREESCALE HOLDINGS (BERMUDA) III, LTD.
To: CITIBANK, N.A. AS COLLATERAL AGENT
Reel/Frame 018855/0129 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 7, 2004
From: MOTOROLA, INC
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 015360/0718 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 21, 2003
From: GRUDOWSKI, PAUL A.
To: MOTOROLA, INC.
Reel/Frame 014324/0773 →
Continuity (1)
Related Publication 20050020022A1 · Jan 27, 2005