Edge-protected catalyst-coated diffusion media and membrane electrode assemblies
View Patent ↗A fuel cell including an anode-side catalyst coated diffusion medium and a cathode-side catalyst coated diffusion medium that sandwich an ionically conductive membrane. A sealing material is disposed between the ionically conductive membrane and the anode-side and cathode-side catalyst coated diffusion medium, wherein the sealing material is formed of a material that has a permeability that is less than a permeability of the ionically conductive member. The sealing material may also be formed of a material that is softer than the ionically conductive membrane such that the sealing material may deform and enable an membrane electrode assembly of the fuel cell to be subjected to uniform pressures throughout the assembly.
1. An assembly for a fuel cell comprising:
an ionically conductive member;
an electrically conductive member disposed at a surface of said ionically conductive member and including an outer peripheral edge, and said electrically conductive member comprises a frame-shaped recess around a periphery of said electrically conductive member;
an electrochemically active material sandwiched between said ionically conductive member and said electrically conductive member, said electrochemically active material extends across said recess to said outer peripheral edge of said electrically conductive member; and
a frame-shaped sealing member disposed in said recess, said sealing member having an inner peripheral edge smaller than said outer peripheral edge of said electrically conductive member and an outer peripheral edge larger than said outer peripheral edge of said electrically conductive member so as to be overlapping said outer peripheral edge of said electrically conductive member wherein said overlapping sufficient to prevent reactant gas cross-over,
wherein said sealing member has a permeability that is less than a permeability of said ionically conductive member.
2. The assembly of claim 1 , wherein said sealing member prevents or at least inhibits permeation of reactant gas through said ionically conductive member.
3. The assembly of claim 2 , wherein said sealing member prevents or at least inhibits permeation of reactant gas from one side of said ionically conductive member to an opposite side at said peripheral edge.
4. The assembly of claim 1 , wherein said permeability of said sealing member is a hydrogen permeability, an oxygen permeability, or both.
5. The assembly of claim 1 , wherein said electrochemically active material is disposed on said electrically conductive member.
6. The assembly of claim 5 , wherein said sealing member overlaps said electrochemically active material.
7. The assembly of claim 1 , wherein said sealing member is on one side of said ionically conductive member.
8. The assembly of claim 1 , wherein said sealing member is on both sides of said ionically conductive member.
9. The assembly of claim 8 , wherein said sealing member on one side has a differently sized opening from said sealing member on an opposite side of said ionically conductive member.
10. The assembly of claim 1 , wherein said sealing member is formed of at least one selected from a group consisting of polyimide, polyethylene naphthalate, ethylene tetrafluoroethylene, polyvinylidene fluoride, polyesters, polyamides, co-polyamides, polyamide elastomers, polyurethanes, polyurethane elastomers, silicones, and thermoplastic elastomers.
11. The assembly of claim 1 , wherein said sealing member softens at a processing temperature used for the assembly of said sealing member with one or more other members of said assembly.
12. The assembly of claim 11 , wherein said sealing member is imbibed into said electrochemically active material.
13. The assembly of claim 11 , wherein said sealing member flows into voids formed between said electrochemically active material and said ionically conductive member.
14. The assembly of claim 1 , wherein said electrically conductive member comprises a porous material, and said sealing member is imbibed into a plurality of pores in said porous material.
15. The assembly of claim 1 , wherein said sealing member comprises an electrically insulating material.
16. The assembly of claim 1 , wherein said sealing member comprises a material with a hydrogen permeability below 1.times.10.sup.-9 (ml(STP)-cm thick )/(s-cm 2 -cm Hg ) measured at 80.degree. C. and 100% RH.
17. The assembly of claim 1 , wherein said sealing member comprises a material with a hydrogen permeability in a range of 1.times.10 −9 (ml(STP)-cm thick )/(s-cm 2 -cm Hg ) to 2.times.10 −10 (ml(STP)-cm thick )/(s-cm 2 -cm Hg ) measured at 80.degree. C. and 100% RH.
18. The assembly of claim 1 , wherein said sealing member comprises a material with an oxygen permeability below 3500 cc-mil/(100 in 2 -24 hr-atm) measured at 77.degree. F. and 100% RH.
19. The assembly of claim 1 , wherein said sealing member comprises a material with an oxygen permeability in a range of 3.4 cc-mil/(100 in 2 -24 hr-atm) to 200 cc-mil/(100 in 2 -24 hr-atm) measured at 77.degree. F. and 100% RH.
20. The assembly of claim 1 , wherein said sealing member, said ionically conductive member, and said electrically conductive member including said frame-shaped recess define a sealed interfacial region between said ionically conductive member and said electrically conductive member.
21. The assembly of claim 1 , further comprising a microporous layer sandwiched between said electrically conductive member and said electrochemically active material, said microporous layer being a water management layer.
22. The assembly of claim 1 , wherein a thickness of said sealing member is a fraction of a thickness of said electrically conductive member.
23. The assembly of claim 22 , wherein said thickness of said sealing member is below 20% of said thickness of said electrically conductive member.
24. The assembly of claim 22 , wherein said thickness of said sealing member is in a range of about 1-5% of said thickness of said electrically conductive member.