IP Library Granted Patent US 8,217,463
Granted Patent B2
US 8,217,463 · App. 13/021,403 · Granted Jul 10, 2012

Methods for protecting gate stacks during fabrication of semiconductor devices and semiconductor devices fabricated from such methods

Assignee: GLOBALFOUNDRIES Inc.
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Quick Facts
Patent No.
US 8,217,463
App. No.
13/021,403
Granted
Jul 10, 2012
Kind
B2
Abstract

Methods for protecting gate stacks during fabrication of semiconductor devices and semiconductor devices fabricated from such methods are provided. Methods for fabricating a semiconductor device include providing a semiconductor substrate having an active region and a shallow trench isolation (STI) region. Epitaxial layer is formed on the active region to define a lateral overhang portion in a divot at the active region/STI region interface. A gate stack is formed having a first gate stack-forming layer overlying the semiconductor substrate. First gate stack-forming layer includes a non-conformal layer of metal gate-forming material which is directionally deposited to form a thinned break portion just below the lateral overhang portion. After the step of forming the gate stack, a first portion of the non-conformal layer is in the gate stack and a second portion is exposed. The thinned break portion at least partially isolates the first and second portions during subsequent etch chemistries.

Claims (30)

1. A semiconductor device comprising:

a semiconductor substrate having an active region and a shallow trench isolation region having a divot;

an epitaxial layer on the active region of the semiconductor substrate with a lateral overhang portion in the divot at an interface of the active region and the shallow trench isolation region; and

a first gate stack-forming layer overlying the semiconductor substrate and comprising a non-conformal layer of metal gate-forming material having a thinned break portion just below the lateral overhang portion, wherein a first portion of the non-conformal layer of metal gate-forming material is in a gate stack and a second portion is exposed with the thinned break portion at least partially isolating the first and second portions.

2. The semiconductor device of claim 1 , wherein the active region comprises a pFET active region and the epitaxial layer comprises a channel Silicon Germanium (cSiGe) epitaxial layer.

3. The semiconductor device of claim 2 , wherein the cSiGe epitaxial layer comprises about 15 to about 40 atomic percent germanium.

4. The semiconductor device of claim 1 , wherein the active region comprises an nFET active region and the epitaxial layer comprises a silicon epitaxial layer.

5. The semiconductor device of claim 1 , wherein the gate stack further comprises a substantially etch resistant gate insulator material and the first portion of the non-conformal layer of metal gate-forming material overlies the gate insulator material.

6. The semiconductor device of claim 5 , wherein the metal gate-forming material is selected from the group consisting of lanthanum, lanthanum alloys, aluminum, aluminum alloys, magnesium, magnesium alloys, titanium-based materials, and tantalum-based materials.

7. The semiconductor device of claim 1 , wherein the gate stack further comprises a second gate stack-forming layer overlying the first gate stack-forming layer, wherein the second gate stack-forming layer has a composition different from the first gate stack-forming layer.

8. The semiconductor device of claim 7 , wherein the second gate stack-forming layer comprises polycrystalline or amorphous silicon.

9. A semiconductor transistor device comprising:

a semiconductor substrate having an active region and a shallow trench isolation region having a divot;

an epitaxial layer on the active region with a lateral overhang portion at an interface of the active region and the shallow trench isolation region;

a gate stack overlying the semiconductor substrate, the gate stack comprising:

a conformal gate insulator on the epitaxial layer including on the lateral overhang portion, the conformal gate insulator also within the divot;

a non-conformal metal gate-forming material on the conformal gate insulator, the non-conformal metal gate-forming material also within the divot, wherein the non-conformal metal gate-forming material has a thinned break portion under the lateral overhang portion, and wherein the conformal gate insulator and the non-conformal metal gate-forming material form a first gate stack-forming layer; and

a second gate stack-forming layer overlying the first gate stack-forming layer in the gate stack and also within the divot; and

sidewall spacers abutting sidewalls of the gate stack, wherein the sidewall spacers cover a first portion of the first gate stack-forming layer in the divot leaving a second portion exposed.

10. The semiconductor transistor device of claim 9 , wherein the active region comprises a pFET active region and the epitaxial layer comprises a channel Silicon Germanium (cSiGe) epitaxial layer.

11. The semiconductor device of claim 10 , wherein the cSiGe epitaxial layer comprises about 15 to about 40 atomic percent germanium.

12. The semiconductor transistor device of claim 9 , wherein the active region comprises an nFET active region and the epitaxial layer comprises a silicon epitaxial layer.

13. The semiconductor transistor device of claim 9 , wherein the conformal gate insulator comprises silicon dioxide, silicon oxide, silicon nitride, silicon oxynitride, or a high-k dielectric.

14. The semiconductor transistor device of claim 9 , wherein the conformal gate insulator is substantially etch-resistant to wet etch chemistries using sulfur peroxide, ammonium peroxide, or hydrofluoric acid.

15. The semiconductor transistor device of claim 9 , wherein the thinned break portion is between the non-conformal metal gate-forming material within the divot and the non-conformal metal gate-forming material in the gate stack.

16. The semiconductor transistor device of claim 15 , wherein a thickness of the non-conformal metal gate-forming material at the thinned break portion is between about 0 nm to about 1 nm.

17. The semiconductor transistor device of claim 9 , wherein the non-conformal metal gate-forming material is selected from the group consisting of lanthanum, lanthanum alloys, aluminum, aluminum alloys, magnesium, magnesium alloys, titanium-based materials, and tantalum-based materials.

18. The semiconductor transistor device of claim 9 , wherein the second gate stack-forming layer has a composition different from the first gate stack-forming layer.

19. The semiconductor transistor device of claim 18 , wherein the second gate stack-forming layer comprises polycrystalline or amorphous silicon.

20. The semiconductor transistor device of claim 9 , wherein the sidewall spacers have a thickness in the range of about 2 nm to about 9 nm.

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded May 12, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 056987/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 20, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES INC.
Reel/Frame 054636/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2020
From: GLOBALFOUNDRIES INC.
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 054633/0001 →
SECURITY AGREEMENT Recorded Nov 29, 2018
From: GLOBALFOUNDRIES INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 049490/0001 →
Continuity (2)
Division 12604281 · Oct 22, 2009
Related Publication 20110121397A1 · May 26, 2011