IP Library Granted Patent US 9,972,682
Granted Patent B2
US 9,972,682 · App. 15/004,756 · Granted May 15, 2018

Low resistance source drain contact formation

Inventors: Oleg Gluschenkov (Tannersville, NY); Zuoguang Liu (Schenectady, NY); Shogo Mochizuki (Clifton Park, NY); Hiroaki Niimi (Cohoes, NY); Chun-chen Yeh (Clifton Park, NY)
Assignee: International Business Machines Corporation
H01L29/0847H01L21/02057H01L21/02532H01L21/02592H01L21/26513H01L21/28518H01L21/324H01L21/823814H01L29/161H01L29/165H01L29/167H01L29/41725H01L29/45H01L29/665H01L29/66636H01L29/7848
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Quick Facts
Patent No.
US 9,972,682
App. No.
15/004,756
Granted
May 15, 2018
Kind
B2
Abstract

Techniques for forming Ga-doped source drain contacts in Ge-based transistors are provided. In one aspect, a method for forming Ga-doped source and drain contacts includes the steps of: depositing a dielectric over a transistor; depositing a dielectric over the transistor; forming contact trenches in the dielectric over, and extending down to, source and drain regions of the transistor; depositing an epitaxial material into the contact trenches; implanting gallium ions into the epitaxial material to form an amorphous gallium-doped layer; and annealing the amorphous gallium-doped layer under conditions sufficient to form a crystalline gallium-doped layer having a homogenous gallium concentration of greater than about 5×10 20 at./cm 3 . Transistor devices are also provided utilizing the present Ga-doped source and drain contacts.

Claims (26)

1. A method for forming gallium-doped p-type source and drain contacts, the method comprising the steps of:

forming a transistor comprising source and drain regions interconnected by a channel region and at least one gate configured to regulate current flow through the channel region;

depositing a dielectric over the transistor;

forming contact trenches in the dielectric over, and extending down to, the source and drain regions;

depositing an epitaxial material into the contact trenches;

implanting gallium ions into the epitaxial material to form an amorphous gallium-doped layer; and

annealing the amorphous gallium-doped layer under conditions sufficient to form a crystalline gallium-doped layer having a homogenous gallium concentration of greater than about 5×10 20 atoms per cubic centimeter (at./cm 3 ),

wherein the implanting further comprises performing a pocketed ion implant of the gallium ions into the epitaxial material whereby the gallium ions are implanted into only a portion of the epitaxial material such that the annealing produces a layered contact structure comprising three distinct regions including: a first region comprising the crystalline gallium-doped layer, a second region comprising the epitaxial material, and a third region comprising the source and drain regions, wherein the first region, the second region and the third region each comprises a germanium-containing semiconductor with the first region and the second region having a higher percentage of germanium than the third region, and wherein the first region has the homogenous gallium concentration of greater than about 5×10 20 at./cm 3 .

2. The method of claim 1 , further comprising the step of:

performing a surface cleaning within the contact trenches.

3. The method of claim 1 , wherein the source and drain regions comprise boron-doped silicon germanium.

4. The method of claim 1 , wherein the epitaxial material comprises boron-doped silicon germanium.

5. The method of claim 1 , wherein the epitaxial material comprises boron-doped germanium.

6. The method of claim 1 , wherein the epitaxial material comprises gallium-doped germanium.

7. The method of claim 1 , wherein the amorphous gallium-doped layer has a depth in the epitaxial material of from about 5 nanometers to about 10 nanometers, and ranges therebetween.

8. The method of claim 1 , wherein the crystalline gallium-doped layer has a homogenous gallium concentration of from about 6×10 20 at./cm 3 to about 8×10 21 at./cm 3 , and ranges therebetween.

9. The method of claim 1 , wherein the conditions comprise a temperature and a duration.

10. The method of claim 9 , wherein the annealing is performed using solid phase epitaxy laser annealing and wherein the temperature is from about 600° C. to about 800° C., and ranges therebetween, and the duration is from about 50 microseconds to about 5 milliseconds, and ranges therebetween.

11. The method of claim 9 , wherein the annealing is performed using liquid phase epitaxy laser annealing and wherein the temperature is from about 750° C. to about 1,100° C., and ranges therebetween, and the duration is from about 10 nanoseconds to about 1,000 nanoseconds, and ranges therebetween.

12. The method of claim 1 , further comprising the step of:

forming a metal silicide on the crystalline gallium-doped layer.

13. The method of claim 1 , further comprising the step of:

filling the contact trenches with a contact metal.

14. The method of claim 13 , wherein the contact metal comprises a metal selected from the group consisting of tungsten, cobalt, aluminum, and combinations thereof.

15. The method of claim 1 , wherein the first region comprising the crystalline gallium-doped layer is directly in contact with the third region comprising the source and drain regions.

16. The method of claim 1 , wherein the first region comprises gallium (Ga) and boron (B) doped silicon germanium (SiGe) (SiGe y :Ga:B), the second region comprises SiGe y :Ga:B, and the third region comprises Si 1-x Ge x :B, wherein x<y<1, and wherein 0≤x≤0.75.

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded May 12, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 056987/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 20, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES INC.
Reel/Frame 054636/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2020
From: GLOBALFOUNDRIES INC.
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 054633/0001 →
SECURITY AGREEMENT Recorded Nov 29, 2018
From: GLOBALFOUNDRIES INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 049490/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 21, 2017
From: GLUSCHENKOV, OLEG; LIU, ZUOGUANG; MOCHIZUKI, SHOGO; YEH, CHUN-CHEN
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 042772/0636 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 21, 2017
From: NIIMI, HIROAKI
To: GLOBALFOUNDRIES INC.
Reel/Frame 042772/0771 →
Continuity (1)
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