IP Library Granted Patent US 11,561,464
Granted Patent B2
US 11,561,464 · App. 17/532,939 · Granted Jan 24, 2023

EUV masks to prevent carbon contamination

Inventors: Pei-Cheng Hsu (Taipei, TW); Ta-Cheng Lien (Hsinchu County, TW); Hsin-Chang Lee (Hsinchu County, TW)
Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
G03F1/24G03F1/22
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Quick Facts
Patent No.
US 11,561,464
App. No.
17/532,939
Granted
Jan 24, 2023
Kind
B2
Abstract

An extreme ultra-violet mask includes a substrate, a multi-layered mirror layer, a capping layer, a first tantalum-containing oxide layer, a tantalum-containing nitride layer, and a second tantalum-containing oxide layer. The multi-layered mirror layer is over the substrate. The capping layer is over the multi-layered mirror layer. The first tantalum-containing oxide layer is over the capping layer. The tantalum-containing nitride layer is over the first tantalum-containing oxide layer. The second tantalum-containing oxide layer is over the tantalum-containing nitride layer.

Claims (37)

1. An extreme ultra-violet (EUV) mask, comprising:

a substrate;

a multi-layered mirror layer over the substrate;

a capping layer over the multi-layered mirror layer;

a first tantalum-containing oxide layer over the capping layer;

a tantalum-containing nitride layer over the first tantalum-containing oxide layer; and

a second tantalum-containing oxide layer over the tantalum-containing nitride layer.

2. The EUV mask of claim 1 , wherein the tantalum-containing nitride layer and the second tantalum-containing oxide layer have a same chemical element besides tantalum.

3. The EUV mask of claim 1 , wherein the tantalum-containing nitride layer comprises boron.

4. The EUV mask of claim 1 , wherein the second tantalum-containing oxide layer comprises boron.

5. The EUV mask of claim 1 , wherein the capping layer comprises ruthenium.

6. The EUV mask of claim 1 , wherein the second tantalum-containing oxide layer has a same thickness as the first tantalum-containing oxide layer.

7. The EUV mask of claim 1 , wherein the second tantalum-containing oxide layer has a thinner thickness than the tantalum-containing nitride layer.

8. The EUV mask of claim 1 , further comprising a tantalum boron layer, the substrate sandwiched between the tantalum boron layer and the multi-layered mirror layer.

9. An extreme ultra-violet (EUV) mask, comprising:

a substrate;

a multi-layered mirror layer over the substrate; and

a multi-layered absorber layer over the multi-layered mirror layer and comprising:

a first metal oxide layer;

a metal nitride layer over the first metal oxide layer, a first metal element of the first metal oxide layer being different than a second metal element of the metal nitride layer; and

a second metal oxide layer over the metal nitride layer and having the second metal element of the metal nitride layer.

10. The EUV mask of claim 9 , wherein the first metal element comprises ruthenium.

11. The EUV mask of claim 9 , wherein the second metal element comprises tantalum.

12. The EUV mask of claim 9 , wherein the metal nitride layer is free of the second metal element.

13. The EUV mask of claim 9 , wherein the second metal oxide layer is free of the first metal element.

14. The EUV mask of claim 9 , wherein the second metal oxide layer has a thinner thickness than the first metal oxide layer.

15. An extreme ultra-violet (EUV) mask, comprising:

a substrate;

a multi-layered mirror layer over the substrate;

a metal oxide layer over the multi-layered mirror layer;

a metal nitride layer over the metal oxide layer and having a thicker thickness than the metal oxide layer; and

a tantalum boron-oxide layer over the metal nitride layer and having a thinner thickness than the metal nitride layer.

16. The EUV mask of claim 15 , wherein the metal oxide layer is made of a same material as the tantalum boron-oxide layer.

17. The EUV mask of claim 15 , wherein the metal oxide layer is made of a different material than the tantalum boron-oxide layer.

18. The EUV mask of claim 15 , wherein the metal nitride layer is made of tantalum boron-nitride.

19. The EUV mask of claim 15 , further comprising a ruthenium oxide layer sandwiched between the multi-layered mirror layer and the metal oxide layer.

20. The EUV mask of claim 15 , further comprising a chromium nitride layer, the substrate sandwiched between the chromium nitride layer and the multi-layered mirror layer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 29, 2021
From: HSU, PEI-CHENG; LIEN, TA-CHENG; LEE, HSIN-CHANG
To: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
Reel/Frame 058230/0282 →
Continuity (2)
Continuation 16746640 · Jan 17, 2020
Related Publication 20220082928A1 · Mar 17, 2022