Bimodal polyethylene-based composition
A bimodal polyethylene-based composition that is useful for making under film extrusion conditions a film that beneficially has both decreased water vapor transmission rate and decreased haze. The composition comprises an improved design of the composition of the polyethylene blend of a higher molecular weight polyethylene polymer constituent and a lower molecular weight polyethylene polymer constituent and an effective amount of a nucleating agent. Additional embodiments include a method of making the bimodal polyethylene-based composition, a formulation comprising the bimodal polyethylene-based composition and at least one additive, a method of making a manufactured article from the bimodal polyethylene-based composition or formulation; the manufactured article made thereby, use of the bimodal polyethylene-based composition for protecting a moisture-sensitive material, and a sealed package made therefrom. A bimodal polyethylene-based composition that is useful for making under film extrusion conditions a film that beneficially has both decreased water vapor transmission rate and decreased haze. The composition comprises an improved design of the composition of the polyethylene blend of a higher molecular weight polyethylene polymer constituent and a lower molecular weight polyethylene polymer constituent and an effective amount of a nucleating agent. Additional embodiments include a method of making the bimodal polyethylene-based composition, a formulation comprising the bimodal polyethylene-based composition and at least one additive, a method of making a manufactured article from the bimodal polyethylene-based composition or formulation; the manufactured article made thereby, use of the bimodal polyethylene-based composition for protecting a moisture-sensitive material, and a sealed package made therefrom.
1. A bimodal polyethylene-based composition comprising a formulated blend of a higher molecular weight polyethylene polymer constituent (HMW PE constituent), a lower molecular weight polyethylene polymer constituent (LMW PE constituent), and an effective amount of at least 65 parts per million weight (ppmw) of a nucleating agent;
wherein the HMW PE constituent has a high load melt index (I 21 ) from 3 to 12 g/10 min.; and the bimodal polyethylene-based composition has an overall melt index (I 2 ) from 0.5 to 2.5 g/10 min.;
an overall melt flow ratio (I 21 /I 2 ) from 20 to 40; and an overall density from 0.935 to 0.970 gram per cubic centimeter (g/cm3), measured according to ASTM D792-08 (Method B, 2-propanol);
wherein I 2 is measured according to ASTM D1238-10 (190° C., 2.16 kg) and I 21 is measured according to ASTM D1238-10 (190° C., 21.6 kg); and wherein each of the HMW and LMW PE constituents independently is a polyethylene homopolymer or a poly (ethylene-co-1-alkene) copolymer having from greater than 0 to 1.0 weight percent (wt %) of comonomeric content.
2. The bimodal polyethylene-based composition of claim 1 wherein the HMW PE constituent has any one of features (i) to (v): (i) a melt index (I 2 ) from 0.195 to 0.700 g/10 min.; (ii) a density from 0.940 to 0.960 g/cm3; (iii) a weight-average molecular weight (Mw) from 100,000 to 225,000 g/mol, as measured by gel permeation chromatography (GPC); (iv) a melt flow ratio (I 21 /I 2 ) from 15 to 25; and (v) a complex viscosity from 10,000 to 100,000 pascal-seconds (Pa·s), as measured by dynamic mechanical analysis (DMA) at 0.1 radian per second (rad/s) and 190° C. using the Complex Viscosity Test Method.
3. The bimodal polyethylene-based composition of claim 1 wherein the bimodal polyethylene-based composition has any one of features (i) to (iv): (i) an amount of the HMW PE constituent of from 35 to 70 wt % and an amount of the LMW PE constituent of from 65 to 30 wt %, respectively, based on the combined weight of the HMW PE and LMW PE constituents; (ii) an overall density from 0.955 to 0.967 g/cm3; (iii) an overall high load melt index (I 21 ) from 18 to 85 g/10 min., measured according to ASTM D1238-10 (190° C., 21.6 kg); and (iv) an overall melt flow ratio (I 21 /I 2 ) from 20.1 to 39.4.
4. The bimodal polyethylene-based composition of claim 1 wherein at least one, alternatively each, of the HMW PE constituent and the LMW PE constituent is a polyethylene homopolymer.
5. The bimodal polyethylene-based composition of claim 1 , wherein the bimodal polyethylene-based composition has any one of features (i) to (iv): (i) the effective amount of the nucleating agent is from 150 to 1,100 weight parts per million (ppmw); (ii) the nucleating agent comprises a Group 2 or Group 12 metal 1,2-dicarboxylate salt, wherein the 1,2-dicarboxylate salt is a dianion of formula (I): —OOC—CH (R2)-CH (R3)-COO— (I), wherein R2 and R3 are independently H or a (C1 to C4) alkyl or R2 and R3 are bonded to each other to give a (C3 to C4) alkylene; and wherein the Group 2 metal is magnesium or calcium and wherein the Group 12 metal is zinc; (iii) the nucleating agent comprises calcium cyclohexane-1,2-dicarboxylate salt, magnesium cyclohexane-1,2-dicarboxylate salt, or zinc cyclohexane-1,2-dicarboxylate salt; and (iv) the bimodal polyethylene-based composition further comprises at least one of calcium stearate, zinc palmitate, and zinc stearate.
6. The bimodal polyethylene-based composition of claim 1 , wherein the bimodal polyethylene-based composition has any one of features (i) to (iii): (i) a water vapor transmission rate (WVTR) of less than 0.25 (grams*25.4 micrometers)/(0.0645 square meter*day), as measured according to ASTM F1249-06 at 38° C., 100% relative humidity, on a film of the composition, the film having a thickness of about 50 micrometers (μm); (ii) normalized haze of less than 33 percent (%), wherein actual haze is measured according to ASTM D1003-07 on a film of the composition, the film having an actual thickness of about 50 μm; and wherein the normalized haze is calculated by multiplying the actual haze times a film thickness ratio equal to 50.8 μm/(actual film thickness value); and both (i) and (ii).
7. A method of making the bimodal polyethylene-based composition of claim 1 , the method comprising contacting ethylene and, optionally, a 1-alkene, with a polymerization catalyst in a first polymerization reactor under effective polymerization conditions to give the HMW PE constituent or the LMW PE constituent, but not both; conveying the HMW PE constituent or the LMW PE constituent, into a second polymerization reactor, which is different than the first polymerization reactor; in the second polymerization reactor contacting the conveyed HMW PE or LMW PE constituent, with additional ethylene, and, optionally, a second 1-alkene and, optionally, a fresh amount of a same or different effective polymerization catalyst, to give a polyethylene blend comprising the HMW PE constituent and the LMW PE constituent; melting the polyethylene blend and blending the melted polyethylene with a nucleating agent to give a melt blend comprising the nucleating agent dispersed within the melt blend of the HMW and LMW PE constituents; and cooling the melt blend to give the bimodal polyethylene-based composition.
8. A formulation comprising the bimodal polyethylene-based composition of claim 1 and at least one additive that is different than the HMW and LMW PE constituents and the nucleating agent.
9. A manufactured article comprising the bimodal polyethylene-based composition of claim 1 .
10. A method of making a manufactured article, the method comprising extruding a melt of the bimodal polyethylene-based composition of claim 1 , under effective conditions so as to make the manufactured article.
11. An extruded film made by extruding a melt of the bimodal polyethylene-based composition of claim 1 in a film extrusion process to give a solid film.
12. A method of protecting a moisture-sensitive material in need of such protection, the method comprising hermetically sealing the moisture-sensitive material inside a package comprising the extruded film of claim 11 to give a sealed package.
13. A sealed package made by the method of claim 12 .
14. A bimodal polyethylene-based composition comprising a formulated blend of a higher molecular weight polyethylene polymer constituent (HMW PE constituent), a lower molecular weight polyethylene polymer constituent (LMW PE constituent), and at least 65 parts per million weight of a nucleating agent; and the composition having has a water vapor transmission rate (WVTR) of less than 0.23 (grams*25.4 micrometers)/(0.0645 square meter*day), as measured according to ASTM F1249-06 at 38° C., 100% relative humidity, on a film having a thickness of about 50 micrometers (μm) and a normalized haze of less than 27.0 percent (%), wherein actual haze is measured according to ASTM D1003-07 on a film of the composition, the film having an actual thickness of about 50 μm; and wherein the normalized haze is calculated by multiplying the actual haze times a film thickness ratio equal to 50.8 μm (2.00 mils)/(actual film thickness value); and wherein each of the HMW and LMW PE constituents independently is a polyethylene homopolymer or a poly (ethylene-co-1-alkene) copolymer having from greater than 0 to 1.0 weight percent (wt %) of comonomeric content.
15. A film made from the composition of claim 14 .