Pneumatic tire having tread with three elastomers
A pneumatic tire comprising a vulcanizable rubber composition which comprises: 1) 100 parts by weight of elastomer consisting of 25 to 35 phr of a styrene-butadiene rubber, 45 to 75 phr of a polybutadiene, and 5 to 15 phr of a natural rubber or synthetic polyisoprene, wherein the styrene-butadiene rubber is a functionalized and has a Tg(A) ranging from −30 to −10° C.; the natural rubber or synthetic polyisoprene has a Tg(B) ranging from −60 to −70° C.; and the polybutadiene is a cis 1,4 polybutadiene having a Tg(C) ranging from −110 to −90° C., wherein Tg(A)−Tg(B)≥25° C., and Tg(B)−Tg(C)≥25° C.; 2) 70 to 100 phr of silica; 3) 1 to 20 phr of carbon black; 4) 1 to 15 phr of rubber processing oil; and 5) 5 to 50 phr of at least one hydrocarbon resin having a Tg≥20° C. and a rosin derived resin.
1. A pneumatic tire comprising a vulcanizable rubber composition, the vulcanization rubber composition comprising:
a) 100 parts by weight of elastomer consisting of 25 to 35 phr of a styrene-butadiene rubber, 45 to 75 phr of a polybutadiene, and 5 to 15 phr of a natural rubber or synthetic polyisoprene,
wherein the styrene-butadiene rubber is a functionalized solution polymerized styrene-butadiene elastomer having a glass transition temperature Tg(A) ranging from −30 to −10° C. and having at least one functional group; the natural rubber or synthetic polyisoprene has a Tg(B) ranging from −60 to −70° C.; and the polybutadiene is a cis 1,4 polybutadiene having a Tg(C) ranging from −110 to −90° C.,
wherein Tg(A)−Tg(B)≥25° C., and Tg(B)−Tg(C)≥25° C.;
b) 70 to 80 phr of silica;
c) 1 to 20 phr of carbon black;
d) from 1 to less than 10 phr of rubber processing oil; and
e) more than 31 to 50 phr of at least one hydrocarbon resin having a Tg≥20° C.;
f) a rosin derived resin; and
g) excluding tris (2 ethyl hexyl) phosphate.
2. The pneumatic tire of claim 1 , wherein the functional group comprises at least one of an amino group, a thiol ester group, an alkoxy group, a hydroxyl group, or a silyl group.
3. The pneumatic tire of claim 1 , wherein the functional group includes an amino, an alkoxy, and a silyl group.
4. The pneumatic tire of claim 1 wherein the styrene-butadiene rubber comprises functional groups selected from the group consisting of terminal functional groups, in chain functional groups, and a combination of the above.
5. The pneumatic tire of claim 1 , wherein the hydrocarbon resin comprises a copolymer of styrene and alphamethylstyrene.