IP Library Granted Patent US 12,221,390
Granted Patent B2
US 12,221,390 · App. 18/381,365 · Granted Feb 11, 2025

Method for selecting the composition of a construction material comprising an excavated clay soil, method and system for preparing such a construction material

Inventors: Mathieu Neuville (Soustons, FR); Manuel Mercé (Benesse Maremne, FR)
Assignee: MATERRUP
C04B40/0032C04B14/06C04B18/141C04B24/128C04B28/001C04B2103/0081C04B2103/10
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Quick Facts
Patent No.
US 12,221,390
App. No.
18/381,365
Granted
Feb 11, 2025
Kind
B2
Abstract

The invention relates to a method ( 100 ) for selecting the composition of a construction material including an excavated clay soil, said construction material composition to include deflocculating agent and activating agent quantities adapted to the excavated clay soil, said method including a step of receiving ( 130 ) a measured value of at least one physicochemical property of an excavated clay soil, and a step of selecting ( 170 ) a deflocculating agent quantity and an activating agent quantity adapted to the excavated clay soil. In addition, the invention also relates to a method ( 200 ) for calibrating a calculation algorithm for determining the composition of a site construction material, to a construction material formed from an excavated clay soil, and to a system ( 400 ) for preparing a construction material including an excavated clay soil.

Claims (31)

1. A construction material comprising an excavated raw clay soil, a deflocculating agent and an alkaline activating agent, the alkaline activating agent being a composition including a compound having a pKa greater than or equal to 10.

2. The construction material according to claim 1 , wherein the excavated raw clay soil has not undergone a combustion stage.

3. The construction material according to claim 1 , comprising:

30 to 80 wt % of the excavated raw clay soil,

1 to 10 wt % of the deflocculating agent, and

10 to 50 wt % of the alkaline activating agent.

4. The construction material according to claim 1 , said construction material comprising at least 0.1 wt. % of said deflocculating agent.

5. The construction material according to claim 1 , said excavated raw clay soil comprising a mixture of different types of clays.

6. The construction material according to claim 1 , said construction material comprising at least 2 wt. % metal oxides.

7. The construction material according to claim 6 , said construction material having a water to dry matter weight ratio less than 1.

8. The construction material according to claim 1 , said excavated raw clay soil having particles of a size greater than 50 μm.

9. The construction material according to claim 1 , said deflocculating agent is selected among a nonionic surfactant, an anionic surfactant, a polyacrylate or an amine.

10. The construction material according to claim 1 , further comprising blast furnace slag.

11. The construction material according to claim 10 , comprising:

30 to 80 wt % of the excavated raw clay soil,

0.1 to 10 wt % of the deflocculating agent, and

5 to 10 wt % of the blast furnace slag.

12. The construction material according to claim 1 , said construction material being a construction binder.

13. The construction material according to claim 1 , further comprising at least 2 wt % silt particles.

14. The construction material according to claim 1 , the excavated raw clay soil having 80 wt % or less of particles larger than 2 μm.

15. The construction material according to claim 1 , wherein the excavated raw clay soil includes at least 25 wt % of clay.

16. A site concrete comprising an excavated raw clay soil, a deflocculating agent and an alkaline activating agent, the alkaline activating agent being a composition including a compound having a pKa greater than or equal to 10.

17. The site concrete according to claim 16 , said site concrete comprising at least 10 wt % of the excavated raw clay soil.

18. The site concrete according to claim 16 , said site concrete comprising at least 20 wt % of the excavated raw clay soil.

19. The site concrete according to claim 16 , comprising:

5 to 20 wt % of the excavated raw clay soil;

0.1 to 3 wt % of the deflocculating agent;

3 to 15 wt % of an activating agent;

25 to 45 wt % sand; and

35 to 55 wt % aggregates.

20. The site concrete according to claim 16 , said site concrete including at least one of the following: plasticizers, superplasticizers, rheological retention agents or air-entraining agents.

Priority Claims (1)
FR 1902304 · Mar 6, 2019 · national
Continuity (3)
Continuation 17850638 · Jun 27, 2022
Continuation 17436674
Related Publication 20240051882A1 · Feb 15, 2024
References Cited (56)
US 1227903A · Glynn · 1917 [cited by applicant]
US 1331554A · Armstrong · 1920 [cited by applicant]
US 3915719A · Rafine · 1975 [cited by applicant]
US 4742105A · Kelley · 1988 [cited by applicant]
US 6042258A · Hines et al. · 2000 [cited by applicant]
US 6656994B1 · Dreher et al. · 2003 [cited by applicant]
US 10315115B2 · Pawlowski et al. · 2019 [cited by applicant]
US 10355278B2 · Yammine et al. · 2019 [cited by applicant]
US 10544060B2 · Hoffmann · 2020 [cited by applicant]
US 11401215B2 · Neuville et al. · 2022 [cited by applicant]
US 11827573B2 · Neuville · 2023 [cited by examiner]
US 20050164868A1 · Choi et al. · 2005 [cited by applicant]
US 20060185559A1 · Chang · 2006 [cited by applicant]
US 20070266905A1 · Amey et al. · 2007 [cited by applicant]
US 20080271641A1 · Ko et al. · 2008 [cited by applicant]
US 20080271644A1 · Ko et al. · 2008 [cited by applicant]
US 20140238276A1 · Baalbaki et al. · 2014 [cited by applicant]
US 20140336305A1 · Shink et al. · 2014 [cited by applicant]
US 20180111878A1 · Hoffmann · 2018 [cited by applicant]
US 20220119313A1 · Neuville · 2022 [cited by applicant]
CN 1646446 · 2005 [cited by applicant]
CN 101234880A · 2008 [cited by applicant]
CN 106278142A · 2017 [cited by applicant]
CN 107646025 · 2018 [cited by applicant]
CN 107746240 · 2018 [cited by applicant]
CZ 32396U1 · 2018 [cited by applicant]
DE 342403C · 1919 [cited by applicant]
DE 354069C · 1922 [cited by applicant]
DE 19921815A1 · 2000 [cited by applicant]
DE 10037609C1 · 2002 [cited by applicant]
EP 2296854A2 · 2011 [cited by applicant]
EP 2774900A1 · 2014 [cited by applicant]
EP 3247686B1 · 2015 [cited by applicant]
FR 1482794A · 1967 [cited by applicant]
FR 2417482A1 · 1979 [cited by applicant]
FR 2751911A1 · 1998 [cited by applicant]
FR 3016376A1 · 2015 [cited by applicant]
FR 3034094A1 · 2016 [cited by applicant]
JP H08277174A · 1996 [cited by applicant]
JP 2008031769 · 2008 [cited by applicant]
WO 2003089383A1 · 2003 [cited by applicant]
WO 2015155110A1 · 2015 [cited by applicant]
WO 2016102867 · 2016 [cited by applicant]
WO 2016156722A1 · 2016 [cited by applicant]
WO 2017072126A1 · 2017 [cited by applicant]
WO 2022025504A1 · 2022 [cited by applicant]
Maskell, et al. “The Compressive Strength of Lignosulphonate Stabilised Extruded Earth Masonry Units.” Terra 2012: 11th International Conference on the Study and Conservation of Earthen Architecture Heritage, Lima, Peru… [cited by applicant]
Lopez, Rodrigo Fernandez. “Calcined Clayey Soils as a Potential Replacement for Cement in Developing Countries.” Ecole Polytechnique Federale De Lausanne. Thesis No. 4302. Feb. 6, 2009. 178 pages. [cited by applicant]
Oti, et al. “Engineering properties of unfired clay masonry bricks.” Engineering Geology vol. 107, Nos. 3-4. 2009. pp. 130-139. [cited by applicant]
Maskell, et al. “The Compressive Strength of Lignosulphonate Stabilised extruded Earth Masonry Units.” University of Bath. 11th International Conference on the Study and Conservation of Earthen Architecture Heritage., L… [cited by applicant]
Evcin, A. “Investigation of the effects of different deflocculants on the viscosity of slips.” Scientific Research and Essays vol. 6 (11), pp. 2302-2305, Jun. 4, 2011. [cited by applicant]
International Search Report in PCT/FR2019/053319 dated Apr. 15, 2020, 4 pages. [cited by applicant]
International Preliminary Report on Patentability in PCT/FR2019/053319 dated Feb. 23, 2021, 5 pages. [cited by applicant]
Preliminary Search Report issued in French patent application No. FR2211581 dated Mar. 17, 2023, 12 pages. [cited by applicant]
Examination Report issued in Indian Patent Application No. 202117034381 dated Nov. 29, 2022, 5 pages. [cited by applicant]
International Search Report & Written Opinion in PCT/FR2020/050469 dated Aug. 7, 2020, 31 pages (including translation). [cited by applicant]