Granted Patent B2

US 12,230,837 · App. 17/296,501 · Granted Feb 18, 2025

Inventors: Jungyoon Lee (Yongin-si, KR); Gain Kim (Yongin-si, KR); Yangseob Kim (Yongin-si, KR); Yongkyoung Kim (Yongin-si, KR); Yeonjoo Choi (Yongin-si, KR)

Assignee: Samsung SDI Co., Ltd.

H01M50/451C08F220/56C08K3/22H01M10/0525H01M50/42H01M50/423H01M50/434H01M50/443H01M50/446H01M50/489C08F2800/10C08K2003/2227C08K2201/005C08K2201/011H01M50/417

Abstract

Claims (37)

1. A separator for a lithium secondary battery, comprising

a porous substrate, and

a coating layer on at least one surface of the porous substrate,

wherein the coating layer comprises:

a binder including a (meth)acrylic copolymer;

first inorganic particles; and

second inorganic particles,

wherein the (meth)acrylic copolymer is a ternary copolymer consisting of a first structural unit, a second structural unit and a third structural unit:

the first structural unit being derived from (meth)acrylamide including an amide functional group (—NH 2 );

the second structural unit including at least one of a structural unit derived from (meth)acrylic acid or (meth)acrylate; and

the third structural unit being derived from (meth)acrylamidosulfonic acid or a salt thereof,

wherein the first inorganic particles have an average particle diameter of 400 to 600 nm, and

an average particle diameter of the second inorganic particles is smaller than the average particle diameter of the first inorganic particles, and

wherein the average particle diameter of the second inorganic particles is 50 to 200 nm.

2. The separator of claim 1 , wherein the separator has a moisture content of less than or equal to 800 ppm.

3. The separator of claim 1 , wherein the coating layer has a thickness of 1 μm to 5 μm.

4. The separator of claim 1 , wherein the second inorganic particles are included in an amount of less than 75 wt % based on a total amount of the first inorganic particles and the second inorganic particles.

5. The separator of claim 1 , wherein the first inorganic particles and the second inorganic particles are included in a weight ratio of 90:10 to 40:60.

6. The separator of claim 1 , wherein a volume ratio of the first inorganic particles and the second inorganic particles is 12:1 to 1:7.

7. The separator of claim 1 , wherein the first inorganic particles and the second inorganic particles each independently comprise Al 2 O 3 , SiO 2 , TiO 2 , SnO 2 , CeO 2 , MgO, NiO, CaO, GaO, ZnO, ZrO 2 , Y 2 O 3 , SrTiO 3 , BaTiO 3 , Mg(OH) 2 , boehmite, or a combination thereof.

8. The separator of claim 1 , wherein a weight ratio between the binder and a sum of the first inorganic particles and the second inorganic particles is 1:15 to 1:50.

9. The separator of claim 1 , wherein a weight average molecular weight of the (meth)acrylic copolymer is 350,000 to 970,000.

10. The separator of claim 1 , wherein the first structural unit is included in an amount of 55 mol % to 95 mol % based on 100 mol % of the (meth)acrylic copolymer, and the second structural unit is included in an amount of 5 mol % to 40 mol % based on 100 mol % of the (meth)acrylic copolymer.

11. The separator of claim 1 , wherein the second structural unit is included in an amount of more than 0 mol % to 40 mol % based on 100 mol % of the (meth)acrylic copolymer, and the third structural unit is included in an amount of more than 0 mol % to 10 mol % based on 100 mol % of the (meth)acrylic copolymer.

12. The separator of claim 1 , wherein the first structural unit is included in an amount of 90 mol % to 95 mol % based on 100 mol % of the (meth)acrylic copolymer, the second structural unit is included in an amount of more than 0 mol % to 5 mol % based on 100 mol % of the (meth)acrylic copolymer, and the third structural unit is included in an amount of more than 0 mol % to 5 mol % based on 100 mol % of the (meth)acrylic copolymer.

13. The separator of claim 1 , wherein

the first structural unit is represented by Chemical Formula 1,

the second structural unit is represented by one of Chemical Formula 2, Chemical Formula 3, or a combination thereof, and

the third structural unit is represented by one of Chemical Formula 4, Chemical Formula 5, Chemical Formula 6, or a combination thereof:

wherein, in Chemical Formula 1 to Chemical Formula 6,

R 1 to R 6 are each independently hydrogen or a C1 to C6 alkyl group,

R 7 is a substituted or unsubstituted C1 to C20 alkyl group,

L 1 to L 3 are each independently a substituted or unsubstituted C1 to C10 alkylene group, a substituted or unsubstituted C3 to C20 cycloalkylene group, a substituted or unsubstituted C6 to C20 arylene group, or a substituted or unsubstituted C3 to C20 heterocyclic group,

a, b, and c are each independently one of integers of 0 to 2, and

M is an alkali metal.

14. A lithium secondary battery, comprising

a positive electrode, a negative electrode, and the separator of claim 1 between the positive electrode and the negative electrode.

Assignments (1)

Priority Claims (1)

Continuity (1)

References Cited (185)