Granted Patent B2

US 12,237,536 · App. 17/296,516 · Granted Feb 25, 2025

Inventors: Yongkyoung Kim (Yongin-si, KR); Gain Kim (Yongin-si, KR); Jungyoon Lee (Yongin-si, KR); Yeonjoo Choi (Yongin-si, KR); Yangseob Kim (Yongin-si, KR)

Assignee: Samsung SDI Co., Ltd.

H01M50/449C08K3/013C08L25/14C08L33/02C08L33/08C08L33/26H01M50/411H01M50/443H01M50/446

Abstract

Claims (42)

1. A separator for a lithium secondary battery, comprising

a porous substrate, and

a coating layer on at least one surface of the porous substrate,

wherein the coating layer includes a heat-resistant binder including a (meth) acrylic copolymer including a first structural unit derived from (meth) acrylamide, and a second structural unit including a structural unit derived from (meth) acrylic acid or (meth) acrylate, and/or including a structural unit derived from (meth) acrylamidosulfonic acid or a salt thereof;

an adhesive binder having a core-shell structure; and

inorganic particles,

wherein the adhesive binder has an average particle diameter of 0.2 μm to 1.0 μm, and

the inorganic particles have an average particle diameter of 0.2 μm to 1.0 μm,

wherein

the coating layer includes

a heat-resistant layer on the porous substrate, and

an adhesive layer on the heat-resistant layer,

wherein the heat-resistant binder is included in the heat-resistant layer, and

the adhesive binder is included in the adhesive layer and the adhesive layer does not include the heat-resistant binder.

2. The separator of claim 1 , wherein the adhesive binder is a (meth) acrylic polymer including a structural unit derived from (meth) acrylic acid or (meth) acrylate and a structural unit derived from a monomer including a polymerizable unsaturated group.

3. The separator of claim 2 , wherein the monomer containing the polymerizable unsaturated group is at least one selected from a styrene-based monomer, an acid-derived monomer, and a combination thereof.

4. The separator of claim 3 , wherein the acid-derived monomer is at least one selected from itaconic acid, (meth) acrylic acid, and a combination thereof.

5. The separator of claim 1 , wherein the adhesive binder is included in an amount of 1 to 20 wt % based on the total amount of the coating layer.

6. The separator of claim 1 , wherein a weight ratio of the heat-resistant binder including the (meth) acrylic copolymer: the inorganic particles is 1:20 to 1:40.

7. The separator of claim 1 , wherein

the thickness of the heat-resistant layer is 1 μm to 5 μm, and

the thickness of the adhesive layer is 0.4 μm to 1.4 μm.

8. The separator of claim 1 , wherein

the coating layer further comprises an organic filler, and

the organic filler is included in at least one layer of the heat-resistant layer and the adhesive layer.

9. The separator of claim 8 , wherein the organic filler has an average particle diameter of 120 nm to 500 nm.

10. The separator of claim 8 , wherein the inorganic particles: the adhesive binder and the organic filler have a volume ratio of 33:1 to 1:1.

11. The separator of claim 1 , wherein the first structural unit is included in an amount of 55 mol % to 95 mol % based on 100 mol % of the (meth) acrylic copolymer and the second structural unit is included in an amount of 5 mol % to 45 mol % based on 100 mol % of the (meth) acrylic copolymer.

12. The separator of claim 1 , wherein the structural unit derived from (meth) acrylic acid or (meth) acrylate is included in an amount of 0 to 40 mol % based on 100 mol % of the (meth) acrylic copolymer and the structural unit derived from (meth) acrylamidosulfonic acid or a salt thereof is included in an amount of 0 to 10 mol % based on 100 mol % of the (meth) acrylic copolymer.

13. The separator of claim 1 , wherein the structural unit derived from the (meth) acrylamide is included in an amount of 80 mol % to 90 mol % based on 100 mol % of the (meth) acrylic copolymer, the structural unit derived from (meth) acrylic acid or (meth) acrylate is included in an amount of 0 to 10 mol % based on 100 mol % of the (meth) acrylic copolymer, and the structural unit derived from (meth) acrylamidosulfonic acid or a salt thereof is included in an amount of 0 to 10 mol % based on 100 mol % of the (meth) acrylic copolymer.

14. The separator of claim 1 , wherein

the first structural unit derived from (meth) acrylamide is represented by Chemical Formula 1, and

the structural unit derived from (meth) acrylic acid or (meth) acrylate is represented by one of Chemical Formula 2, Chemical Formula 3, and a combination thereof, and

the structural unit derived from (meth) acrylamidosulfonic acid or a salt thereof is represented by one of Chemical Formula 4, Chemical Formula 5, Chemical Formula 6, and a combination thereof:

wherein, in Chemical Formula 1 to Chemical Formula 6,

R 1 to R 6 are each independently hydrogen or a C1 to C6 alkyl group,

R 7 is a substituted or unsubstituted C1 to C20 alkyl group,

L 1 to L 3 are each independently a substituted or unsubstituted C1 to C10 alkylene group, a substituted or unsubstituted C3 to C20 cycloalkylene group, a substituted or unsubstituted C6 to C20 arylene group, or a substituted or unsubstituted C3 to C20 heterocyclic group,

a, b, and c are each independently one of integers of 0 to 2, and

M is an alkali metal.

15. A lithium secondary battery, comprising

a positive electrode, a negative electrode, and the separator for lithium secondary battery of claim 1 between the positive electrode and the negative electrode.

Assignments (1)

Priority Claims (1)

Continuity (1)

References Cited (187)