Perovskite color converter and method of manufacturing the same
Disclosed are a perovskite color converter and a method for manufacturing the same. In order to maintain strong physical properties, the siloxane resin is synthesized in two steps. The silane precursor performs siloxane bond through a non-aqueous sol-gel reaction to form a siloxane resin, and a bond between methacrylate group, and a bond between methacrylate group and an organic ligand are formed through a secondary cross-linking reaction.
1. A perovskite color converter comprising:
a siloxane resin having a siloxane bond by a sol-gel reaction and a cross-linking reaction between silane precursors;
perovskite nanoparticles that perform a light-emitting operation; and
organic ligands surrounding the perovskite nanoparticle,
wherein the organic ligands are chemically cross-linked with the siloxane resin,
wherein the perovskite nanoparticles are dispersed in the cross-linked siloxane resin,
wherein the silane precursors are an organic alkoxysilane or an organic silanediol, and
wherein the organic ligand has an unsaturated carbon bond.
2. The perovskite color converter of claim 1 , wherein the perovskite nanoparticle is inorganic halide perovskite or organic-inorganic hybrid halide perovskite.
3. The perovskite color converter of claim 1 , wherein the perovskite nanoparticle is larger than exciton Bohr's diameter.
4. The perovskite color converter of claim 1 , wherein the perovskite nanoparticle is larger than 7 nm.
5. The perovskite color converter of claim 1 , wherein the silane precursors are (3-methacryloxypropyl) trimethoxysilane (MPTS) and diphenylsilanediol (DPSD).
6. The perovskite color converter of claim 5 , wherein the cross-linked siloxane resin forms a network structure by bonding between the methacrylate groups in MPTS as shown in Reaction Formula 2.
7. The perovskite color converter of claim 1 , wherein the sol-gel reaction is performed through a non-aqueous sol-gel reaction by Reaction Formula 1.
8. The perovskite color converter of claim 1 , wherein the perovskite nanoparticles are encapsulated by cross-linked siloxane resin.
9. The perovskite color converter of claim 1 , wherein the cross-linked siloxane resin has more than 87% of degree of condensation in 29Si-NMR data.
10. The perovskite color converter of claim 1 , wherein the perovskite color converter is in the form of a film.
11. A manufacturing method of a perovskite color converter comprising:
forming a first dispersion in which perovskite nanoparticles and silane precursor are mixed;
forming a second dispersion in which a siloxane resin having a siloxane bond is formed through a non-aqueous sol-gel reaction in the first dispersion; and
inducing a crosslinking reaction between silane precursors in the second dispersion to form a cross-linked siloxane resin; and
inducing chemical bonding between organic ligands of the perovskite nanoparticles and the cross-linked siloxane resin.
12. The manufacturing method of claim 11 , wherein the silane precursors are an organic alkoxysilane or an organic silanediol.
13. The manufacturing method of claim 12 , wherein the silane precursors are (3-methacryloxypropyl) trimethoxysilane (MPTS) and diphenylsilanediol (DPSD).
14. The manufacturing method of claim 13 , wherein the perovskite nanoparticles are uniformly dispersed in the silane precursor by hydrophobic interaction between the methacrylate group of MPTS and the phenyl group of DPSD, and the organic ligand.
15. The manufacturing method of claim 14 , wherein the barium hydroxide is added while the first dispersion is stirred.
16. The manufacturing method of claim 13 , wherein the non-aqueous sol-gel reaction is performed by Reaction Formula 1.
17. The manufacturing method of claim 13 , wherein the cross-linked siloxane resin forms a network structure by bonding between the methacrylate groups of in MPTS as shown in Reaction Formula 2.
18. The manufacturing method of claim 13 , wherein ultraviolet light is irradiated to the second dispersion for the crosslinking reaction, and a photocatalyst is introduced into the second dispersion.
19. The manufacturing method of claim 18 , wherein the photocatalyst is 2,2-dimethoxy-2-phenylacetophenone (BDK).
20. The manufacturing method of claim 11 , wherein barium hydroxide is used as a basic catalyst for the non-aqueous sol-gel reaction.
21. The manufacturing method of claim 11 , wherein the crosslinking reaction and the chemical bonding are induced during a photolithography process to make the perovskite color converter patterned.
22. The manufacturing method of claim 11 , wherein the perovskite color converter is encapsulated by an additional polymer resin through mechanical processing or chemical treatment.