Light-emitting device, light-emitting appliance, display device, electronic appliance, and lighting device
A light-emitting device with high emission efficiency and reliability is provided. The light-emitting device includes first and second fluorescent light-emitting layers. A host material used in the first fluorescent light-emitting layer has a function of converting triplet excitation energy into light emission, a guest material used in the first light-emitting layer has a molecular structure including a luminophore and a protecting group, and one molecule of the guest material includes five or more protecting groups. The introduction of the protecting groups into the molecule inhibits transfer of triplet excitation energy by the Dexter mechanism from the host material to the guest material. An alkyl group or a branched-chain alkyl group is used as the protecting groups. The materials are selected such that the triplet excitation energy level of the host material in the second light-emitting layer is lower than the triplet excitation energy level of the guest material in the second light-emitting layer.
1. A light-emitting device comprising a first light-emitting layer and a second light-emitting layer between a pair of electrodes,
wherein the first light-emitting layer includes a first material and a second material,
wherein the first material has a function of converting triplet excitation energy into light emission,
wherein the second material has a function of converting singlet excitation energy into light emission and includes a luminophore and five or more protecting groups,
wherein the luminophore is a condensed aromatic ring,
wherein the five or more protecting groups each independently have any one of an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, and a trialkylsilyl group having 3 to 12 carbon atoms,
wherein light emission is obtained from the second material,
wherein the second light-emitting layer includes a third material and a fourth material,
wherein the third material has a function of converting singlet excitation energy into light emission, and
wherein a triplet excitation energy level of the fourth material is lower than a triplet excitation energy level of the third material.
2. The light-emitting device according to claim 1 ,
wherein at least four of the five or more protecting groups are each independently any one of an alkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, and a trialkylsilyl group having 3 to 12 carbon atoms.
3. The light-emitting device according to claim 1 , wherein the triplet excitation energy level of the fourth material is lower than a triplet excitation energy level of the second material.
4. The light-emitting device according to claim 1 , wherein a singlet excitation energy level of the second material is lower than a singlet excitation energy level of the third material.
5. The light-emitting device according to claim 1 , wherein the alkyl group is a branched-chain alkyl group.
6. The light-emitting device according to claim 5 , wherein the branched-chain alkyl group has quaternary carbon.
7. An electronic appliance comprising:
the light-emitting device according to claim 1 ; and
at least one of a housing and a display portion.
8. A light-emitting device comprising a first light-emitting layer and a second light-emitting layer between a pair of electrodes,
wherein the first light-emitting layer includes a first material and a second material,
wherein the first material has a function of converting triplet excitation energy into light emission,
wherein the second material has a function of converting singlet excitation energy into light emission and includes a luminophore and at least four protecting groups,
wherein the luminophore is a condensed aromatic ring,
wherein the four protecting groups are not directly bonded to the condensed aromatic ring or the condensed heteroaromatic ring,
wherein the four protecting groups each independently have any one of an alkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, and a trialkylsilyl group having 3 to 12 carbon atoms,
wherein light emission is obtained from the second material,
wherein the second light-emitting layer includes a third material and a fourth material,
wherein the third material has a function of converting singlet excitation energy into light emission, and
wherein a triplet excitation energy level of the fourth material is lower than a triplet excitation energy level of the third material.
9. The light-emitting device according to claim 8 , wherein the triplet excitation energy level of the fourth material is lower than a triplet excitation energy level of the second material.
10. The light-emitting device according to claim 8 , wherein a singlet excitation energy level of the second material is lower than a singlet excitation energy level of the third material.
11. The light-emitting device according to claim 8 , wherein the alkyl group is a branched-chain alkyl group.
12. The light-emitting device according to claim 11 , wherein the branched-chain alkyl group has quaternary carbon.
13. An electronic appliance comprising:
the light-emitting device according to claim 8 ; and
at least one of a housing and a display portion.