Electrode assembly manufacturing method, electrode assembly, and electrochemical device including the same
Disclosed is an electrode assembly manufacturing method, in which, in a step of stacking and pressing electrodes and a separator, the pressing is performed in that state in which pores of a porous substrate are filled with a polymer solution. The form or volume of the pores is not changed due to the polymer solution. Consequently, porosity of the separator after manufacture of an electrode assembly is similar to porosity of the separator before stacking. As a result, a battery including the electrode assembly has high ionic conductivity and excellent performance.
1. An electrode assembly manufacturing method comprising:
1) dissolving a polymer soluble in an electrolytic solution in a solvent to form a polymer solution;
2) filling pores of a porous substrate with the polymer solution of step 1) to form a separator;
3. manufacturing a stack comprising the separator of step 2) and at least one electrode by pressing;
4) injecting a primary electrolytic solution into the stack of step 3) to discharge the polymer solution in the pores of the separator to an outside of the stack; and
5) injecting a secondary electrolytic solution into the stack of step 4).
2. The electrode assembly manufacturing method according to claim 1 , wherein the solvent of step 1) is not an electrolytic solution.
3. The electrode assembly manufacturing method according to claim 1 , wherein filling the pores of the porous substrate with the polymer solution of step 2) comprises applying the polymer solution to the porous substrate or impregnating the porous substrate with the polymer solution.
4. The electrode assembly manufacturing method according to claim 1 , further comprising drying the separator after step 2).
5. The electrode assembly manufacturing method according to claim 1 , further comprising further coating at least one surface of the separator after step 2).
6. The electrode assembly manufacturing method according to claim 1 , wherein the stack comprises a heat resistance layer in step 3).
7. The electrode assembly manufacturing method according to claim 1 , wherein the pressing of step 3) is performed at a pressure of 3 MPa to 20 MPa and a temperature of from 50° C. to 100° C.
8. The electrode assembly manufacturing method according to claim 1 , wherein the primary electrolytic solution and the secondary electrolytic solution are mixable with each other.
9. The electrode assembly manufacturing method according to claim 1 , wherein the primary electrolytic solution and the secondary electrolytic solution are identical to each other.
10. The electrode assembly manufacturing method according to claim 1 , wherein
the polymer soluble in the electrolytic solution in step 1) is a PVdF-based polymer, and
the solvent is an organic solvent.
11. The electrode assembly manufacturing method according to claim 1 , further comprising performing initial charging and discharging after step 5).