Granted Patent B2

US 12,340,829 · App. 18/538,014 · Granted Jun 24, 2025

Inventors: Bala Krishna Pathem (Fremont, CA); Nicholas Ryan Conley (Apex, NC); Bruno Jean Marchon (Palo Alto, CA)

Assignee: Western Digital Technologies, Inc.

G11B5/7257C08G65/007C10M107/38G11B5/4826C10M2213/043C10N2020/04C10N2040/18C10N2050/08G11B2005/0021G11B5/4866

Abstract

Claims (85)

1. A lubricant comprising:

a plurality of segments, each linked together by ether linkages according to a general formula:

Re 1 —Rb 1 -Ri-Rc-Ri-Rb 2 —Re 2 ;

wherein Rc is a divalent center segment including a perfluoroalkyl ether moiety;

wherein each of Rb 1 and Rb 2 is, independently, a sidechain segment including a perfluoroalkyl ether moiety;

wherein each Ri is, independently, a divalent linking segment including a functional group including elements from Group 13-17 of the periodic table of the elements;

wherein each of Re 1 and Re 2 is, independently, a monovalent end segment including a functional group including elements from Group 13-17 of the periodic table of the elements; and

wherein Rb 1 ≠Rc≠Rb 2 .

2. The lubricant of claim 1 , wherein the lubricant has a bonding percentage of about 70% to about 100% corresponding to a total area of a surface on which the lubricant is located, and an average thickness of a layer of the lubricant on the surface is about 0.3 nanometers to about 3 nanometers.

3. The lubricant of claim 1 , wherein the lubricant has a bonding percentage of about 80% to about 100% corresponding to a total area of a surface on which the lubricant is located, and an average thickness of a layer of the lubricant on the surface is about 0.3 nanometers to about 3 nanometers.

4. The lubricant of claim 1 , wherein the lubricant has a segment weight average molecular weight (α) determined according to the formula:

α=[molecular weight of Rb 1 +molecular weight of Rb 2 +molecular weight of Rc]÷3;

and

wherein a dewetting thickness of the lubricant, T dw , is determined according to the formula:

T dw =ψ(α);

wherein ψ is a function determined from a relationship between a dewetting thickness and a segment weight average molecular weight of a plurality of other lubricants;

wherein each of the plurality of other lubricants includes one or more segments including perfluoroalkyl ether moieties;

wherein the segment weight average molecular weight (α) of each of the plurality of other lubricants is equal to a weight average molecular weight of the one or more segments including perfluoroalkyl ether moieties present in the respective other lubricant; and

wherein the segment weight average molecular weight of each of the plurality of other lubricants is about 300 grams/mole (g/mol) to about 5,000 g/mol.

5. The lubricant of claim 1 ,

wherein each functional group is —OH; or

wherein each functional group includes: a saturated C 1 -C 20 radical, an unsaturated C 1 -C 20 radical, an alicyclic C 3 -C 20 radical, a heterocyclic C 3 -C 20 radical, an aromatic C 5 -C 20 radical, a heteroaromatic C 5 -C 20 radical, a cyclotriphosphazine radical, a halogen, —NR* 2 , —NR*—CO—R*, —OR*, —O—CO—R*, —CO—O—R*, —SeR*, —TeR*, —PR* 2 , —PO—(OR*) 2 , —O—PO—(OR*) 2 , —N═P(NR* 2 ) 3 , —AsR* 2 , —SR*, —SO 2 —(OR*) 2 , —BR* 2 , —SiR* 3 , —(CH 2 )q-SiR* 3 , —(CF 2 )q-SiR* 3 , or a combination thereof, wherein q is 1 to 10 and each R* is, independently, a hydrogen, a halogen, a saturated, unsaturated, aromatic, and/or heterocyclic C 1 -C 20 radical, and wherein two or more R* may join together to form a ring structure, and wherein at least one functional group is selected to be attachable to a protective overcoat of a magnetic recording media comprising the lubricant.

6. The lubricant of claim 1 , wherein a weight average molecular weight is from about 1 to about 20 kiloDaltons (kDa) and a polydispersity is about 1 to about 2.

7. The lubricant of claim 1 , wherein:

Rc includes a perfluoroethyl ether moiety;

each of Rb 1 and Rb 2 includes a perfluoroethyl ether moiety;

each Ri has the general formula:

Re 1 has the general formula:

and

Re 2 has the general formula:

wherein each R 1 is, independently, a functional group including elements from Group 13-17 of the periodic table of the elements, and

Rc is of the formula:

Rb 1 is of the formula:

and

Rb 2 is of the formula:

and

wherein each of x, y 1 and y 2 is, independently, an integer from 1 to 10.

8. The lubricant of claim 7 , wherein x is less than y 1 and x is less than y 2 ; or

wherein x is greater than y 1 and x is greater than y 2 .

9. The lubricant of claim 7 , wherein y 1 ≠y 2 .

10. A lubricant comprising:

a plurality of segments, each linked together by ether linkages according to a general formula:

Re 1 —Rb 1 -Ri-Rc-Ri-Rb 2 —Re 2 ;

wherein Rc is a divalent center segment including a perfluoroalkyl ether moiety;

wherein each of Rb 1 and Rb 2 is, independently, a sidechain segment including a perfluoroalkyl ether moiety;

wherein each Ri is, independently, a divalent linking segment including an —OH functional group;

wherein each of Re 1 and Re 2 is, independently, a monovalent end segment including an —OH functional group; and

wherein Rb 1 ≠Rc≠Rb 2 .

11. The lubricant of claim 10 , wherein the lubricant has a bonding percentage of about 70% to about 100% corresponding to a total area of a surface on which the lubricant is located, and an average thickness of a layer of the lubricant on the surface is about 0.3 nanometers to about 3 nanometers.

12. The lubricant of claim 10 , wherein the lubricant has a bonding percentage of about 80% to about 100% corresponding to a total area of a surface on which the lubricant is located, and an average thickness of a layer of the lubricant on the surface is about 0.3 nanometers to about 3 nanometers.

13. The lubricant of claim 10 , wherein the lubricant has a segment weight average molecular weight (α) determined according to the formula:

α=[molecular weight of Rb 1 +molecular weight of Rb 2 +molecular weight of Rc]÷3; and

wherein a dewetting thickness of the lubricant, T dw , is determined according to the formula:

T dw =ψ(α);

wherein ψ is a function determined from a relationship between a dewetting thickness and a segment weight average molecular weight of a plurality of other lubricants;

wherein each of the plurality of other lubricants includes one or more segments including perfluoroalkyl ether moieties;

wherein the segment weight average molecular weight (α) of each of the plurality of other lubricants is equal to a weight average molecular weight of the one or more segments including perfluoroalkyl ether moieties present in the respective other lubricant; and

wherein the segment weight average molecular weight (α) of each of the plurality of other lubricants is about 300 grams/mole (g/mol) to about 5,000 g/mol.

14. The lubricant of claim 10 , wherein a weight average molecular weight is from about 1 to about 20 kiloDaltons (kDa) and a polydispersity is about 1 to about 2.

15. A lubricant comprising:

a plurality of segments, each linked together by ether linkages according to a general formula:

Re 1 —Rb 1 -Ri-Rc-Ri-Rb 2 —Re 2 ;

wherein Rc is a divalent center segment including fluorine and oxygen;

wherein each of Rb 1 and Rb 2 is, independently, a sidechain segment including fluorine and oxygen;

wherein each Ri is, independently, a divalent linking segment including a functional group including elements from Group 13-17 of the periodic table of the elements;

wherein each of Re 1 and Re 2 is, independently, a monovalent end segment including a functional group including elements from Group 13-17 of the periodic table of the elements; and

wherein Rb 1 ≠Rc≠Rb 2 .

16. The lubricant of claim 15 , wherein the lubricant has a bonding percentage of about 70% to about 100% corresponding to a total area of a surface on which the lubricant is located, and an average thickness of a layer of the lubricant on the surface is about 0.3 nanometers to about 3 nanometers.

17. The lubricant of claim 15 , wherein the lubricant has a bonding percentage of about 80% to about 100% corresponding to a total area of a surface on which the lubricant is located, and an average thickness of a layer of the lubricant on the surface is about 0.3 nanometers to about 3 nanometers.

18. The lubricant of claim 15 , wherein the lubricant has a segment weight average molecular weight (α) determined according to the formula:

α=[molecular weight of Rb 1 +molecular weight of Rb 2 +molecular weight of Rc]÷3;

and

wherein a dewetting thickness of the lubricant, T dw , is determined according to the formula:

T dw =ψ(α);

wherein ψ is a function determined from a relationship between a dewetting thickness and a segment weight average molecular weight of a plurality of other lubricants;

wherein each of the plurality of other lubricants includes one or more segments including perfluoroalkyl ether moieties;

wherein the segment weight average molecular weight (α) of each of the plurality of other lubricants is equal to a weight average molecular weight of the one or more segments including perfluoroalkyl ether moieties present in the respective other lubricant; and

wherein the segment weight average molecular weight of each of the plurality of other lubricants is about 300 grams/mole (g/mol) to about 5,000 g/mol.

19. The lubricant of claim 15 , wherein a weight average molecular weight is from about 1 to about 20 kiloDaltons (kDa) and a polydispersity is about 1 to about 2.

20. The lubricant of claim 15 ,

wherein each functional group is —OH; or

wherein each functional group includes: a saturated C 1 -C 20 radical, an unsaturated C 1 -C 20 radical, an alicyclic C 3 -C 20 radical, a heterocyclic C 3 -C 20 radical, an aromatic C 5 -C 20 radical, a heteroaromatic C 5 -C 20 radical, a cyclotriphosphazine radical, a halogen, —NR* 2 , —NR*—CO—R*, —OR*, —O—CO—R*, —CO—O—R*, —SeR*, —TeR*, —PR* 2 , —PO—(OR*) 2 , —O—PO—(OR*) 2 , —N═P(NR* 2 ) 3 , —AsR* 2 , —SR*, —SO 2 —(OR*) 2 , —BR* 2 , —SiR* 3 , —(CH 2 )q-SiR* 3 , —(CF 2 )q-SiR* 3 , or a combination thereof, wherein q is 1 to 10 and each R* is, independently, a hydrogen, a halogen, a saturated, unsaturated, aromatic, and/or heterocyclic C 1 -C 20 radical, and wherein two or more R* may join together to form a ring structure, and wherein at least one functional group is selected to be attachable to a protective overcoat of a magnetic recording media comprising the lubricant.

21. A lubricant comprising a plurality of segments linked together by ether linkages according to a formula:

wherein each of x, y 1 , and y 2 is an integer from 1 to 10; and

wherein y 1 ≠x≠y 2 .

Assignments (3)

Continuity (4)

References Cited (72)