Polyorganosiloxane, polyorganosiloxane composition, cured product, polyorganosiloxane-containing electrolytic solution for electrolytic capacitor, and electrolytic capacitor using same
A polyorganosiloxane may be high in elasticity and/or strength. The polyorganosiloxane may include an M unit (R 1 R 2 R 3 SiO 1/2 ) at a content of 10 mol. % or more relative to the total of silicon and a T unit (R 6 SiO 3/2 ) at a content of 80 mol. % or less relative to the total of silicon. The polyorganosiloxane may have an alkoxy group bound, at a content of 0.07 to 4 wt. %, based on total polyorganosiloxane weight, and a reactive functional group bound to silicon, with 3 to 12 of the reactive functional groups bound on a number basis per a molecular weight of 1000 of the polyorganosiloxane. The weight loss of the polyorganosiloxane at 110° C. under 0.15 torr for 2 hours may be 5 wt. % or less.
1 . A polyorganosiloxane, having a formula (101):
(R 101 R 102 R 103 SiO 1/2 ) M1 (R 104 R 105 R 106 SiO 1/2 ) M2 (R 107 R 108 SiO 2/2 ) D1 (R 109 R 106 SiO 2/2 ) D2 (R 110 SiO 3/2 ) T1 (R 106 SiO 3/2 ) T2 (SiO 4/2 ) Q (O 1/2 R 110 ) Y1 (O 1/2 R 106 ) Y2 (101),
wherein
R 101 to R 105 and R 107 to R 110 are each independently H, an organic functional group, or a first reactive functional group,
R 106 is independently an organic group comprising a second reactive functional group, provided that the second reactive functional group differs from the first reactive functional group,
R 110 is H or an organic group having 1 to 20 carbon atoms not comprising the first or second reactive functional group,
M1, D1, and T1 are each in a range of from 0 to less than 0.6,
Q is in a range of from more than 0 to less than 0.6,
M1+M2>0,
T1+T2+Q>0,
M2+D2+T2>0.25,
M1+M2+D1+D2+T1+T2+Q=1, and
Y1 and Y2 are each 0 or a positive value,
wherein M1, M2, D1, D2, T1, T2, and Q are relative to total silicon atoms,
wherein the first or second a reactive functional group bound to silicon comprises an alkenyl group, a methacryloyl group, an acryloyl group, an acyl group, a cyclic ether group, and/or a hydrogen atom taken together with silicon to form a hydrosilyl group, and is not an alkoxy group,
wherein the organic functional group of R 101 to R 105 and R 107 to R 110 comprises C and H, and optionally further oxygen, nitrogen, phosphorus, sulfur, and/or halogen, the organic functional group not being reactive in silicone formation and not being the first or second reactive functional group,
wherein the polyorganosiloxane has in a range of from 3 to 12 of the first and second reactive functional groups, bound to silicon, on a number basis per a molecular weight of 1000 of the polyorganosiloxane,
wherein the polyorganosiloxane has a maximum absorption wavenumber of a Si—O stretching vibration is in a wavenumber range of from 1030 to 1060 cm −1 in infrared absorption spectrum analysis, and
wherein the polyorganosiloxane has a weight loss of a polyorganosiloxane component in heating at 110° C. under a pressure of 0.15 torr for 2 hours of 5 wt. % or less.
2 . The polyorganosiloxane of claim 1 ,
wherein a total of M units, having formulas
R 101 R 102 R 103 SiO 1/2 and R 104 R 105 R 106 SiO 1/2 ,
is in a range of from 10 to 60 mol. %, relative to total silicon.
3 . The polyorganosiloxane of claim 1 , wherein the first or second reactive functional group is a vinyl group, and
wherein the polyorganosiloxane has in a range of from 4 to 9 of the first and second reactive functional groups bound to silicon, on a number basis per a molecular weight of 1000 of the polyorganosiloxane.
4 . The polyorganosiloxane of claim 1 , which is a liquid at 40° C., and
wherein polyorganosiloxane comprises, relative to total silicon, an M unit in 10 mol. % or more and a T unit in 80 mol. % or less,
wherein the polyorganosiloxane has the alkoxy group bound to silicon at a content of 0.07 to 4 wt. %, based on total polyorganosiloxane weight.
5 . The polyorganosiloxane of claim 1 , having a viscosity at 25° C., in a range of from 5 to 20000 mPa·s.
6 . The polyorganosiloxane of claim 1 , having a number average molecular weight Mn in a range of from 600 to 5000, as a GPC measurement result in terms of polystyrene.
7 . The polyorganosiloxane of claim 1 ,
wherein R 101 to R 103 are each independently H or the organic functional group.
8 . The polyorganosiloxane of claim 1 , wherein
(R 101 R 102 R 103 SiO 1/2 ) M1 and/or (R 104 R 105 R 106 SiO 1/2 ) M2 ,
comprises a trimethylsiloxy group.
9 . The polyorganosiloxane of claim 1 , wherein (R 101 R 102 R 103 SiO 1/2 ) M1 and/or (R 104 R 105 R 106 SiO 1/2 ) M2 ,
comprises a dimethylsiloxy group.
10 . The polyorganosiloxane of claim 1 , wherein the polyorganosiloxane is an MQ resin.
11 . The polyorganosiloxane of claim 1 , wherein the polyorganosiloxane is an MTQ resin.
12 . A composition, comprising:
the polyorganosiloxane of claim 1 .
13 . The polyorganosiloxane of claim 1 , wherein the first or second reactive functional group bound to silicon is an alkenyl group.
14 . The polyorganosiloxane of claim 1 , wherein the first or second reactive functional group bound to silicon is a methacryloyl group.
15 . The polyorganosiloxane of claim 1 , wherein the first or second reactive functional group bound to silicon is an acryloyl group.
16 . The polyorganosiloxane of claim 1 , wherein the first or second reactive functional group bound to silicon is an acyl group.
17 . The polyorganosiloxane of claim 1 , wherein the first or second reactive functional group bound to silicon is a cyclic ether group.
18 . The polyorganosiloxane of claim 1 , wherein the first or second reactive functional group bound to silicon is a hydrogen atom taken together with silicon to form a hydrosilyl group.
19 . The polyorganosiloxane of claim 1 , wherein M2+T2>0.25.
20 . The polyorganosiloxane of claim 1 , wherein R 110 is a methyl group.