IP Library Granted Patent US 12,476,021
Granted Patent B2
US 12,476,021 · App. 18/780,075 · Granted Nov 18, 2025

Conductive composite material

Inventors: Hiroyuki Morita (Nagaokakyo, JP); Kosuke Sugiura (Nagaokakyo, JP); Masanori Abe (Nagaokakyo, JP); Akari Seko (Nagaokakyo, JP)
Assignee: MURATA MANUFACTURING CO., LTD.
H01B1/22B05D5/12H01B1/24
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,476,021
App. No.
18/780,075
Granted
Nov 18, 2025
Kind
B2
Abstract

A conductive composite material that includes: particles of a layered material including one or plural layers, wherein the one or plural layers include a layer body represented by: M m X n , where M is at least one metal of Group 3, 4, 5, 6, or 7, X is a carbon atom, a nitrogen atom, or a combination thereof, n is not less than 1 and not more than 4, m is more than n but not more than 5, and a modifier or terminal T exists on a surface of the layer body, where T is at least one of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, or a hydrogen atom; and a polymer material that includes a hydrogen acceptor and a hydrogen donor, a ratio of the particles of the layered material is more than 19% by volume but not more than 95% by volume.

Claims (18)

1 . A conductive composite material comprising:

particles of a layered material including one or plural layers, wherein the one or plural layers include a layer body represented by:

M m X n

where M is at least one metal of Group 3, 4, 5, 6, or 7,

X is a carbon atom, a nitrogen atom, or a combination thereof,

n is not less than 1 and not more than 4,

m is more than n but not more than 5, and

a modifier or terminal T exists on a surface of the layer body, where T is at least one selected from the group consisting of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, or a hydrogen atom; and

a polymer material that includes a hydrogen acceptor that is at least one selected from the group consisting of a fluorine atom, a chlorine atom, an oxygen atom, or a nitrogen atom; and a hydrogen donor that is a hydroxyl group and/or a secondary amino group,

wherein a ratio of the particles of the layered material to the conductive composite material is more than 19% by volume but not more than 95% by volume, and

wherein the polymer material is a polymer having a unit derived from a (meth)acryloyl group.

2 . The conductive composite material according to claim 1 , wherein the hydrogen acceptor is at least one selected from the group consisting of the fluorine atom, the chlorine atom, or the oxygen atom; and the hydrogen donor is the hydroxyl group and/or a hydrogen atom.

3 . The conductive composite material according to claim 1 , wherein the Mis at least one selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, or Mn.

4 . The conductive composite material according to claim 1 , wherein the Mis at least one selected from the group consisting of Ti, V, Cr, or Mo.

5 . The conductive composite material according to claim 1 , wherein the layer body includes at least one selected from the group consisting of Ti 3 C 2 , Ti 3 CN, or Ti 2 C.

6 . The conductive composite material according to claim 1 , wherein the ratio of the particles of the layered material to the conductive composite material is 30% by volume to 75% by volume.

7 . The conductive composite material according to claim 1 , wherein the conductive composite material is in a coating film form.

8 . The conductive composite material according to claim 1 , wherein the conductive composite material has an electrical conductivity of 280 S/cm or more.

Priority Claims (1)
JP 2020-131866 · Aug 3, 2020 · national
Continuity (3)
Continuation 18158154 · Jan 23, 2023
Continuation PCTJP2021028610 · Aug 2, 2021
Related Publication 20240379260A1 · Nov 14, 2024
References Cited (22)
US 11202398B2 · Soda · 2021 [cited by examiner]
US 11246247B2 · Choi et al. · 2022 [cited by applicant]
US 20200015391A1 · Lee · 2020 [cited by applicant]
US 20200405165A1 · Mtale et al. · 2020 [cited by applicant]
CN 110698847A · 2020 [cited by applicant]
CN 111171703A · 2020 [cited by applicant]
WO 2019055784A1 · 2019 [cited by applicant]
Michael S. Carey “On the Synthesis & Characterization of TiCTx MXene Polymer Composites”, Drexel University 2017: Carey, M. S. (2017). On the Synthesis & Characterization of TiCTx MXene Polymer Composites [Drexel Univer… [cited by examiner]
Zhao et al “Hollow MXene Spheres and 3D Macroporous MXene Frameworks for Na-Ion Storage”. Adv. Mater. 2017, 29, 1702410. [cited by examiner]
Han et al., “Ti3C2 MXenes with Modified Surface for High-Performance Electromagnetic Absorption and Shielding in the X-Band,” ACS Appl. Mater. Interfaces, 2016, vol. 8, pp. 21011-21019. [cited by applicant]
International Search Report in PCT/JP2021/028610, mailed Oct. 19, 2021, 3 pages. [cited by applicant]
Kong et al., “Further surface modification by carbon coating for in-situ growth of Fe304 nanoparticles on MXene Ti3C2 multilayers . . . ”, Electrochimica Acta 289 (2018) 228-237. [cited by applicant]
Ling et al., “Flexible and conductive MXene films and nanocomposites with high capacitance,” PNAS, 2014-11-25, vol. 111, No. 47, pp. 16676-16681. [cited by applicant]
Qian et al., “Fabrication of urchin-like ZnO-MXene nanocomposites for high-performance electromagnetic absorption”, Ceramics International 43 (2017) 10757-10762. [cited by applicant]
Ronchi et al.“Thermoplastic polyurethane-Ti3C2(Tx) MXene nanocomposite . . . ”, Applied Surface Science 528 (2020) 146526. [cited by applicant]
Shahzad et al., “Electromagnetic interference shielding with 2D transition metal carbides (MXenes),” Science, Sep. 9, 2016, vol. 353, Issue 6304, pp. 1137-1140. [cited by applicant]
Sheng et al., “Properties of two-dimensional Ti3C2 MXene/thermoplastic polyurethane nanocomposites . . . ”, Composites Science and Technology 181 (2019) 107710. [cited by applicant]
Wang et al., “Fabrication on the annealed Ti3C2Tx MXene/Epoxy nanocomposites for electromagnetic interference shielding application,” Composites Part B, 2019, vol. 171, pp. 111-118. [cited by applicant]
Yoon et al., “Low-dimensional carbon and MXene-based electrochemical capacitor electrodes”, Nanotechnology 27 (2016) 172001 (21pp). [cited by applicant]
Yu et al., “Interface decoration of exfoliated MXene ultra-thin nanosheets for fire and smoke suppressions of thermoplastic polyurethane elastomer,” Journal of Hazardous Materials, 2019, vol. 374, pp. 110-119. [cited by applicant]
Zhang et al., “Cu2O hybridized titanium carbide with open conductive frameworks for lithium-ion batteries”, Electrochemica Acta 202 (2016) 24-31. [cited by applicant]
Zhi et al., “Study of MXene-filled polyurethane nanocomposites prepared via an emulsion method,” Composites Science and Technology, 2018, vol. 168, pp. 404-411. [cited by applicant]