Solid state battery
A solid state battery having: a laminated structure in which one or more positive electrode layers and one or more negative electrode layers are alternately laminated with a solid electrolytic layer interposed in between; a positive end face electrode on a first end face of the laminated structure; and a negative end face electrode on a second end face of the laminated structure, wherein (1) at least one of the one or more positive electrode layers has an end portion having a protruding shape protruding toward the positive end face electrode in a sectional view and electrically connected to the positive end face electrode, or (2) at least one of the one or more negative electrode layers has an end portion having a protruding shape protruding toward the negative end face electrode in the sectional view and electrically connected to the negative end face electrode.
1 . A solid state battery comprising:
a laminated structure having one or more positive electrode layers and one or more negative electrode layers alternately laminated with a solid electrolytic layer interposed in between;
a positive end face electrode on a first end face of the laminated structure; and
a negative end face electrode on a second end face of the laminated structure, wherein
(1) at least one of the one or more positive electrode layers has an end portion having a protruding shape protruding toward the positive end face electrode and past a vertical line passing through a farthest point from the positive end face electrode among points on a line defining an end face of the end portion in a sectional view and electrically connected to the positive end face electrode, or
(2) at least one of the one or more negative electrode layers has an end portion having a protruding shape protruding toward the negative end face electrode and past a vertical line passing through a farthest point from the negative end face electrode among points on a line defining an end face of the end portion in the sectional view and electrically connected to the negative end face electrode, and
(3) the end portion of the at least one of the one or more positive electrode layers is indirectly electrically connected to the positive end face electrode via a first joining part, and the first joining part is made of a material different from constituent materials of the at least one of the one or more positive electrode layers and the positive end face electrode, or
(4) the end portion of the at least one of the one or more negative electrode layers is indirectly electrically connected to the negative end face electrode via a second joining part, and the second joining part is made of a material different from constituent materials of the at least one of the one or more negative electrode layers and the negative end face electrode.
2 . The solid state battery according to claim 1 , wherein the at least one of the one or more positive electrode layers or the at least one of the one or more negative electrode layers has a structure with no current collector member.
3 . The solid state battery according to claim 1 , wherein (1) the first joining part has a complementary shape portion having a shape that is complementary with respect to the end portion of the at least one of the one or more positive electrode layers in the sectional view, or (2) the second joining part has a complementary shape portion having a shape that is complementary with respect to the end portion of the at least one of the one or more negative electrode layers in the sectional view.
4 . The solid state battery according to claim 1 , wherein (1) a connection surface between the end portion of the at least one of the one or more positive electrode layers and the first joining part forms a step structure, an inclined structure, a curved structure, or a combination thereof, or (2) a connection surface between the end portion of the at least one of the one or more negative electrode layers and the second joining part forms a step structure, an inclined structure, a curved structure, or a combination thereof.
5 . The solid state battery according to claim 1 , wherein (1) an end portion of the first joining part on a side of the positive end face electrode has a protruding shape protruding toward the positive end face electrode in the sectional view, and is electrically connected to the positive end face electrode, or (2) an end portion of the second joining part on a side of the negative end face electrode has a protruding shape protruding toward the negative end face electrode in the sectional view, and is electrically connected to the negative end face electrode.
6 . The solid state battery according to claim 5 , wherein (1) the positive end face electrode has a complementary shape portion having a shape that is complementary with respect to the end portion of the first joining part on the side of the positive end face electrode in the sectional view, or (2) the negative end face electrode has a complementary shape portion having a shape that is complementary with respect to the end portion of the second joining part on the side of the negative end face electrode in the sectional view.
7 . The solid state battery according to claim 5 , wherein (1) a connection surface between the first joining part and the positive end face electrode forms a step structure, an inclined structure, a curved structure, or a combination thereof, or (2) a connection surface between the second joining part and the negative end face electrode forms a step structure, an inclined structure, a curved structure, or a combination thereof.
8 . The solid state battery according to claim 5 , wherein (1) the protruding shape of the end portion of the first joining part has a protruding length that is 5 μm to 500 μm, or (2) the protruding shape of the end portion of the second joining part has a protruding length that is 5 μm to 500 μm.
9 . The solid state battery according to claim 1 , wherein (1) the at least one of the one or more positive electrode layers and the first joining part are integrally sintered bodies, or (2) the at least one of the one or more negative electrode layers and the second joining part are integrally sintered bodies.
10 . The solid state battery according to claim 1 , wherein (1) the at least one of the one or more positive electrode layers, the first joining part, and the positive end face electrode are integrally sintered bodies, or (2) the at least one of the one or more negative electrode layers, the second joining part, and the negative end face electrode are integrally sintered bodies.
11 . The solid state battery according to claim 1 , wherein (1) the first joining part includes a mixed material that is a mixture of a material of the at least one of the one or more positive electrode layers and a material of the positive end face electrode, or (1) the second joining part includes a mixed material that is a mixture of a material of the at least one of the one or more negative electrode layers and a material of the negative end face electrode.
12 . The solid state battery according to claim 1 , wherein (1) an entire end face of the end portion of the at least one of the one or more positive electrode layers is directly electrically connected to the first joining part, or (1) an entire end face of the end portion of the at least one of the one or more negative electrode layers is directly electrically connected to the second joining part.
13 . The solid state battery according to claim 1 , wherein (1) a first part of an end face of the end portion of the at least one of the one or more positive electrode layers is directly electrically connected to the first joining part and a second part of the end face is directly electrically connected to the positive end face electrode, or (2) a first part of an end face of the end portion of the at least one of the one or more negative electrode layers is directly electrically connected to the second joining part and a second part of the end face is directly electrically connected to the negative end face electrode.
14 . The solid state battery according to claim 1 , wherein the positive end face electrode and the negative end face electrode have different colors.