Organopolysiloxane composition for forming pressure sensitive adhesive layer and use of same
Provided is a curing reactive organopolysiloxane composition that forms a pressure-sensitive adhesive layer having practically sufficient curability and pressure-sensitive adhesive strength, and a relatively high shear storage elastic modulus and tensile stress at 500% strain. The organopolysiloxane composition comprises: (A) a chain organopolysiloxane having a content of vinyl portions in alkenyl groups within a range of 0.02 to 0.30 mass %; (B) an organopolysiloxane resin having a content of hydroxyl groups and the like of 9 mol % or less, and a molecular weight of 4500 or more; (C) an organohydrogenpolysiloxane; and (D) a hydrosilylation reaction catalyst. A mass ratio of a resin component to a chain siloxane component is within a range of 1.4 to 3.0. A pressure-sensitive adhesive layer obtained by curing the organopolysiloxane composition has a shear storage elastic modulus G′ at 25° C. of 1.0 MPa or more and a stress at 500% strain of 0.50 MPa or more.
1 . An organopolysiloxane composition for forming a pressure-sensitive adhesive layer, the composition comprising:
(A) a chain organopolysiloxane having on average more than one alkenyl group in a molecule;
(B) an organopolysiloxane resin, wherein the total content of hydroxyl groups and hydrolyzable groups relative to all silicon atoms in a molecule is 9 mol % or less, and a weight average molecular weight (Mw) measured in terms of standard polystyrene by gel permeation chromatography (GPC) is 4500 or more;
(C) an organohydrogenpolysiloxane having at least two Si—H bonds in a molecule; and
(D) an effective amount of a hydrosilylation reaction catalyst; and
optionally, (A′) a chain organopolysiloxane not containing a reactive group having a carbon-carbon double bond in a molecule;
wherein a content of vinyl (CH 2 ═CH) portions of the alkenyl groups in component (A) is within a range of 0.04 to 0.300 mass %, and a mass ratio of component (B) to the sum of components (A) and (A′) is within a range of 1.75 to 1.90; and
wherein a pressure-sensitive adhesive layer obtained by curing the composition has a shear storage elastic modulus G′ at 25° C. of 1.5 to 7.5 MPa and a stress at 500% strain at 25° C. of 1.0 to 3.0 MPa.
2 . The organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 , wherein a pressure-sensitive adhesive force of a pressure-sensitive adhesive layer having a thickness of 50 μm obtained by curing the composition, as measured at a tension rate of 300 mm/min using a 180° peeling test method in accordance to JIS Z 0237 for a polymethyl methacrylate sheet having a thickness of 2 mm, is within a range of 1300 gf/inch or more.
3 . The organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 , wherein a pressure-sensitive adhesive force of a pressure-sensitive adhesive layer having a thickness of 50 μm obtained by curing the composition, as measured at a tension rate of 300 mm/min using a 180° peeling test method in accordance to JIS Z 0237 for a polymethyl methacrylate sheet having a thickness of 2 mm, is within a range of 1400 gf/inch or more.
4 . The organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 , wherein:
component (A) is a chain organopolysiloxane in which the content of vinyl (CH 2 ═CH) portions of the alkenyl groups is within a range of 0.04 to 0.27 mass % and at least a portion of component (A) is (A1) a raw rubber organopolysiloxane containing an alkenyl group and having a viscosity of 100,000 mPa's or more at 25° C. or having a plasticity within a range of 50 to 200 as measured in accordance with a method as specified in JIS K6249;
component (B) is an organopolysiloxane resin mixture containing a R 3 SiO 1/2 unit (M unit) and an SiO 4/2 unit (Q unit), where R is a monovalent organic group and 90 mol % or more of R is an alkyl group having 1 to 6 carbon atoms or a phenyl group;
an amount of component (C) is in an amount such that the ratio (molar ratio) of the amount of SiH groups in component (C) relative to the total amount of the alkenyl groups in components (A) and (B) is 0.1 to 100; and
an amount of component (D) is in an amount such that a platinum-based metal in a solid fraction of the composition is within a range of 0.1 to 200 ppm.
5 . The organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 , wherein component (A) is a chain organopolysiloxane having on average more than one alkenyl group in a molecule, wherein the alkenyl is bonded to a silicon atom at a site other than an end of a molecular chain.
6 . The organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 , wherein an amount of component (C) is in an amount such that the ratio (molar ratio) of the substance amount of SiH groups in component (C) relative to the total substance amount of the alkenyl groups in components (A) and (B) is 20 to 60.
7 . A pressure-sensitive adhesive layer obtained by curing the organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 .
8 . A laminated body, comprising a pressure-sensitive adhesive layer obtained by curing the organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 on a film substrate.
9 . The laminated body according to claim 8 , wherein a release layer for the pressure-sensitive adhesive layer is provided on one or two or more film substrates.
10 . An elastic pressure-sensitive adhesive member obtained by curing the organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 .
11 . An electronic apparatus or electrical device, comprising the elastic pressure-sensitive adhesive member according to claim 10 .
12 . A speaker, comprising the elastic pressure-sensitive adhesive member according to claim 10 .
13 . The organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 , wherein octamethyltetrasiloxane and decamethylpentasiloxane are each present in the composition in an amount of less than 0.1 mass % of component (A).
14 . The organopolysiloxane composition for forming a pressure-sensitive adhesive layer according to claim 1 , wherein component (B) has a molar ratio of M units to Q units of from 0.5 to 2.0.