Process for converting olefins to distillate fuels
A process for oligomerizing an olefin stream with an oligomerization catalyst to produce an oligomerized olefin stream. Oligomerization may comprise a first stage ethylene oligomerization step followed by a second stage oligomerization of the first stage oligomerized olefin to higher olefins. The oligomerized olefin stream can be separated into jet and diesel fuel streams. The olefin stream may be obtained by converting oxygenates to olefins with an MTO catalyst.
1 . A process for oligomerizing an olefin stream comprising:
oligomerizing said olefin stream, as a first stage oligomerization step, with a first stage oligomerization catalyst to provide a first stage oligomerized olefin stream;
oligomerizing said first stage oligomerized olefin stream, as a second stage oligomerization step, with a second stage oligomerization catalyst to provide a second stage oligomerized olefin stream;
separating a distillate olefin stream from said second stage oligomerized olefin stream and hydrotreating said distillate olefin stream;
feeding the hydrotreated distillate olefin stream to a stripper column;
taking a C9+ paraffin diluent stream from a bottoms stream from said stripper column and charging said diluent stream to said first stage oligomerization step, wherein the diluent stream is provided at a diluent-to-feed weight ratio of 2:1 to 5:1; and
separating an ethylene stream from said first stage oligomerized olefin stream and/or said second stage oligomerized olefin stream and recycling said ethylene stream to the first stage oligomerization step.
2 . The process of claim 1 wherein said first stage oligomerization catalyst comprises a metal on amorphous silica alumina.
3 . The process of claim 1 wherein said first stage or said second stage oligomerization catalyst comprises one or more zeolites having a structure selected from MRE, TON, MTT, MFS, MFI, MEL, AFO, AEL, EUO and FER.
4 . The process of claim 1 wherein the first stage oligomerization catalyst or the second stage oligomerization catalyst is regenerated by contact with air.
5 . The process of claim 1 further comprising recycling oligomerized olefins from said second stage oligomerized stream to said second stage oligomerization step.
6 . The process of claim 1 further comprising recycling a portion of the first stage oligomerized olefin stream to said first stage oligomerization step.
7 . The process of claim 6 wherein said second stage oligomerization step is downstream of said first stage oligomerization step.
8 . The process of claim 6 further comprising separating an ethylene stream from said second stage oligomerized olefin stream and recycling said ethylene stream to the first oligomerization step.
9 . The process of claim 1 further comprising separating an ethylene stream from said first stage oligomerized olefin stream and recycling said ethylene stream to the first stage oligomerization step.
10 . The process of claim 1 further comprising separating an intermediate olefin stream from said second stage oligomerized olefin stream and recycling said intermediate olefin stream to said second stage oligomerization step.
11 . The process of claim 1 further comprising separating a portion of said bottoms stream into a jet stream and a diesel stream.
12 . The process of claim 1 wherein said olefin stream comprises at least about 5 wt % ethylene.
13 . A process for converting methanol to distillate fuel comprising:
contacting an oxygenate stream with a methanol-to-olefin (MTO) catalyst to produce an olefin stream;
recovering a deoxygenated olefin stream from said olefin stream;
selectively hydrogenating said deoxygenated olefin stream to produce a selectively hydrogenated olefin stream;
oligomerizing said selectively hydrogenated olefin stream, as a first stage oligomerization step, with an oligomerization catalyst to produce an oligomerized olefin stream;
oligomerizing said oligomerized olefin stream, as a second stage oligomerization step, to provide a second stage oligomerized olefin stream;
separating a distillate olefin stream from said second stage oligomerized olefin stream;
hydrogenating said distillate olefin stream to provide a hydrogenated distillate olefin stream comprising distillate fuel; and
feeding the hydrogenated distillate olefin stream to a stripper column;
taking a C9+ paraffin diluent stream from a bottoms stream from said stripper column and charging said diluent stream to said first stage oligomerization step, wherein the diluent stream is provided at a diluent-to-feed weight ratio of 2:1 to 5:1.
14 . The process of claim 13 wherein said oligomerizing said selectively hydrogenated olefin stream is conducted with a first stage oligomerization catalyst.
15 . The process of claim 13 further comprising separating an ethylene stream and an intermediate olefin stream from said oligomerized olefin stream and recycling said ethylene stream to said first stage oligomerization step and recycling said intermediate olefin stream to said second stage oligomerization step.
16 . A process for converting ethylene to distillate fuel comprising:
oligomerizing said ethylene stream, as a first stage oligomerization step, with a first stage oligomerization catalyst to produce a first stage oligomerized olefin stream;
oligomerizing said first stage oligomerized olefin stream, as a second stage oligomerization step, with a second stage oligomerization catalyst to produce a second stage oligomerized olefin stream;
separating a distillate olefin stream from said second stage oligomerized olefin stream;
hydrogenating said distillate olefin stream to provide a hydrogenated distillate olefin stream comprising distillate fuel; and
feeding the hydrogenated distillate olefin stream to a stripper column;
taking a C9+ paraffin diluent stream from a bottoms stream from said stripper column and charging said diluent stream to said first stage oligomerization step, wherein the diluent stream is provided at a diluent-to-feed weight ratio of 2:1 to 5:1.
17 . The process of claim 16 further comprising separating an ethylene stream and an intermediate olefin stream from said second stage oligomerized olefin stream and recycling said ethylene stream to the first stage oligomerization step and recycling said intermediate olefin stream to said second stage oligomerization step.
18 . The process of claim 16 wherein the ethylene stream is obtained by contacting an oxygenate stream with an MTO catalyst to produce an olefin stream.
19 . The process of claim 16 wherein said olefin stream comprises at least about 5 wt % ethylene.