High performance CO2 capture solvent compositions, and CO2 capture systems and processes utilizing same
An aqueous solvent composition useful for CO 2 capture is described, that includes one or more CO 2 -sorbing amines, e.g., an amino acid salt and a tertiary or a sterically hindered amine. The solvent composition may include one or more promoters that are effective to enhance solvent characteristics such as (i) CO 2 sorption capacity, (ii) CO 2 sorption rate, (iii) CO 2 desorption capacity, (iv) CO 2 desorption rate, and (v) regeneration temperature, in relation to a corresponding solvent lacking the promoters. In relation to existing CO 2 capture solvent compositions, the disclosed aqueous solvent composition provides high solvent CO 2 capacity, high rate of CO 2 absorption and desorption, high thermal and oxidative stability, low solvent regeneration energy, low solvent emissions, and low solvent toxicity.
1 . A method of CO 2 capture, comprising:
contacting a CO 2 -containing gas with a CO 2 -sorptive aqueous solvent composition to produce CO 2 -enriched aqueous solvent composition and CO 2 -reduced gas, wherein the CO 2 -sorptive aqueous solvent composition comprises:
potassium lysinate (KlyS);
methyldiethanolamine (MDEA);
piperazine (PZ);
at least one additional amine selected from the group consisting of (i) primary, secondary, and tertiary amines, (ii) primary, secondary, and tertiary alkylamines, (iii) primary, secondary, and tertiary alkanolamines, and (iv) cyclic amines; and
a promoter that is effective to enhance reaction of the KlyS and the MDEA with the CO 2 from CO 2 -containing gas when in contact therewith, for CO 2 capture producing the CO 2 -reduced gas, wherein the promoter consists of at least one selected from the group consisting of amino acids, organic acid amines, and compounds of the formula R 1 R 2 N—R 3 —COOH, wherein each of R 1 , R 2 and R 3 is independently selected from H, C 1 -C 12 alkyl, C 1 -C 12 alkoxy, C 1 -C 12 carboxy, C 1 -C 12 haloalkyl, C 6 -C 12 aryl, C 6 -C 14 arylalkyl, C 5 -C 10 cycloalkyl, amino or substituted amino, thiol, phosphate, sulfate, phosphonate, and sulfonate.
2 . The method of claim 1 , wherein the at least one additional amine in the CO 2 -sorptive aqueous solvent composition is selected from the group consisting of monoethanolamine (MEA), diethanolamine (DEA), aminomethyl propanol (AMP), piperazine (PZ), benzylamine (BZA), diglycolamine (DGA), triethanolamine (TEA), diethylenetriamine (DETA), 2-(2-aminoethylamino) ethanol, diisopropanolamine (DIPA), 2-amino-2-methyl-1,3-propanediol, pentaethylenehexamine, tetramethylenepentaamine, and tetraethylenepentamine (TEPA).
3 . The method of claim 1 , wherein the at least one additional amine in the CO 2 -sorptive aqueous solvent composition is selected from the group consisting of primary alkanolamines, secondary alkanolamines, and cyclic amines.
4 . The method of claim 1 , wherein the at least one additional amine in the CO 2 -sorptive aqueous solvent composition is selected from the group consisting of MEA, DEA, DGA, AMP, and BZA.
5 . The method of claim 1 , wherein the KlyS is present in the CO 2 -sorptive aqueous solvent composition at concentration of 5 to 25% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
6 . The method of claim 1 , wherein the KlyS is present in the CO 2 -sorptive aqueous solvent composition at concentration of 10 to 20% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
7 . The method of claim 1 , wherein the MDEA is present in the CO 2 -sorptive aqueous solvent composition at concentration of 5 to 45% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
8 . The method of claim 1 , wherein the promoter consists of at least one selected from the group consisting of amino acids and organic acid amines.
9 . The method of claim 1 , wherein the promoter consists of at least one selected from the group consisting of amino acids.
10 . The method of claim 1 , wherein the promoter consists of at least one selected from the group consisting of alanine, arginine, asparagine, aspartic acid, cysteine, glutamic acid, glutamine, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine, and valine.
11 . The method of claim 1 , wherein the promoter consists of at least one selected from the group consisting of organic acid amines.
12 . The method of claim 11 , wherein the organic acid amine is an amine of an organic acid selected from the group consisting of succinic acid, maleic acid, fumaric acid, and glutamic acid.
13 . The method of claim 1 , wherein the promoter consists of taurine.
14 . The method of claim 13 , wherein the taurine is present in the CO 2 -sorptive aqueous solvent composition at concentration of 0.1 to 10% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
15 . The method of claim 1 , wherein the MDEA is present in the CO 2 -sorptive aqueous solvent composition at concentration of 10 to 25% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
16 . The method of claim 1 , wherein water is present in the CO 2 -sorptive aqueous solvent composition at concentration of 45 to 70% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
17 . The method of claim 1 , wherein the promoter is present in the CO 2 -sorptive aqueous solvent composition at concentration up to 5% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
18 . The method of claim 1 , wherein the at least one additional amine in the CO 2 -sorptive aqueous solvent composition comprises at least one primary or secondary alkanolamine.
19 . The method of claim 18 , wherein the at least one additional amine in the CO 2 -sorptive aqueous solvent composition comprises one or more selected from the group consisting of monoethanolamine (MEA), diethanolamine (DEA), aminomethyl propanol (AMP), and diglycolamine (DGA).
20 . The method of claim 18 , wherein the at least one additional amine in the CO 2 -sorptive aqueous solvent composition is present at concentration up to 20% by weight, based on total weight of the CO 2 -sorptive aqueous solvent composition.
21 . The method of claim 1 , further comprising regenerating the CO 2 -enriched aqueous solvent composition to remove CO 2 therefrom and produce regenerated CO 2 -sorptive aqueous solvent composition.
22 . The method of claim 1 , further comprising regenerating the CO 2 -enriched aqueous solvent composition, wherein the regenerating comprises:
heating the CO 2 -enriched aqueous solvent composition to desorb CO 2 therefrom, to form a regenerated CO 2 -reduced aqueous solvent composition and desorbed CO 2 -containing gas;
recovering the desorbed CO 2 -containing gas; and
recycling the regenerated CO 2 -reduced aqueous solvent composition to the contacting.
23 . The method of claim 22 , wherein the CO 2 -enriched aqueous solvent composition is heated in the regenerating to temperature in a range of from 80° C. to 150° C.
24 . The method of claim 22 , wherein the recovered desorbed CO 2 -containing gas comprises water vapor.
25 . The method of claim 24 , comprising purifying the recovered desorbed CO 2 -containing gas comprising water vapor, to remove water and impurities therefrom, and produce a purified CO 2 gas.
26 . The method of claim 25 , comprising (i) sequestering the purified CO 2 gas in a sequestration locus, or (ii) enhancing hydrocarbon recovery in a hydrocarbon extraction process using the purified CO 2 gas.
27 . The method of claim 1 , wherein the CO 2 -containing gas that is contacted with the CO 2 -sorptive aqueous solvent composition in the contacting comprises one or more selected from the group consisting of:
coal-fired power plant flue gas;
natural gas combined cycle power plant flue gas;
blast furnace exhaust gas;
cement plant exhaust gas;
natural gas fired once through steam generator gas;
steam methane reformer syngas;
steam methane reformer flue gas;
steam methane reformer PSA tail gas;
dry reforming syngas;
integrated gasification combined cycle (IGCC) syngas;
biogas;
biomass gasification syngas;
municipal waste gasification syngas;
aluminum smelting off gas;
motive vehicle effluent; and
electrical power-generating plant effluent.
28 . A method of CO 2 capture, comprising:
contacting a CO 2 -containing gas with a CO 2 -sorptive aqueous solvent composition to produce CO 2 -enriched aqueous solvent composition and CO 2 -reduced gas,
wherein the CO 2 -sorptive aqueous solvent composition is selected from the group consisting of the following compositions (I)-(VII):
(I) a composition comprising MDEA, KlyS, AMP, PZ, BZA, MEA, H 2 O, and taurine (TAU);
(II) a composition comprising MDEA, KlyS, PZ, MEA, H 2 O, and TAU;
(III) a composition comprising MDEA, KlyS, PZ, DEA, H 2 O, and TAU;
(IV) a composition comprising MDEA, KlyS, PZ, DGA, DEA, H 2 O, and TAU;
(V) a composition comprising MDEA, KlyS, AMP, PZ, DGA, H 2 O, and TAU;
(VI) a composition comprising MDEA, KlyS, PZ, AMP, MEA, H 2 O, and TAU; and
(VII) a composition comprising MDEA, KlyS, PZ, DGA, H 2 O, and TAU,
wherein TAU is present in the composition as a promoter in an amount that is effective to enhance reaction of the KlyS and the MDEA with CO 2 from CO 2 -containing gas when in contact therewith.
29 . The method of claim 28 , wherein the CO 2 -sorptive aqueous solvent composition is selected from the group consisting of the compositions (II), (III), (IV), and (VI).
30 . The method of claim 29 , wherein the CO 2 -sorptive aqueous solvent composition is composition (VII), wherein MDEA is present at concentration of 10 to 25% by weight, KlyS is present at concentration of 10 to 20% by weight, PZ is present at concentration of up to 10% by weight, DGA is present at concentration of up to 10% by weight, H2O is present at concentration of 45 to 70% by weight, and TAU is present at concentration of 0.5 to 10% by weight, wherein each of such percentages by weight is based on total weight of the CO 2 -sorptive aqueous solvent composition, and wherein the total of the weight percentages of all components of the CO 2 -sorptive aqueous solvent composition total to 100 weight percent.