IP Library Granted Patent US 12,531,268
Granted Patent B2
US 12,531,268 · App. 18/150,689 · Granted Jan 20, 2026

Solid electrolyte material and battery using same

Inventors: Tetsuya Asano (Nara, JP); Takashi Kubo (Hyogo, JP); Keita Mizuno (Aichi, JP); Akihiro Sakai (Nara, JP); Takehiro Tanaka (Hyogo, JP); Kensuke Wakasugi (Tokyo, JP); Tomoyuki Komori (Osaka, JP); Takahiro Hamada (Osaka, JP); Mikiya Fujii (Osaka, JP)
Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
H01M10/0562H01M2300/008
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Quick Facts
Patent No.
US 12,531,268
App. No.
18/150,689
Granted
Jan 20, 2026
Kind
B2
Abstract

The solid electrolyte material of the present disclosure consists of Li, M1, M2, and X, wherein M1 is at least two selected from the group consisting of Ca, Mg, and Zn; M2 is at least one selected from the group consisting of Y, Gd, and Sm; and X is at least one selected from the group consisting of F, Cl, Br, and I.

Claims (32)

1 . A solid electrolyte material consisting of:

Li, M1, M2, and X, wherein

M1 is at least two selected from the group consisting of Ca, Mg, and Zn;

M2 is at least one selected from the group consisting of Y, Gd, and Sm;

X is at least one selected from the group consisting of F, Cl, Br, and I; and

in an X-ray diffraction pattern obtained by X-ray diffraction measurement of the solid electrolyte material using Cu-Kα rays:

there is a first peak in a diffraction angle 2θ range of 30.0° or more and 31.0° or less,

there is a second peak in a diffraction angle 2θ range of 39.0° or more and 40.3° or less,

there is a third peak in a diffraction angle 2θ range of 15.0° or more and 15.7° or less,

there is a fourth peak in a diffraction angle 2θ range of 16.3° or more and 17.1° or less, and

there is a fifth peak in a diffraction angle 2θ 0 range of 46.6° or more and 48.1° or less.

2 . The solid electrolyte material according to claim 1 , wherein

M1 is Ca and Mg or is Ca and Zn.

3 . The solid electrolyte material according to claim 1 , wherein

X is at least one selected from the group consisting of Cl and Br.

4 . The solid electrolyte material according to claim 1 , represented by a following composition formula (1):

Li 3−2a−3b (Ca 1−x M1′ x ) a (Y 1−y M2′ y ) 1+b Br 6−z CL z   (1)

here,

M1′ is at least one selected from the group consisting of Zn and Mg;

M2′ is at least one selected from the group consisting of Gd and Sm; and

following five mathematical expressions:

0<a ≤0.3;

0≤b ≤0.1;

0<x ≤0.5;

0≤y ≤0.9; and

0≤z≤6

are satisfied.

5 . A battery comprising:

a positive electrode;

a negative electrode; and

an electrolyte layer disposed between the positive electrode and the negative electrode, wherein

at least one selected from the group consisting of the positive electrode, the negative electrode, and the electrolyte layer contains the solid electrolyte material according to claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2023
From: ASANO, TETSUYA; KUBO, TAKASHI; MIZUNO, KEITA; SAKAI, AKIHIRO; TANAKA, TAKEHIRO; WAKASUGI, KENSUKE; KOMORI, TOMOYUKI; HAMADA, TAKAHIRO; FUJII, MIKIYA
To: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
Reel/Frame 064052/0161 →
Priority Claims (1)
JP 2020-125316 · Jul 22, 2020 · national
Continuity (2)
Continuation PCTJP2021021702 · Jun 8, 2021
Related Publication 20230163352A1 · May 25, 2023
References Cited (8)
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JP 2011129312 · 2011 [cited by applicant]
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International Search Report of PCT application No. PCT/JP2021/021702 dated Jul. 27, 2021. [cited by applicant]