Epitaxial structure of nonpolar AlGaN-based deep-ultraviolet (DUV) photoelectric detector and preparation method thereof
An epitaxial structure of a nonpolar AlGaN-based deep-ultraviolet (DUV) photoelectric detector and a preparation method thereof are provided. The epitaxial structure of the nonpolar AlGaN-based DUV photoelectric detector includes a nonpolar AlN buffer layer, a nonpolar Al 0.15 Ga 0.85 N buffer layer, and a nonpolar Al 0.7 Ga 0.3 N epitaxial layer that are sequentially grown on a LaAlO 3 substrate. The LaAlO 3 substrate takes a (100) plane as an epitaxial plane, and AlN[11-20] as an epitaxial growth direction. With the LaAlO 3 substrate, the epitaxial structure reduces dislocations and stresses between the substrate and the epitaxial buffer layer. By designing two AlGaN epitaxial buffer layers with different components, the epitaxial structure reduces a dislocation density and a surface roughness of the nonpolar AlGaN epitaxial layer, further accelerates photoresponse and detectivity of the detector, and enhances overall performance of the nonpolar AlGaN-based DUV photoelectric detector.
1 . An epitaxial structure of a nonpolar AlGaN-based deep-ultraviolet (DUV) photoelectric detector, comprising a LaAlO 3 substrate, wherein a nonpolar AlN buffer layer, a nonpolar Al 0.15 Ga 0.85 N buffer layer, and a nonpolar Al 0.7 Ga 0.3 N epitaxial layer are sequentially grown on the LaAlO 3 substrate; and the LaAlO 3 substrate takes a (100) plane as an epitaxial plane, and AlN[11-20] as an epitaxial growth direction.
2 . The epitaxial structure of the nonpolar AlGaN-based DUV photoelectric detector according to claim 1 , wherein the nonpolar AlN buffer layer has a thickness of 300 nm to 400 nm.
3 . The epitaxial structure of the nonpolar AlGaN-based DUV photoelectric detector according to claim 1 , wherein the nonpolar Al 0.15 Ga 0.85 N buffer layer has a thickness of 350 nm to 400 nm.
4 . The epitaxial structure of the nonpolar AlGaN-based DUV photoelectric detector according to claim 1 , wherein the nonpolar Al 0.7 Ga 0.3 N epitaxial layer has a thickness of 450 nm to 550 nm.
5 . A preparation method of an epitaxial structure of a nonpolar AlGaN-based deep-ultraviolet (DUV) photoelectric detector, comprising: selecting a LaAlO 3 substrate, and cleaning a surface of the LaAlO 3 substrate to obtain a cleaned LaAlO 3 substrate;
putting the cleaned LaAlO 3 substrate into an ultrahigh vacuum (UHV) chamber, and annealing the cleaned LaAlO 3 substrate at a high temperature to remove surface contamination;
charging nitrogen to the UHV chamber, and epitaxially growing a nonpolar AlN buffer layer on the LaAlO 3 substrate by pulsed laser deposition (PLD);
changing a target material in an environment of growing the nonpolar AlN buffer layer, and growing a nonpolar Al 0.15 Ga 0.85 N buffer layer on the nonpolar AlN buffer layer in-situ; and
changing the target material in the environment of growing the nonpolar AlN buffer layer, and growing a nonpolar Al 0.7 Ga 0.3 N epitaxial layer on the Al 0.15 Ga 0.85 N buffer layer;
wherein the LaAlO 3 substrate takes a (100) plane as an epitaxial plane, and AlN[11-20] as an epitaxial growth direction.
6 . The preparation method according to claim 5 , wherein the environment of growing the nonpolar AlN buffer layer is as follows: by keeping a vacuum degree in the UHV chamber, a laser energy at 220 mJ to 300 mJ, a laser frequency at 15 Hz to 30 Hz, a nitrogen flow at 2 sccm to 8 sccm, and a nitrogen pressure in the UHV chamber at 6 mTorr to 10 mTorr, the nonpolar AlN buffer layer is grown in an N-rich atmosphere.
7 . The preparation method according to claim 5 , wherein the nonpolar AlN buffer layer is epitaxially grown on the LaAlO 3 substrate, and an Al source is an AlN high-purity ceramic target material.
8 . The preparation method according to claim 5 , wherein the nonpolar Al 0.15 Ga 0.85 N buffer layer is grown on the nonpolar AlN buffer layer in-situ, and the target material is gallium-rich AlGaN ceramic.
9 . The preparation method according to claim 5 , wherein the nonpolar Al 0.7 Ga 0.3 N epitaxial layer is grown on the Al 0.15 Ga 0.85 N buffer layer, and the target material is aluminum-rich AlGaN ceramic.
10 . The preparation method according to claim 5 , wherein the nonpolar AlN buffer layer has a thickness of 300 nm to 400 nm;
the nonpolar Al 0.15 Ga 0.85 N buffer layer has a thickness of 350 nm to 400 nm; and
the nonpolar Al 0.7 Ga 0.3 N epitaxial layer has a thickness of 450 nm to 550 nm.