Organic light emitting device
The present specification relates to an organic light emitting device including an anode, a first organic material layer including a compound of Chemical Formula 1, a second organic material layer including a compound of Chemical Formula 2, a light emitting layer and a cathode: wherein all the variables are described herein.
1 . An organic light emitting device comprising:
a cathode;
an anode;
a light emitting layer provided between the cathode and the anode, and comprising an aromatic amine derivative as a dopant;
a first organic material layer provided between the anode and the light emitting layer and including a compound of Chemical Formula 1; and
a second organic material layer provided between the first organic material layer and the light emitting layer and including a compound of Chemical Formula 13:
wherein, in Chemical Formula 1,
L1 is a phenyl group, a biphenylyl group, a naphthyl group, or a fluorenylenyl group unsubstituted or substituted with an alkyl group, L2 and L3 are the same as or different from each other, and each independently a substituted or unsubstituted arylene group, a is an integer of 1 to 3, b and c are each an integer of 0 to 3, at least one of b or c is not an integer of 0, and when a to c are each 2 or greater, L1 to L3 in each occurrence are the same as or different from each other;
Ar1 to Ar6 are the same as or different from each other, and each independently a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group, or Ar1 and Ar2; Ar3 and Ar4; Ar5 and Ar6; Ar3 and L2; or Ar5 and L3 bond to each other and together with the N atom to which they are attached, respectively, to form a monocyclic or multicyclic aromatic or aliphatic hydrocarbon ring or heteroring, 1 is 0, m and n are each independently an integer of 0 to 2, m+n is 1 or greater, and when m or n is 2, each occurrence of —NAr3Ar4 or —NAr5Ar6, respectively, is the same as or different from each other, hydrogen bonds to L1 instead of —NAr1Ar2, when m or n is 0, hydrogen bonds to L2 or L3 instead of —NAr3 Ar4 or —NAr5Ar6, respectively;
X is NR′; O; or S, p is 0 or 1, and when p is 0, the 2 carbons attached to X directly bond to each other;
R is deuterium;
d is an integer of 0 to 3,
R′ is hydrogen or deuterium;
at least one of —NAr3Ar4 or —NAr5Ar6 is represented by the following structural formula:
which is attached to L2 or L3, respectively, on the para-position, when b or c, respectively, is not 0, and L2 or L3 is each a phenylene,
wherein,
Xa is NRc, O, or S; and r is 0 such that the two carbons attached to Xa directly bond to each other,
Ra is deuterium, g is an integer of 0 to 8, and
Rc is hydrogen or deuterium,
in Chemical Formula 13,
Ar7 and Ar8 are the same as or different from each other, and each independently a substituted or unsubstituted aryl group;
R3 to R5 are deuterium; and
e is an integer of 0-4, f is an integer of 0-3, and x is an integer of 0 to 8,
wherein the first organic material layer is a hole transfer layer, and does not function as a light emitting layer.
2 . The organic light emitting device of claim 1 , wherein, in Chemical Formula 1, p is 0.
3 . The organic light emitting device of claim 1 , wherein, in Chemical Formula 1, a is an integer of 1 to 3.
4 . The organic light emitting device of claim 1 , wherein Chemical Formula 1 is represented by Chemical Formula 4:
wherein, in Chemical Formula 4, Ar1, Ar2, L1 to L3, R, X, a, b, c, d, 1 and p have the same definitions as in Chemical Formula 1;
Xa and Xb are the same as or different from each other, and each independently NRc, O, or S; and r and q are each 0 so that the two carbons attached to each of Xa and Xb directly bond to each other;
Ra and Rb are deuterium, g and h are each an integer of 0 to 8 and
Rc is hydrogen or deuterium.
5 . The organic light emitting device of claim 1 , wherein Chemical Formula 1 is selected from among the following compounds:
6 . The organic light emitting device of claim 1 , wherein Chemical Formula 13 is selected from among the following compounds:
7 . The organic light emitting device of claim 1 , wherein the second organic material layer is an electron blocking layer.
8 . The organic light emitting device of claim 4 , wherein in Chemical Formula 4, p is 0.
9 . The organic light emitting device of claim 1 , wherein in Chemical Formula 1, when m is 0, L2 is not an unsubstituted or substituted phenylene; and when n is 0, L3 is not an unsubstituted or substituted phenylene.
10 . The organic light emitting device of claim 9 , wherein Chemical Formula 1 is selected from among the following compounds: