Negative electrode active material, negative electrode including same, secondary battery including same, and method for manufacturing negative electrode active material
A negative electrode active material, a negative electrode including silicon-containing particles comprising SiO x , wherein 0<x<2, and a Li compound, and a carbon layer present on at least a part of a surface of the silicon-containing particles; and a layer comprising LiF present on at least a part of the silicon-containing particles having the carbon layer. During analysis by X-ray photoelectron spectroscopy (XPS), an atomic ratio (F/O ratio) of F relative to O is 0.45 or more and an atomic ratio (F/C ratio) of F relative to C is 0.5 or less.
1 . A negative electrode active material comprising:
silicon-containing particles comprising SiO x , wherein 0<x<2, and a Li compound, and a carbon layer present on at least a part of a surface of the silicon-containing particles; and
a layer comprising LiF present on at least a part of the silicon-containing particles having the carbon layer,
wherein during analysis by X-ray photoelectron spectroscopy (XPS), an atomic ratio (F/O ratio) of F relative to O is 0.45 or more and an atomic ratio (F/C ratio) of F relative to C is 0.5 or less.
2 . The negative electrode active material of claim 1 , wherein when the negative electrode active material is analyzed by X-ray photoelectron spectroscopy (XPS), the atomic ratio (F/O ratio) of F relative to O is 0.48 or more and 2 or less.
3 . The negative electrode active material of claim 1 , wherein when the negative electrode active material is analyzed by X-ray photoelectron spectroscopy (XPS), the atomic ratio (F/C ratio) of F relative to C is more than 0 and 0.3 or less.
4 . The negative electrode active material of claim 1 , wherein the layer comprising LiF is present in an amount of 0.5 parts by weight to 5 parts by weight based on a total of 100 parts by weight of the negative electrode active material.
5 . The negative electrode active material of claim 1 , wherein a lithium compound is present between the silicon-containing particles and the layer comprising LiF.
6 . The negative electrode active material of claim 5 , wherein the lithium compound comprises one or more selected from the group consisting of Li 2 O, LiOH and Li 2 CO 3 .
7 . The negative electrode active material of claim 1 , wherein the layer comprising LiF is formed by a reaction of one or more lithium compounds selected from the group consisting of Li 2 O, LiOH and Li 2 CO 3 with HF.
8 . The negative electrode active material of claim 1 , wherein Li is present in an amount of 0.1 parts by weight to 40 parts by weight based on a total of 100 parts by weight of the negative electrode active material.
9 . The negative electrode active material of claim 1 , wherein the carbon layer is present in an amount of 0.1 parts by weight to 50 parts by weight based on a total of 100 parts by weight of the negative electrode active material.
10 . A method for preparing the negative electrode active material according to claim 1 , the method comprising:
forming silicon-containing particles comprising SiO x , wherein 0<x<2, and a Li compound and having a carbon layer provided on at least a part of the surface thereof; and
forming a layer comprising LiF on at least a part of the silicon-containing particles by reacting the silicon-containing particles with a HF solution.
11 . The method of claim 10 , wherein the forming of the layer comprising LiF on at least a part of the silicon-containing particles by reacting the silicon-containing particles with the HF solution comprises reacting the lithium compound provided on at least a part of the silicon-containing particles with the HF solution.
12 . A negative electrode comprising the negative electrode active material according to claim 1 .
13 . A secondary battery comprising the negative electrode according to claim 12 .