IP Library › Granted Patent US 12,628,467
Granted Patent B2
US 12,628,467 · App. 17/680,495 · Granted May 12, 2026

Heterogeneous chip integration of III-nitride-based materials for optoelectronic device arrays in the visible and ultraviolet

Inventors: John Michael Dallesasse (Geneva, IL); John A. Carlson (Westlake Village, CA)
Assignee: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
H10H20/018H10H20/0133H10P72/74H10W72/07331H10W72/07336H10W72/07355H10W72/3524
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Quick Facts
Patent No.
US 12,628,467
App. No.
17/680,495
Granted
May 12, 2026
Kind
B2
Abstract

Aspects of the subject disclosure may include, for example, bonding III-Nitride epitaxial layer(s) to a carrier wafer, wherein the III-Nitride epitaxial layer(s) are grown on a non-native substrate, after the bonding, removing at least a portion of the non-native substrate from the III-Nitride epitaxial layer(s), processing the III-Nitride epitaxial layer(s) to derive an array of III-Nitride islands, establishing a metal layer over the array of III-Nitride islands, resulting in an array of metal-coated III-Nitride islands, arranging the carrier wafer relative to a host wafer to position the array of metal-coated III-Nitride islands on a surface of the host wafer, causing the array of metal-coated III-Nitride islands and the surface of the host wafer to eutectically bond, and removing the carrier wafer to yield an integrated arrangement of III-Nitride islands on the host wafer. Additional embodiments are disclosed.

Claims (57)

1 . A method comprising:

bonding one or more III-Nitride epitaxial layers to a carrier wafer, wherein the one or more III-Nitride epitaxial layers are grown on a non-native substrate;

after the bonding, removing at least a portion of the non-native substrate from the one or more III-Nitride epitaxial layers;

processing the one or more III-Nitride epitaxial layers to derive an array of III-Nitride islands;

establishing a metal layer over the array of III-Nitride islands, resulting in an array of metal-coated III-Nitride islands;

arranging the carrier wafer relative to a host wafer to position the array of metal-coated III-Nitride islands on a surface of the host wafer;

causing the array of metal-coated III-Nitride islands and the surface of the host wafer to eutectically bond;

removing the carrier wafer to yield an integrated arrangement of III-Nitride islands on the host wafer;

obtaining a second device that includes a second carrier wafer having a second array of metal-coated III-Nitride islands, wherein the second device is derived according to one or more steps that correspond to one or more of the bonding, the removing of the at least a portion of the non-native substrate, the processing, and the establishing;

using an optical alignment tool to align the second carrier wafer relative to the host wafer to position the second array of metal-coated III-Nitride islands on the surface of the host wafer relative to the integrated arrangement of III-Nitride islands;

causing the second array of metal-coated III-Nitride islands and the surface of the host wafer to eutectically bond; and

removing the second carrier wafer, thereby resulting in a further integrated arrangement of III-Nitride islands on the host wafer in which the second array of metal-coated III-Nitride islands is interleaved with the integrated arrangement of III-Nitride islands.

2 . The method of claim 1 , wherein the arranging the carrier wafer relative to the host wafer comprises epitaxial transferring the array of metal-coated III-Nitride islands, in unison, onto the surface of the host wafer.

3 . The method of claim 1 , wherein the processing the one or more III-Nitride epitaxial layers comprises performing photolithographic defining and etching to derive the array of III-Nitride islands.

4 . The method of claim 1 , further comprising planarizing and patterning the integrated arrangement of III-Nitride islands to fabricate photonic pixels.

5 . The method of claim 4 , wherein the photonic pixels are fabricated to provide functions relating to one or more of white light emission, ultraviolet (UV) light emission, chip-to-chip communications, visible light communications (VLC), and quantum information processing.

6 . The method of claim 1 , wherein the bonding the one or more III-Nitride epitaxial layers to the carrier wafer is performed via a bonding polymer.

7 . The method of claim 6 , further comprising, after the bonding the one or more III-Nitride epitaxial layers to the carrier wafer, removing excess portions of the bonding polymer.

8 . The method of claim 7 , further comprising, after the processing the one or more III-Nitride epitaxial layers to derive the array of III-Nitride islands, removing additional portions of the bonding polymer based on locations of the III-Nitride islands.

9 . The method of claim 8 , further comprising removing remaining portions of the bonding polymer to enable removal of the carrier wafer.

10 . The method of claim 1 , wherein the one or more steps comprise:

bonding additional III-Nitride epitaxial layers to the second carrier wafer, wherein the additional III-Nitride epitaxial layers are grown on a second non-native substrate;

after the bonding the additional III-Nitride epitaxial layers to the second carrier wafer, removing at least a portion of the second non-native substrate from the additional III-Nitride epitaxial layers;

processing the additional III-Nitride epitaxial layers to derive a second array of III-Nitride islands; and

establishing a second metal layer over the second array of III-Nitride islands, resulting in the second array of metal-coated III-Nitride islands.

11 . A heterogenous integration process, comprising:

epitaxially bonding wide band gap semiconductor materials with a silicon carrier wafer, wherein the wide band gap semiconductor materials are grown on a non-native substrate;

removing the non-native substrate from the wide band gap semiconductor materials;

defining and deriving an array of wide band gap semiconductor islands;

establishing a metal layer over the array of wide band gap semiconductor islands, resulting in an array of metal-coated wide band gap semiconductor islands;

epitaxially transferring the array of metal-coated wide band gap semiconductor islands to a surface of a host wafer;

forming a eutectic bond between the array of metal-coated wide band gap semiconductor islands and the surface of the host wafer, wherein one or more metal layer portions of the eutectic bond function as a mirror that provides reflectivity spanning a visible spectrum and an ultraviolet (UV) spectrum;

removing the silicon carrier wafer;

obtaining a second device that includes a second silicon carrier wafer having a second array of metal-coated wide band gap semiconductor islands, wherein the second device is derived according to one or more steps that correspond to one or more of the bonding, the removing of the non-native substrate, the defining and deriving, and the establishing;

using an optical alignment tool to align the second silicon carrier wafer relative to the host wafer to position the second array of metal-coated wide band gap semiconductor islands on the surface of the host wafer relative to the array of metal-coated wide band gap semiconductor islands;

causing the second array of metal-coated wide band gap semiconductor islands and the surface of the host wafer to eutectically bond; and

removing the second silicon carrier wafer, thereby resulting in an integrated arrangement of wide band gap semiconductor islands on the host wafer in which the second array of metal-coated wide band gap semiconductor islands is interleaved with the array of metal-coated wide band gap semiconductor islands.

12 . The heterogenous integration process of claim 11 , wherein the wide band gap semiconductor materials comprise III-Nitride epitaxial materials.

13 . The heterogenous integration process of claim 11 , wherein the metal layer is composed of aluminum.

14 . The heterogenous integration process of claim 13 , wherein the eutectic bond comprises an aluminum-silicon eutectic bond.

15 . The heterogenous integration process of claim 11 , wherein eutectic bonding between the array of wide band gap semiconductor islands and the surface of the host wafer mechanically secures the array of wide band gap semiconductor islands to the host wafer, and forms one or more electrical interconnects for complementary metal-oxide-semiconductor (CMOS) and optoelectronic planes.

16 . An integration method, comprising:

epitaxially bonding III-Nitride materials with a silicon carrier wafer, wherein the III-Nitride materials are grown on a non-native substrate;

removing the non-native substrate from the III-Nitride materials;

defining and deriving an array of III-Nitride islands;

establishing a metal layer over the array of III-Nitride islands, resulting in an array of metal-coated III-Nitride islands;

epitaxially transferring the array of metal-coated III-Nitride islands to a surface of a host wafer;

forming a eutectic bond between the array of metal-coated III-Nitride islands and the surface of the host wafer, thereby mechanically securing the array of metal-coated III-Nitride islands to the host wafer;

removing the silicon carrier wafer to yield an integrated arrangement of III-Nitride islands on the host wafer;

obtaining a second device that includes a second silicon carrier wafer having a second array of metal-coated III-Nitride islands, wherein the second device is derived according to one or more steps that correspond to one or more of the bonding, the removing, the defining and deriving, and the establishing;

using an alignment tool to align the second silicon carrier wafer relative to the host wafer to position the second array of metal-coated III-Nitride islands on the surface of the host wafer relative to the integrated arrangement of III-Nitride islands;

causing the second array of metal-coated III-Nitride islands and the surface of the host wafer to eutectically bond; and

removing the second silicon carrier wafer, thereby resulting in a further integrated arrangement of III-Nitride islands on the host wafer in which the second array of metal-coated III-Nitride islands is interleaved with the integrated arrangement of III-Nitride islands.

17 . The integration method of claim 16 , wherein the epitaxially transferring involves epitaxially transferring the array of metal-coated III-Nitride islands, in unison, onto the surface of the host wafer.

18 . The integration method of claim 16 , wherein the metal layer is composed of aluminum.

19 . The integration method of claim 18 , wherein the eutectic bond comprises an aluminum-silicon eutectic bond.

20 . The integration method of claim 16 , wherein eutectic bonding between the array of metal-coated III-Nitride islands and the surface of the host wafer forms one or more electrical interconnects for complementary metal-oxide-semiconductor (CMOS) and optoelectronic planes, and functions as a mirror that provides reflectivity spanning a visible spectrum and an ultraviolet (UV) spectrum.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 8, 2022
From: DALLESASSE, JOHN MICHAEL; CARLSON, JOHN A.
To: THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
Reel/Frame 059192/0766 →
Continuity (3)
Provisional Application 63185800 · May 7, 2021
Provisional Application 63154399 · Feb 26, 2021
Related Publication 20220278073A1 · Sep 1, 2022
References Cited (29)
US 6015719A · Kish, Jr. et al. · 2000 [cited by applicant]
US 6514782B1 · Wierer, Jr. et al. · 2003 [cited by applicant]
US 8110823B2 · Bowers · 2012 [cited by applicant]
US 8138515B2 · Zeng et al. · 2012 [cited by applicant]
US 8547036B2 · Tran · 2013 [cited by applicant]
US 8866149B2 · Holder et al. · 2014 [cited by applicant]
US 9178100B2 · Webster et al. · 2015 [cited by applicant]
US 9478583B2 · Hu et al. · 2016 [cited by applicant]
US 10111305B2 · Tran · 2018 [cited by applicant]
US 10192857B2 · Fiorentino et al. · 2019 [cited by applicant]
US 10193627B1 · Herman et al. · 2019 [cited by applicant]
US 10312661B2 · Lambert · 2019 [cited by applicant]
US 10551719B2 · Kim et al. · 2020 [cited by applicant]
US 20100074293A1 · Lochmann et al. · 2010 [cited by applicant]
US 20140191246A1 · Oraw · 2014 [cited by applicant]
US 20170179192A1 · Zhang et al. · 2017 [cited by applicant]
US 20170334711A1 · Chang · 2017 [cited by examiner]
US 20180052283A1 · Krasulick et al. · 2018 [cited by applicant]
EP 2705472B1 · 2019 [cited by applicant]
KR 102080217B1 · 2020 [cited by applicant]
Matsuo et al. Comparison of GaN growth processes on GaAs(111)A and (111)B substrates studied by ab initio calculation, Journal of Crystal Growth, vols. 237-239, Part 2. (Year: 2002). [cited by examiner]
Carlson et al., Epitaxial Bonding and Transfer Processes for Large-Scale Heterogeneously Integrated Electronic-Photonic Circuitry, 2019 J. Electrochem. Soc. 166 D3158 (Year: 2018). [cited by examiner]
Sabine, Refiectivities of Evaporated Metal Films in the Near and Far Ultraviolet, Phys. Rev. 55, 1064 (1939) (Year: 1939). [cited by examiner]
Handbook of Optical Constants of Solids. Edward D. Palik, ed., Academic Press, 1985. [cited by applicant]
Carlson, J.A. et al., “Epitaxial Bonding and Transfer Processes for Large-Scale Heterogeneously Integrated Electronic-Photonic Circuitry”, Journal of The Electrochemical Society 166, No. 1:D3158-D3166, 2019. [cited by applicant]
Ikhmayies, S. , “Phase Diagrams of Al—Si System”, in Energy Technology 2019, The Minerals, Metals & Materials Series, Springer, Cham, 2019, 231-237. [cited by applicant]
Lu, T.J. et al., “Aluminum nitride integrated photonics platform for the ultraviolet to visible spectrum”, Optics express 26, No. 9:11147-11160, 2018. [cited by applicant]
Rajbhandari, S. et al., “A review of gallium nitride LEDs for multi-gigabit-per-second visible light data communications”, 2017 Semicond. Sci. Technol 32, No. 02300, 2019. [cited by applicant]
Rutz, H. et al., “Towards a quantum interface between telecommunication and UV wavelengths: design and classical performance”, Applied Physics B 122, No. 1:13, 2016. [cited by applicant]