Granted Patent
B2
US 12,635,286 · App. 18/745,265 · Granted May 19, 2026
Physical forms of MXene materials exhibiting novel electrical and optical characteristics
Inventors:
Michael J. Ghidiu (Bridgeton, NJ); Michel W. Barsoum (Moorestown, NJ); Yury Gogotsi (Warminster, PA); Aaron Thomas Fafarman (Philadelphia, PA); Andrew Devries Dillon (Philadelphia, PA)
Assignee:
Drexel University
H10F77/244C01B32/914C01B32/921C01B32/949C04B35/56C04B35/5607C04B35/5618C04B35/58C04B35/58007H10H20/833C04B2235/3201C04B2235/3203C04B2235/3205C04B2235/445
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Abstract
The present invention(s) is directed to novel conductive M n+1 X n (T s ) compositions exhibiting high volumetric capacitances, and methods of making the same. The present invention(s) is also directed to novel conductive M n+1 X n (T s ) compositions, methods of preparing transparent conductors using these materials, and products derived from these methods.
Claims (23)
1 . A MXene composition, comprising:
a composition comprising a M n+1 X n (T s ) composition and water,
the ratio of water to the M n+1 X n (T s ) composition—being from about 0.3 to about 0.65 on a mass basis,
the M n+1 X n (T s ) composition having at least one layer having a first and second surface, the layer comprising:
a substantially two-dimensional array of crystal cells,
each crystal cell having an empirical formula of M n+1 X n , such that each X is positioned within an octahedral array of M,
wherein M is at least one Group 3, 4, 5, 6, or 7 metal,
wherein each X is C, N, or a combination thereof and n=1, 2, or 3, and
wherein at least one of said surfaces of the layers has surface terminations, T s , independently comprising alkoxide, alkyl, carboxylate, halide, hydroxide, hydride, oxide, sub-oxide, nitride, sub-nitride, sulfide, sulfonate, thiol, or a combination thereof.
2 . The MXene composition of claim 1 , wherein M is at least one Group 4, 5, 6, or 7 metal.
3 . MXene composition of claim 1 , wherein M is at least one of Hf, Cr, Mn, Mo, Nb, Sc Ta, Ti, V, W or Zr.
4 . The MXene composition of claim 1 , wherein M n+1 X n comprises Sc 2 C, Sc 2 N, Ti 2 C, Ti 2 N, V 2 C, V 2 N, Cr 2 C, Cr 2 N, Zr 2 C, Zr 2 N, Nb 2 C, Nb 2 N, Hf 2 C, Hf 2 N, Ta 2 C, Mo 2 C, Ti 3 C 2 , Ti 3 N 2 , V 3 C 2 , Ta 3 C 2 , Ta 3 N 2 , Mo 3 C 2 , (Cr 2/3 Ti 1/2 ) 3 C 2 , Ti 4 C 3 , Ti 4 N 3 , V 4 C 3 , V 4 N 3 , Ta 4 C 3 , Ta 4 N 3 , Nb 4 C 3 , or a combination thereof.
5 . The MXene composition of claim 1 , wherein the ratio of water to the M n+1 X n (T s ) composition is from about 0.4 to about 0.5 on a mass basis.
6 . The MXene composition of claim 1 , wherein the MXene composition is characterized as malleable.
7 . The MXene composition of claim 1 , wherein the composition is characterized as printable.
8 . The MXene composition of claim 1 , wherein the M n+1 X n (T s ) composition has multiple layers.
9 . A method, comprising dispensing a MXene composition according to claim 1 .
10 . The method of claim 9 , further comprising drying the MXene composition.
11 . The method of claim 9 , further comprising compressing the MXene composition.
12 . The method of claim 11 , wherein the compressing is effect with a pressure in a range of from about 5 psig to about 500 psig.
13 . The method of claim 12 , wherein the compressing gives rise to a solid body having a thickness in a range of from about 0.1 micron to about 100 microns.
14 . The method of claim 12 , wherein the solid body exhibits a volumetric capacitance in a range of about 500 F/cm 3 to about 1500 F/cm 3 , or in a range of from about 100 F/g to about 500 F/g, when tested as a scan rate of 2 mV/s.
15 . The method of claim 12 , wherein the wherein the M n+1 X n (T s ) composition has multiple layers and further wherein the layers have at least one of lithium ions or lithium atoms intercalated therebetween.
Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST
Recorded Oct 7, 2024
From: GHIDIU, MICHAEL J.; BARSOUM, MICHEL W.; GOGOTSI, YURY; FAFARMAN, AARON THOMAS; DILLON, ANDREW DEVRIES
To: DREXEL UNIVERSITY
Reel/Frame 068816/0269 →
Continuity (6)
Continuation
15513740
Provisional Application
62214380
· Sep 4, 2015
Provisional Application
62055155
· Sep 25, 2014
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