Color stable organic light emitting diode stack
The present invention relates to OLED devices and stacks for OLED devices that include a symmetric emissive-layer architecture. In one embodiment, the present invention relates to an emissive stack having three layers, wherein the top and bottom layers emit light in the same or similar color region while the middle layer emits light in a different color region than the other two layers. In such an embodiment, the three layers are in contact with each other with no other layers in between. The symmetric emissive-layer architecture of the present invention can be used to improve the color stability of OLED devices.
1 . An organic light emitting device, comprising:
a first electrode;
a first emissive layer disposed over the first electrode and comprising a first fluorescent blue emissive material;
a first charge generation layer disposed over the first emissive layer;
a second emissive layer disposed over the first charge generation layer and comprising a first red emissive material having a peak wavelength in the range 580-700 nm;
a third emissive layer disposed over the second emissive layer and comprising a first green emissive material;
a fourth emissive layer disposed over the third emissive layer and comprising a second red emissive material having a peak wavelength in the range 580-700 nm;
a second charge generation layer disposed over the fourth emissive layer; and
a fifth emissive layer disposed over the second charge generation layer and comprising a second fluorescent blue emissive material;
wherein:
no emissive layer disposed between the first electrode and the first charge generation layer includes a red emissive material having a peak wavelength in the range 580-700 nm; and
no emissive layer disposed over the second charge generation layer includes a red emissive material having a peak wavelength in the range 580-700 nm.
2 . The device of claim 1 , wherein the second red emissive material is the same material as the first red emissive material.
3 . The device of claim 1 , wherein the second red emissive material comprises a different material than the first red emissive material.
4 . The device of claim 1 , wherein the first red emissive material and/or the second red emissive material is a phosphorescent emissive material.
5 . The device of claim 1 , wherein the second fluorescent blue emissive material comprises a same material as the first fluorescent blue emissive material.
6 . The device of claim 1 , wherein the second fluorescent blue emissive material comprises a different material than the first fluorescent blue emissive material.
7 . The device of claim 1 , wherein the third emissive layer has a thickness that is not more than 5 times the thickness of the second emissive layer and/or the fourth emissive layer.
8 . The device of claim 1 , wherein the third emissive layer has a thickness that is not more than 10 times the thickness of the second emissive layer and/or the fourth emissive layer.
9 . An organic light emitting device, comprising:
a substrate;
a first electrode disposed over the substrate;
a second electrode disposed over the first electrode;
a first charge generation layer disposed between the first electrode and the second electrode;
a second charge generation layer disposed over the first charge generation layer;
a first emissive stack disposed between the first electrode and the second electrode, the first emissive stack comprising:
a first emissive layer comprising a first green emissive material;
a second emissive layer comprising a phosphorescent first blue emissive material; and
a third emissive layer comprising a second green emissive material;
a second emissive stack disposed between the first electrode and the second electrode, the second emissive stack comprising:
a fourth emissive layer comprising a second blue emissive material; and
a third emissive stack disposed between the first electrode and the second electrode, the third emissive stack comprising:
a fifth emissive layer comprising a third blue emissive material;
wherein each emissive stack is separated from any adjacent emissive stack by the first charge generation layer or the second charge generation layer; and
wherein the second emissive stack and the third emissive stack exclude emissive layers comprising red emissive materials, each having a peak wavelength in the range 580-700 nm.
10 . The device of claim 9 , wherein:
the first emissive stack is disposed between the first and second charge generation layers;
the second emissive stack is disposed between the first electrode and the first charge generation layer; and
the third emissive stack is disposed between the second electrode and the second charge generation layer.
11 . The device of claim 9 , wherein at least one of the second blue emissive material and the third blue emissive material comprises a different material than the first blue emissive material.
12 . The device of claim 9 , wherein at least one of the second blue emissive material and the third blue emissive material comprises a same material as the first blue emissive material.
13 . The device of claim 9 , wherein at least one of the second blue emissive material and the third blue emissive material is phosphorescent.
14 . The device of claim 9 , wherein at least one of the second blue emissive material and the third blue emissive material is fluorescent.
15 . The device of claim 9 , wherein the second green emissive material comprises a same material as the first green emissive material.
16 . The device of claim 9 , wherein:
the first emissive stack is disposed between the first electrode and the first charge generation layer;
the second emissive stack is disposed between the first and second charge generation layers; and
the third emissive stack is disposed between the second electrode and the second charge generation layer.
17 . The device of claim 9 , wherein:
the first emissive stack is disposed between the second electrode and the second charge generation layer;
the second emissive stack is disposed between the first and second charge generation layers;
the third emissive stack is disposed between the first electrode and the first charge generation layer.
18 . The device of claim 9 , wherein the second emissive layer has a thickness that is not more than 5 times the thickness of the first emissive layer and/or the third emissive layer.
19 . The device of claim 9 , wherein the second emissive layer has a thickness that is not more than 10 times the thickness of the first emissive layer and/or the third emissive layer.
20 . An organic light emitting device, comprising:
a substrate;
a first electrode disposed over the substrate;
a second electrode disposed over the first electrode;
a first charge generation layer disposed between the first electrode and the second electrode;
a second charge generation layer disposed over the first charge generation layer;
a third charge generation layer disposed over the second charge generation layer;
a first emissive stack disposed between the first electrode and the second electrode, the first emissive stack comprising:
a first emissive layer comprising a first red emissive material;
a second emissive layer comprising a first green emissive material; and
a third emissive layer comprising a second red emissive material;
a second emissive stack disposed between the first electrode and the second electrode, the second emissive stack comprising:
a fourth emissive layer comprising a first blue emissive material; and
a third emissive stack disposed between the first electrode and the second electrode, the third emissive stack comprising:
a fifth emissive layer comprising a second blue emissive material; and
a fourth emissive stack disposed between the first electrode and the second electrode, the fourth emissive stack comprising:
a sixth emissive layer comprising a third blue emissive material;
wherein each emissive stack is separated from any adjacent emissive stack by the first charge generation layer, the second charge generation layer, or the third charge generation layer; and
wherein at least two of the second emissive stack, the third emissive stack, and the fourth emissive stack exclude emissive layers comprising red emissive materials having a peak wavelength in the range 580-700 nm.