IP Library Granted Patent US 6,855,963
Granted Patent B1
US 6,855,963 · App. 10/652,400 · Granted Feb 15, 2005

Ultra high-speed Si/SiGe modulation-doped field effect transistors on ultra thin SOI/SGOI substrate

Assignee: International Business Machines Corporation
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Quick Facts
Patent No.
US 6,855,963
App. No.
10/652,400
Granted
Feb 15, 2005
Kind
B1
Abstract

A silicon and silicon germanium based semiconductor MODFET device design and method of manufacture. The MODFET design includes a high-mobility layer structure capable of ultra high-speed, low-noise for a variety of communication applications including RF, microwave, sub-millimeter-wave and millimeter-wave. The epitaxial field effect transistor layer structure includes critical (vertical and lateral) device scaling and layer structure design for a high mobility strained n-channel and p-channel transistor incorporating silicon and silicon germanium layers to form the optimum modulation-doped heterostructure on an ultra thin SOI or SGOI substrate capable of achieving greatly improved RF performance.

Claims (142)

1. A high-electron-mobility layer semiconductor structure comprising:

an SGOI substrate comprising a SiGe layer on insulator having Ge content ranging between 30-40% and ranging in thickness between 20 nm-30 nm, and having a p-type doping concentration ranging between 1e14 cm −3 -5e17 cm −3 ;

an epitaxial Si 0.95 Ge 0.05 seed layer grown on top of said SiGe layer and ranging in thickness between 0 nm-5 nm;

a regrown Si 1-x Ge x buffer layer grown on top of said seed layer and ranging in thickness between 20 nm-30 nm and having Ge content x ranging between 10%-40%;

an epitaxial tensile strained Si layer grown on top of said buffer layer and ranging in thickness between 5 nm-7 nm;

an epitaxial Si 1-y Ge y spacer layer grown on top of said strained Si layer and ranging in thickness between 3 nm-5 nm and having Ge content y ranging between 30-40%;

an epitaxial Si 1-z Ge z supply layer grown on top of said spacer layer ranging in thickness between 2 nm-8 nm and having a n-type doping concentration ranging between 2e18 cm −3 -2e19 cm −3 and having Ge content ranging between 35-50%; and,

an epitaxial tensile strained Si cap layer grown on top of said supply layer ranging in thickness between 0 nm-3 nm and having a n-type doping concentration ranging between 5e17 cm −3 -5e19 cm −3 .

2. The high-electron-mobility layer semiconductor structure as claimed in claim 1 , wherein said Si 1-y Ge y spacer layer includes a Ge content y=x+a, where “a” ranges between 0-20%.

3. The high-electron-mobility layer semiconductor structure as claimed in claim 1 , wherein said Si 1-z Ge z supply layer includes a Ge content z=x+b, where “b” ranges between 0-30%.

4. The high-electron-mobility layer semiconductor structure as claimed in claim 1 , wherein said Si 1-z Ge z supply layer comprises a Si 1-m-n Ge m C n layer, where m=x+c, and “c” ranges between 0-20%, and “n” ranges between 0.1-2%.

5. The high-electron-mobility layer semiconductor structure as claimed in claim 1 , further comprising:

a gate dielectric layer formed on top of said strained Si cap layer and having an equivalent oxide thickness in a range of 0-1 nm;

a gate conductor formed on top of said gate dielectric layer;

a drain region having a n-type doping concentration greater than 5e19 cm −3 ; and,

a source region having a n-type doping concentration greater than 5e19 cm −3 , wherein said structure forms a high-electron-mobility field effect transistor.

6. The high-electron-mobility field effect transistor as claimed in claim 5 , wherein said Si 1-z Ge z supply layer ranges from about 5 nm-8 nm in thickness and has a sheet doping density of about 3e12 cm −2 .

7. The high-electron-mobility field effect transistor as claimed in claim 5 , wherein said Si 1-z Ge z supply layer is about 4 nm in thickness and has a sheet doping density of about 2.4e12 cm −2 .

8. The high-electron-mobility field effect transistor as claimed in claim 6 , wherein said Si 1-z Ge z supply layer comprises a SiGeC layer having a C content of about 1-1.5%.

9. The high-electron-mobility field effect transistor as claimed in claim 5 , wherein said gate dielectric layer is selected from a group comprising: an oxide, nitride, oxynitride of silicon, and oxides and silicates of Hf, Al, Zr, La, Y, Ta, singly or in combinations thereof.

10. The high-electron-mobility field effect transistor as claimed in claim 5 , wherein said gate conductor is selected from a group comprising: Pt, Ir, W, Pd, Al, Au, Cu, Ti, Co, singly or in combinations thereof.

11. The high-electron-mobility field effect transistor as claimed in claim 5 , wherein said gate conductor is one of: a T-gate geometry, rectangular geometry or a multi-finger geometry.

12. The high-electron-mobility field effect transistor as claimed in claim 5 , wherein a gate length ranges between 30 nm-100 nm.

13. The high-electron-mobility field effect transistor as claimed in claim 5 , wherein a distance between said gate conductor and either said drain or source region ranges from about 20 nm-100 nm.

14. The high-electron-mobility field effect transistor as claimed in claim 5 , further comprising a passivation layer surrounding the gate electrode, said passivation layer having a permittivity ranging between 1-4.

15. A high-electron-mobility field effect transistor comprising:

an SGOI substrate comprising a SiGe layer on insulator having Ge content ranging between 30-40% and ranging in thickness between 20 nm-30 nm, and having a p-type doping concentration ranging between 1e14 cm −3 -5e17 cm −3 ;

a regrown Si 1-x Ge x buffer layer grown on top of said SiGe layer and ranging in thickness between 20 nm-30 nm, and having a Ge content x of 30-40%;

an epitaxial tensile strained Si layer grown on top of said buffer layer and ranging in thickness between 5 nm-7 nm;

an epitaxial Si 1-y Ge y spacer layer grown on top of said strained Si layer and ranging in thickness between 3 nm-5 nm and having Ge content ranging between 30-40%;

an epitaxial Si 1-z Ge z supply layer grown on top of said spacer layer ranging in thickness between 2 nm-8 nm and having a n-type doping concentration ranging between 2e18 cm −3 -2e19 cm −3 and having Ge content ranging between 35-50%;

an epitaxial tensile strained Si cap layer grown on top of said supply layer ranging in thickness between 0 nm-3 nm and having a n-type doping concentration ranging between 5e17 cm −3 -5e19 cm −3 ;

a gate dielectric layer formed on top of said strained Si cap layer and having an equivalent oxide thickness in a range of 0-1 nm;

a gate conductor formed on top of said gate dielectric layer;

a drain region having a n-type doping concentration greater than 5e19 cmM 3 ; and,

a source region having a n-type doping concentration greater than 5e19 cm −3 .

16. A high-electron-mobility layer semiconductor structure comprising:

an SGOI substrate comprising a Si 1-x Ge x layer on insulator ranging in thickness between 10 nm-50 nm;

an epitaxial Si 0.95 Ge 0.05 seed layer grown on top of said SiGe layer and ranging in thickness between 0 nm-5 nm;

an epitaxial Si 1-y Ge y supply layer grown on top of said seed layer ranging in thickness between 2 nm-8 nm and having a n-type doping concentration ranging between 1e18 cm −1 -5e19 cm −3 ; and,

an epitaxial Si 1-y Ge y spacer layer grown on top of said supply layer and ranging in thickness between 3 nm-5 nm;

an epitaxial tensile strained Si layer grown on top of said spacer layer and ranging in thickness between 3 nm-10 nm;

an epitaxial Si 1-y Ge y spacer layer grown on top of said strained Si layer and ranging in thickness between 1 nm-2 nm; and,

an epitaxial tensile strained Si cap layer grown on top of said spacer layer ranging in thickness between 0 nm-2 nm.

17. The high-electron-mobility layer semiconductor structure as claimed in claim 16 , wherein said SGOI substrate includes a Si 1-x Ge x layer with a Ge content x ranging between 30-50%.

18. The high-electron-mobility layer structure as claimed in claim 16 , wherein said Si 1-z Ge z supply layer has a Ge content z=x+a, where “a” ranges between about 0-30% and x ranges between 30-50%.

19. The high-electron-mobility layer semiconductor structure as claimed in claim 16 , wherein said Si 1-z Ge z supply layer comprises a Si 1-m-n Ge m C n layer, where m=x+b, and “b” ranges between 0-30%, and “n” ranges between 0.1-2%.

20. The high-electron-mobility layer semiconductor structure as claimed in claim 16 , wherein said Si 1-y Ge y spacer layer includes a Ge content y=x+c, where “c” ranges between 0-20%.

21. The high-electron-mobility layer semiconductor structure as claimed in claim 16 , further comprising:

a gate dielectric layer formed on top of said strained Si cap layer and having an equivalent oxide thickness in a range of 0-1 nm;

a gate conductor formed on top of said gate dielectric layer;

a drain region having a n-type doping concentration greater than 5e19 cm −3 ; and,

a source region having a n-type doping concentration greater than 5e19 cm −3 , wherein said structure forms a high-electron-mobility field effect transistor.

22. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein said Si 1-z Ge z supply layer is about 5nm-8 nm in thickness and has a sheet doping density of about 3e12 cm −2 .

23. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein said Si 1-z Ge z supply layer is about 4 nm in thickness and has a sheet doping density of about 2.4e12 cm −2 .

24. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein said Si 1-z Ge z supply layer comprises a SiGeC layer having a C content of about 1-1.5%.

25. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein said gate dielectric layer is selected from a group comprising: an oxide, nitride, oxynitride of silicon, and oxides and silicates of Hf, Al, Zr, La, Y, Ta, singly or in combinations thereof.

26. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein said gate conductor is selected from a group comprising: Pt, Ir, W, Pd, Al, Au, Cu, Ti, Co, singly or in combinations thereof.

27. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein said gate conductor is one of: a T-gate geometry, rectangular geometry or a multi-finger geometry.

28. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein a gate length ranges between 30 nm-100 nm.

29. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , wherein a distance between said gate conductor and either said drain or source region ranges from about 20 nm-100 nm.

30. The high-electron-mobility layer semiconductor structure as claimed in claim 21 , further comprising a passivation layer surrounding the gate electrode, said passivation layer having a permittivity ranging between 1-4.

31. A high-electron-mobility field effect transistor comprising:

an SGOI substrate comprising a SiGe layer on insulator having Ge content ranging between 30-40% and ranging in thickness between 20 nm-30 nm;

an epitaxial Si 1-z Ge z supply layer grown on top of said SiGe layer ranging in thickness between 2.5 nm-8 nm and having a n-type doping concentration ranging between 2e18 cm −3 -2e19 cm −3 and having Ge content ranging between 35-50%;

an epitaxial Si 1-y Ge y spacer layer grown on top of said supply layer and ranging in thickness between 3 nm-5 nm and having Ge content ranging between 30-40%;

an epitaxial tensile strained Si channel layer grown on top of said spacer layer ranging in thickness between 5 nm-7 nm and having a doping concentration less than 1e16 cm −3 ;

an epitaxial Si 1-y Ge y spacer layer grown on top of said Si channel layer and ranging in thickness between 1 nm-2 nm and having Ge content ranging between 30-40%;

an epitaxial tensile strained Si cap layer grown on top of said spacer layer ranging in thickness between 0 nm-2 nm;

a gate dielectric layer formed on top of said strained Si cap layer and having an equivalent oxide thickness in a range of 0-1 nm;

a gate conductor formed on top of said gate dielectric layer;

a drain region having a n-type doping concentration greater than 5e19 cm −3 ; and,

a source region having a n-type doping concentration greater than 5e19 cm −3 .

32. A high-electron-mobility layer semiconductor structure comprising:

an SGOI substrate comprising a Si 1-z Ge z supply layer ranging in thickness between 2 nm-8 nm and having a n-type doping concentration ranging between 1e18 cm −3 -5e19 cm −3 ; and,

an epitaxial Si 1-y Ge y spacer layer grown on top of said supply layer and ranging in thickness between 3 nm-5 nm;

an epitaxial tensile strained Si layer grown on top of said spacer layer and ranging in thickness between 3 nm-10 nm;

an epitaxial Si 1-y Ge y spacer layer grown on top of said strained Si layer and ranging in thickness between 1 nm-2 nm; and,

an epitaxial tensile strained Si cap layer grown on top of said spacer layer ranging in thickness between 0 nm-2 nm.

33. The high-electron-mobility layer semiconductor structure as claimed in claim 32 , wherein said SGOI substrate includes a Ge content “x” ranging between 30-50%.

34. The high-electron-mobility layer semiconductor structure as claimed in claim 32 , wherein said doped transferred Si 1-z Ge z supply layer has a Ge content z=x+a, where “a” ranges between about 0-30% and may be formed by a wafer bonding and smart-cut process.

35. The high-electron-mobility layer semiconductor structure as claimed in claim 32 , wherein said doped transferred Si 1-z Ge z supply layer comprises a Si 1-m-n Ge m C n layer, where m=x+b, and “b” ranges between 0-30%, and “n” ranges between 0.1-2%.

36. The high-electron-mobility layer semiconductor structure as claimed in claim 32 , wherein said Si 1-y Ge y spacer layer includes a Ge content y=x+c, where “c” ranges between 0-20%.

37. The high-electron-mobility layer semiconductor structure as claimed in claim 32 , further comprising:

a gate dielectric layer formed on top of said strained Si cap layer and less than 1 nm in thickness;

a gate conductor formed on top of said gate dielectric layer;

a drain region having a n-type doping concentration greater than 5e19 cm −3 ; and,

a source region having a n-type doping concentration greater than 5e19 cm −3 .

38. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , wherein said doped transferred Si 1-z Ge z supply layer is about 5 nm-8 nm in thickness and has a sheet doping density of about 3e12 cm-2.

39. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , wherein said doped transferred Si 1-z Ge z supply layer is about 4 nm in thickness and has a sheet doping density of about 2.4e12 cm-2.

40. The high-electron-mobility layer semiconductor structure as claimed in claim 32 , wherein said doped transferred Si 1-z Ge z supply layer comprises a SiGeC layer having a C content of about 1-1.5%.

41. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , wherein said gate dielectric layer is selected from a group comprising: an oxide, nitride, oxynitride of silicon, and oxides and silicates of Hf, Al, Zr, La, Y, Ta, singly or in combinations thereof.

42. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , wherein said gate conductor is selected from a group comprising: Pt, Ir, W, Pd, Al, Au, Cu, Ti, Co, singly or in combinations thereof.

43. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , wherein said gate conductor is one of: a T-gate geometry, rectangular geometry, or a multi-finger geometry.

44. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , wherein a gate length ranges between 30 nm-100 nm.

45. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , wherein a distance between said gate conductor and either said drain or source region ranges from about 20 nm-100 nm.

46. The high-electron-mobility layer semiconductor structure as claimed in claim 37 , further comprising a passivation layer surrounding the gate electrode, said passivation layer having a permittivity ranging between 1-4.

47. A high-electron-mobility layer semiconductor structure comprising:

an SGOI substrate comprising a SiGe layer on insulator ranging in thickness between 10 nm-50 nm, and having a n-type doping concentration ranging between 1e17 cm −3 -5e19 cm −3 ;

a Si 1-x Ge x regrown buffer layer grown on top of said SiGe layer and ranging in thickness between 10 nm-50 nm and serving as a bottom spacer layer;

an epitaxial tensile strained Si layer grown on top of said regrown buffer layer and ranging in thickness between 3 nm-10 nm;

an epitaxial Si 1-y Ge y spacer layer grown on top of said strained Si layer and ranging in thickness between 3 nm-5 nm;

an epitaxial Si 1-z Ge z supply layer grown on top of said spacer layer ranging in thickness between 2 nm-8 nm and having a n-type doping concentration ranging between 1e18 cm −3 -5e19 cm −3 ; and,

an epitaxial tensile strained Si cap layer grown on top of said supply layer ranging in thickness between 0 nm-3 nm and having a n-type doping concentration ranging between 5e17 cm −3 -5e19 cm −3 .

48. The high-electron-mobility layer semiconductor structure as claimed in claim 47 , wherein said SGOI substrate includes a Ge content ranging between 30-50%.

49. The high-electron-mobility layer semiconductor structure as claimed in claim 47 , wherein said Si 1-x Ge x regrown buffer layer includes a Ge content x ranging between 10-35%.

50. The high-electron-mobility layer semiconductor structure as claimed in claim 47 , wherein said Si 1-y Ge y spacer layer includes a Ge content y=x+a, where “a”, ranges between 0-20%.

51. The high-electron-mobility layer semiconductor structure as claimed in claim 47 , wherein said Si 1-z Ge z supply layer includes a Ge content z=x+b, where “b” ranges between 0-30%.

52. The high-electron-mobility layer semiconductor structure as claimed in claim 47 , wherein said Si 1-z Ge z supply layer comprises a Si 1-m-n Ge m C n layer, where m=x+c, and “c” ranges between 0-20%, and “n” ranges between 0.1-2%.

53. The high-electron-mobility layer semiconductor structure as claimed in claim 47 , further comprising:

a gate dielectric layer formed on top of said strained Si cap layer and having an equivalent oxide thickness in a range of 0-1 nm;

a gate conductor formed on top of said gate dielectric layer;

a drain region having a n-type doping concentration greater than 5e19 cm −3 ; and,

a source region having a n-type doping concentration greater than 5e19 cm −3 .

54. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , wherein said Si 1-z Ge z supply layer is about 5 nm-8 nm in thickness and has a sheet doping density of about 3e12 cm-2.

55. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , wherein said Si 1-z Ge z supply layer is about 4 nm in thickness and has a sheet doping density of about 2.4e12 cm-2.

56. The high-electron-mobility layer semiconductor structure as claimed in claim 54 , wherein said Si 1-z Ge z supply layer comprises a SiGeC layer having a C content of about 1-1.5%.

57. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , wherein said gate dielectric layer is selected from a group comprising: an oxide, nitride, oxynitride of silicon, and oxides and silicates of Hf, Al, Zr, La, Y, Ta, singly or in combinations thereof.

58. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , wherein said gate conductor is selected from a group comprising: Pt, Ir, W, Pd, Al, Au, Cu, Ti, Co, singly or in combinations thereof.

59. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , wherein said gate conductor is one of: a T-gate, rectangular, or multi-finger geometry.

60. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , wherein a gate length ranges between 30 nm-100 nm.

61. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , wherein a distance between said gate conductor and either said source or drain region ranges from about 20 nm-100 nm.

62. The high-electron-mobility layer semiconductor structure as claimed in claim 53 , further comprising a passivation layer surrounding the gate electrode, said passivation layer having a permittivity ranging between 1-4.

63. A high-hole-mobility layer semiconductor structure comprising:

an SGOI substrate comprising an epitaxial Si 1-j Ge j supply layer ranging in thickness between 5 nm-25 nm, and having a p-type doping concentration ranging between 1e18-5e19 cm −3 ;

an epitaxial Si 1-k Ge k spacer layer grown on top of said supply layer and ranging in thickness between 3 nm-7 nm;

an epitaxial compressively strained Si 1-m Ge m channel layer grown on top of said spacer layer and ranging in thickness between 5 nm-20 nm; and,

an epitaxial strained Si 1-n Ge n cap layer grown on top of said strained Si 1-m Ge m channel layer and ranging in thickness between 2 nm-10 nm.

64. The high-hole-mobility layer semiconductor structure as claimed in claim 63 , wherein said Si 1-j Ge j supply layer includes a Ge content j ranging between 30-70%.

65. The high-hole-mobility layer semiconductor structure as claimed in claim 63 , wherein said Si 1-k Ge k spacer layer includes a Ge content k ranging between 30-70%.

66. The high-hole-mobility layer semiconductor structure as claimed in claim 63 , wherein said Si 1-m Ge m channel layer includes a Ge content m ranging between 60-100%.

67. The high-hole-mobility layer semiconductor structure as claimed in claim 63 , wherein said stained Si 1-n Ge n cap layer includes a Ge content n ranging between 0%-30%.

68. The high-hole-mobility layer semiconductor structure as claimed in claim 63 , further comprising:

a gate conductor formed on top of said gate dielectric layer;

a drain region having a p-type doping concentration greater than 5e19 cm −3 ; and,

a source region having a p-type doping concentration greater than 5e19 cm −3 .

69. The high-hole-mobility layer semiconductor structure as claimed in claim 68 , wherein said gate dielectric layer is selected from a group comprising: an oxide, nitride, oxynitride of silicon, and oxides and silicates of Hf, Al, Zr, La, Y, Ta, singly or in combinations thereof.

70. The high-hole-mobility layer semiconductor structure as claimed in claim 68 , wherein said gate conductor is selected from a group comprising: Pt, Ir, W, Pd, Al, Au, Cu, Ti, Co, singly or in combinations thereof.

71. The high-hole-mobility layer semiconductor structure as claimed in claim 68 , wherein said gate conductor is one of: a T-gate, rectangular, or multi-finger geometry.

72. The high-hole-mobility layer semiconductor structure as claimed in claim 68 , wherein a gate length ranges between 30 nm-100 nm.

73. The high-hole-mobility layer semiconductor structure as claimed in claim 68 , wherein a distance between said gate conductor and either said drain or source region ranges from about 20 nm-100 nm.

74. The high-hole-mobility layer semiconductor structure as claimed in claim 68 , further comprising a passivation layer surrounding the gate electrode, said passivation layer having a permittivity ranging between 1-4.

Assignments (8)
RELEASE OF SECURITY INTEREST Recorded May 12, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 056987/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 20, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES INC.
Reel/Frame 054636/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2020
From: GLOBALFOUNDRIES INC.
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 054633/0001 →
SECURITY AGREEMENT Recorded Nov 29, 2018
From: GLOBALFOUNDRIES INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 049490/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2015
From: GLOBALFOUNDRIES U.S. 2 LLC; GLOBALFOUNDRIES U.S. INC.
To: GLOBALFOUNDRIES INC.
Reel/Frame 036779/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2015
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: GLOBALFOUNDRIES U.S. 2 LLC
Reel/Frame 036550/0001 →
CONFIRMATORY LICENSE Recorded Oct 25, 2010
From: IBM
To: NAVY, UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE
Reel/Frame 025189/0421 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 29, 2003
From: CHU, JACK O.; OUYANG, QIQING C.
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 014471/0139 →