Method of polishing a silicon-containing dielectric
View Patent ↗The inventive method of polishing a silicon-containing dielectric layer involves the use of a chemical-mechanical polishing system comprising (a) an inorganic abrasive, (b) a polishing additive, and (c) a liquid carrier, wherein the polishing composition has a pH of about 4 to about 6. The inventive chemical-mechanical polishing system comprises (a) ceria, (b) a polishing additive, and (c) a liquid carrier, wherein the polishing system has a pH of about 4 to about 6.
1. A method of polishing a substrate comprising:
(i) contacting a substrate comprising a silicon dioxide layer and a silicon nitride layer with a chemical-mechanical polishing system comprising:
(a) an inorganic abrasive,
(b) a polishing additive bearing a functional group with a pK a of about 3 to about 9, wherein the polishing additive is selected from the group consisting of aniline and arylamines having one or more substituents selected from the group consisting of carboxylic acids, sulfonic acids, phosphonic acids, thiol groups, sulfonamides, salts thereof, and combinations thereof, and
(c) a liquid carrier,
wherein the polishing system has a pH of about 7 or less and does not contain a significant amount of cross-linked polymer abrasive particles that are electrostatically associated with the inorganic abrasive, and
(ii) abrading at least a portion of the silicon dioxide layer to polish the substrate.
2. The method of claim 1 , wherein the polishing additive bears a functional group with a pK a of about 3 to about 8.
3. The method of claim 1 , wherein the polishing additive is selected from the group consisting of aniline, anthranilic acid, orthanilic acid, salts thereof, and combinations thereof.
4. The method of claim 1 , wherein the polishing additive bears a functional group with a pK a of about 4 to about 9.
5. The method of claim 4 , wherein the inorganic abrasive has a positive zeta potential.
6. The method of claim 4 , wherein the polishing composition has a conductivity of about 2000 μS/cm or less.
7. The method of claim 4 , wherein the inorganic abrasive is fixed onto a polishing surface of a polishing pad.
8. The method of claim 4 , wherein the polishing system is colloidally stable over a period of at least 24 hours.
9. The method of claim 4 , wherein the polishing system further comprises a surfactant.
10. The method of claim 4 , wherein the polishing system has a pH of about 2 to about 6.5.
11. The method of claim 10 , wherein the polishing system has a pH of about 3.5 to about 5.5.
12. The method of claim 4 , wherein the inorganic abrasive is selected from the group consisting of alumina, ceria, silica, titania, chromia, zirconia, silicon carbide, boron nitride, magnesia, iron oxide, co-formed products thereof, and combinations thereof.
13. The method of claim 12 , wherein the inorganic abrasive is ceria.
14. The method of claim 4 , wherein the polishing system comprises about 2 wt. % or less inorganic abrasive.
15. The method of claim 14 , wherein the polishing system comprises about 0.5 wt. % or less inorganic abrasive.