Method of polishing a silicon-containing dielectric
View Patent ↗A chemical-mechanical polishing system comprising: (a) ceria abrasive having an average particle size of about 180 nm or less and a positive zeta potential, (b) a polishing additive bearing a functional group with a pK a of about 3 to about 9, wherein the polishing additive is selected from the group consisting of arylamines, aminoalcohols, aliphatic amines, heterocyclic amines, hydroxamic acids, aminocarboxylic acids, cyclic monocarboxylic acids, unsaturated monocarboxylic acids, substituted phenols, sulfonamides, thiols, salts thereof, and combinations thereof, and (c) a liquid carrier, wherein the chemical-mechanical polishing system has a pH of about 4 to about 6.
1. A chemical-mechanical polishing system comprising:
(a) ceria abrasive having an average primary particle size of about 180 nm or less,
(b) a polishing additive bearing a functional group with a pK a of about 4 to about 9, wherein the polishing additive is selected from the group consisting of arylamines, aminoalcohols, aliphatic amines, heterocyclic amines, hydroxamic acids, aminocarboxylic acids, cyclic monocarboxylic acids, unsaturated monocarboxylic acids, substituted phenols, sulfonamides, thiols, salts thereof, and combinations thereof, and
(c) a liquid carrier,
wherein the chemical-mechanical polishing system has a pH of about 4 to about 6.
2. A method of shallow trench isolation processing comprising (i) providing the chemical-mechanical polishing system of claim 1 , (ii) contacting a shallow trench isolation substrate comprising a silicon dioxide layer and a silicon nitride layer with the chemical-mechanical polishing system, and (iii) abrading at least a portion of the substrate to polish the substrate.
3. A method of polishing an interlayer dielectric device or premetal dielectric device comprising (i) providing the chemical-mechanical polishing system of claim 1 , (ii) contacting an interlayer dielectric layer with the chemical-mechanical polishing system, and (iii) abrading at least a portion of the interlayer dielectric layer to polishing the interlayer dielectric or premetal dielectric device.
4. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is selected from the group consisting of aniline and arylamines having one or more substituents selected from the group consisting of carboxylic acids, sulfonic acids, phosphonic acids, thiol groups, sulfonamides, salts thereof, and combinations thereof.
5. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive bears a functional group with a pK a of about 4 to about 7.
6. The method of claim 2 , wherein at least a portion of the silicon dioxide layer is abraded.
7. The method of claim 3 , wherein the interlayer dielectric layer comprises a silicon dioxide layer, and at least a portion of the silicon dioxide layer is abraded.
8. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is a heterocyclic amine.
9. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is selected from the group consisting of imidazole, quinoline, pyridine, 2-methylpyridine, pyridinedicarboxylic acids, 2-quinolinecarboxylic acid, morpholine, piperazine, triazoles, pyrrole, pyrrole-2-carboxylic acid, tetrazoles, salts thereof, and combinations thereof.
10. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is 2-pyridinecarboxylic acid.
11. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is an aminocarboxylic acid.
12. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is selected from the group consisting of glutamic acid, aspartic acid, histidine, salts thereof, and combinations thereof.
13. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is a cyclic monocarboxylic acid comprising a C 4-12 cyclic alkyl or C 6-12 aryl group.
14. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is selected from the group consisting of benzoic acid, cyclohexane carboxylic acid, cyclohexylacetic acid, 2-phenylacetic acid, salts thereof, and combinations thereof.
15. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is selected from the group consisting of unsaturated monocarboxylic acids, hydroxamic acids, and combinations thereof.
16. The chemical-mechanical polishing system of claim 1 , wherein the polishing additive is selected from the group consisting of substituted phenols, thiols, sulfonamides, and combinations thereof.
17. The method of claim 2 , wherein the polishing additive is 2-pyridinecarboxylic acid.
18. The method of claim 3 , wherein the polishing additive is 2-pyridinecarboxylic acid.
19. The method of claim 6 , wherein the polishing additive is 2-pyridinecarboxylic acid.
20. The method of claim 7 , wherein the polishing additive is 2-pyridinecarboxylic acid.
21. The chemical-mechanical polishing system of claim 1 , wherein the ceria abrasive has an average primary particle size of about 20 nm to about 180 nm.
22. The chemical-mechanical polishing system of claim 1 , wherein the ceria abrasive has an average primary particle size of about 50 nm to about 180 nm.
23. The chemical-mechanical polishing system of claim 1 , wherein the ceria abrasive is suspended in the liquid carrier in an amount of about 0.01 wt. % to about 10 wt. %.
24. The chemical-mechanical polishing system of claim 1 , wherein the ceria abrasive is suspended in the liquid carrier in an amount of about 0.05 wt. % to about 1 wt. %.
25. The chemical-mechanical polishing system of claim 22 , wherein the ceria abrasive is suspended in the liquid carrier in an amount of about 0.05 wt. % to about 1 wt. %.