IP Library Granted Patent US 11,384,253
Granted Patent B2
US 11,384,253 · App. 16/729,905 · Granted Jul 12, 2022

Dual additive composition for polishing memory hard disks exhibiting edge roll off

Inventor: Tong Li (Singapore, SG)
Assignee: CMC Materials, Inc.
C09G1/02C09K13/00H01L21/30625H01L21/3212C23F1/30C23F3/06G11B5/84
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Quick Facts
Patent No.
US 11,384,253
App. No.
16/729,905
Granted
Jul 12, 2022
Kind
B2
Abstract

The invention provides a chemical-mechanical polishing composition comprising (a) an abrasive comprising colloidal silica, (b) a compound of formula (I), (c) a compound of formula (II), (d) hydrogen peroxide, and (e) water, wherein the polishing composition has a pH of about 1 to about 5. The invention also provides a method of chemically-mechanically polishing a substrate, especially a nickel-phosphorous substrate, by contacting the substrate with the inventive chemical-mechanical polishing composition.

Claims (47)

1. A chemical-mechanical polishing composition comprising:

(a) an abrasive comprising colloidal silica,

(b) about 0.001 wt. % to about 1 wt. % of a compound of formula (I):

wherein R is

CH 2 ═CHCONHC(CH 3 ) 2 CH 2 —,

wherein X is independently O or a covalent bond,

or an alkali metal salt thereof,

(c) a compound of formula (II):

wherein R 9 is H or a hydroxyalkyl, and

wherein m is an integer of from 2 to about 6,

(d) hydrogen peroxide, and

(e) water,

wherein the polishing composition has a pH of about 1 to about 5.

2. The polishing composition of claim 1 , wherein the colloidal silica has an average particle size of about 10 nm to about 200 nm.

3. The polishing composition of claim 1 , wherein the abrasive further comprises fused silica.

4. The polishing composition of claim 3 , wherein the fused silica has an average particle size of about 100 nm to about 800 nm.

5. The polishing composition of claim 1 , wherein the compound of formula (I) is 2 acrylamido-2-methyl-1-propanesulfonic acid.

6. The polishing composition of claim 1 , wherein the compound of formula (II) is selected from ethylenediamine, 1,3-diaminopropane, and combinations thereof.

7. The polishing composition of claim 1 , wherein the polishing composition comprises about 0.001 wt. % to about 1 wt. % of the compound of formula (II).

8. The polishing composition of claim 1 , wherein the polishing composition comprises about 0.1 wt. % to about 10 wt. % of a combination of colloidal silica and fused silica.

9. A method of chemically mechanically polishing a substrate comprising:

(i) providing a substrate,

(ii) providing a polishing pad,

(iii) providing a chemical-mechanical polishing composition comprising:

(a) an abrasive comprising colloidal silica,

(b) about 0.001 wt. % to about 1 wt. % of a compound of formula (I):

wherein R is

CH 2 ═CHCONHC(CH 3 ) 2 CH 2 —,

wherein X is independently O or a covalent bond,

or an alkali metal salt thereof,

(c) a compound of formula (II):

wherein R 9 is H or a hydroxyalkyl, and

wherein m is an integer of from 2 to about 6,

(d) hydrogen peroxide, and

(e) water,

wherein the polishing composition has a pH of about 1 to about 5,

(iv) contacting the substrate with the polishing pad and the chemical-mechanical polishing composition, and

(v) moving the polishing pad and the chemical mechanical polishing composition relative to the substrate to abrade at least a portion of a surface of the substrate to thereby polish the substrate.

10. The method of claim 9 , wherein the colloidal silica has an average particle size of about 10 nm to about 200 nm.

11. The method of claim 9 , wherein the abrasive further comprises fused silica.

12. The method of claim 11 , wherein the fused silica has an average particle size of about 100 nm to about 800 nm.

13. The method of claim 9 , wherein the compound of formula (1) is 2 acrylamido-2-methyl-1-propanesulfonic acid.

14. The method of claim 9 , wherein the compound of formula (II) is selected from ethylenediamine, 1,3-diaminopropane, and combinations thereof.

15. The method of claim 9 , wherein the polishing composition comprises about 100 ppm to about 500 ppm of the compound of formula (I).

16. The method of claim 9 , wherein the polishing composition comprises about 100 ppm to about 2000 ppm of the compound of formula (II).

17. The method of claim 9 , wherein the polishing composition comprises about 0.1 wt. % to about 10 wt % of a combination of colloidal silica and fused silica.

18. The method of claim 9 , wherein the substrate is a nickel-phosphorous-coated aluminum memory disk, wherein the substrate comprises nickel-phosphorous on a surface of the substrate, and wherein at least a portion of the nickel-phosphorous on a surface of the substrate is abraded to polish the substrate.

Assignments (8)
CORRECTIVE ASSIGNMENT TO CORRECT THE PROPERTY PATENT NUMBERS 11/09380610/66679712/30921210/75515410/93190810/75313810/66037910/56872710/80707910/86939711/67013710/90142010/97446010/98248611/29485312/38426612/36425311/24113711/47802311/25964512/76426811/63457612/04301011/41236912/46206711/69912911/59553612/85447011/44820511/51790912/23417312/23423714/65759415/34683516/66423511/67351812/05297013/84612611/98692113/00411312/22102313/55482912/17095412/12673912/63028812/36493713/54612812/45563112/46263812/76218012/97171414/50908112/76101613/37991112/80732413/35133913/79968013/79992013/08785713/44462013/23788113/54655213/47753513/60659913/47829213/59494713/78433014/05097713/84134413/75441314/44020914/45945214/05072213/89884214/28972814/03503714/51572314/05112114/09492114/10033914/15620114/22271614/91952614/88183714/75027114/91949015/43306815/39409015/78494910/89719211/99821213/61213512/38170914/87417912/45654613/75716312/65713512/83290812/89546514/09965512/97912314/18389412/89547914/15279213/01463013/18439514/55012913/30684514/73249713/30684914/72758613/48814913/74713915/47977913/82999015/72388615/92081312/58434313/94744914/20362114/96516814/20364714/20369314/61625015/32732614/51556014/26962214/70058014/22208614/22273614/56831114/74992314/74994814/75005014/75010714/63956415/33872414/63959815/05619814/75020414/99383714/62708114/61273615/09127514/92499714/84906614/91940414/92505415/20797316/01828114/91944915/60363415/41478614/98889114/91875615/62948715/27385510/81007011/99819612/76771211/25154714/48917715/04277711/88482912/89552913/10182614/61099114/53053414/30784615/87577314/61106414/93173715/64937815/61559115/82530515/86472015/95135815/95159815/70619215/39893316/38909715/68447015/93421916/27150816/79743815/8179591797250916/51340417/00996116/92368816/13118016/20874216/20877916/20879716/00006216/23696216/86896516/82640916/84902116/72990517/60774317/58266718/103,13517/55746117/07698916/86875517/07707017/07715517/07729517/07741417/07748517/12329517/21709716/89571416/89576917/55741217/47454317/39167417/47869017/38494017/59261217/59227917/59229417/37927917/58453217/951,28863/409,07917/50342217/90221063/424,05217/89596718/110,63363/409,08618/210,42263/426,22863/415,14863/418,93129/337774 PREVIOUSLY RECORDED ON REEL 65663 FRAME 469. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Dec 12, 2023
From: CMC MATERIALS, INC.
To: CMC MATERIALS LLC
Reel/Frame 066848/0815 →
CHANGE OF NAME Recorded Nov 8, 2023
From: CMC MATERIALS, INC.
To: CMC MATERIALS LLC
Reel/Frame 065517/0783 →
SECURITY INTEREST Recorded Jul 8, 2022
From: ENTEGRIS, INC.; ENTEGRIS GP, INC.; POCO GRAPHITE, INC.; CMC MATERIALS, INC.; INTERNATIONAL TEST SOLUTIONS, LLC; QED TECHNOLOGIES INTERNATIONAL, INC.
To: TRUIST BANK, AS NOTES COLLATERAL AGENT
Reel/Frame 060613/0072 →
SECURITY INTEREST Recorded Jul 8, 2022
From: CMC MATERIALS, INC.; INTERNATIONAL TEST SOLUTIONS, LLC; QED TECHNOLOGIES INTERNATIONAL, INC.
To: MORGAN STANLEY SENIOR FUNDING, INC., AS COLLATERAL AGENT
Reel/Frame 060615/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 6, 2022
From: JPMORGAN CHASE BANK, N.A.
To: CABOT MICROELECTRONICS CORPORATION; QED TECHNOLOGIES INTERNATIONAL, INC.; FLOWCHEM LLC; KMG ELECTRONIC CHEMICALS, INC.; KMG-BERNUTH, INC.; MPOWER SPECIALTY CHEMICALS LLC; SEALWELD (USA), INC.; INTERNATIONAL TEST SOLUTIONS, LLC; CMC MATERIALS, INC.
Reel/Frame 060592/0260 →
SECURITY AGREEMENT Recorded Jul 2, 2021
From: CMC MATERIALS, INC.
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 056752/0645 →
CHANGE OF NAME Recorded Jan 13, 2021
From: CABOT MICROELECTRONICS CORPORATION
To: CMC MATERIALS, INC.
Reel/Frame 054980/0681 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 30, 2019
From: LI, TONG
To: CABOT MICROELECTRONICS CORPORATION
Reel/Frame 051385/0823 →