IP Library › Granted Patent US 12,227,631
Granted Patent B2
US 12,227,631 · App. 16/842,180 · Granted Feb 18, 2025

Cured product and production method of same, and resin sheet and resin composition

Inventor: Hiroyuki Sakauchi (Kawasaki, JP)
Assignee: Ajinomoto Co., Inc.
C08K9/06C08G59/4238C08K7/26C08L63/00H01L23/295H05K1/0373C08K2201/003C08L2205/035
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,227,631
App. No.
16/842,180
Granted
Feb 18, 2025
Kind
B2
Abstract

Cured products that are formed of a cured material obtained by curing a resin composition including (A) at least one epoxy resin, (B) at least one curing agent, and (C) at least one inorganic filler, and have a ground surface, in which the maximum depth of a depressed portion present on the ground surface is less than 10 μm are useful for making printed wiring boards.

Claims (68)

1. A cured product formed of a cured material obtained by curing a resin composition, comprising:

(A) at least one epoxy resin;

(B) at least one curing agent; and

(C) at least one inorganic filler,

wherein the cured product has a ground surface,

a maximum depth of a depressed portion present on the ground surface is less than 10 μm,

the cured material has a dielectric loss tangent of 0.008 or less measured at 60 GHZ,

the cured material has a tensile modulus of elasticity of 5 Gpa or more and 20 Gpa or less at 25° C.

the (C) inorganic filler has been subjected to a surface treatment with an amino silane compound,

the (C) inorganic filler includes a hollow filler particle having a hollow portion formed inside thereof, and

the hollow portion of the hollow filler particle included in said component (C) has a maximum long diameter of less than 5 μm.

2. The cured product according to claim 1 , wherein said component (B) comprises a phenol-based curing agent or an acid anhydride-based curing agent.

3. The cured product according to claim 1 , wherein said component (C) has an average particle diameter of 0.5 μm to 20 μm.

4. The cured product according to claim 1 , wherein

the ground surface includes a filler surface part formed by grinding of said component (C), and

a depressed portion having a depth of less than 10 μm is formed on the filler surface part.

5. The cured product according to claim 1 , wherein the cured product is for formation of a rewiring layer on the ground surface.

6. The cured product according to claim 1 , wherein the cured product is included in a structural body in combination with a connection terminal portion having a surface portion that is flush with the ground surface, and the cured product is for formation of a rewiring layer on the ground surface.

7. The cured product according to claim 1 , wherein the cured product is for formation of a rewiring layer after a thin film layer is formed on the ground surface.

8. A method for producing the cured product according to claim 1 , said method comprising:

(a) forming a resin composition layer of the resin composition;

(b) curing the resin composition to obtain a cured product; and

(c) grinding the cured product.

9. The cured product according to claim 1 , wherein the resin composition further comprises an (E) organic filler.

10. The cured product according to claim 1 , wherein the (C) inorganic filler further comprises alumina.

11. The cured product according to claim 1 , wherein the (A) epoxy resin comprises a combination of a liquid epoxy resin and a solid epoxy resin.

12. A resin sheet, comprising a support and a resin composition layer comprising a resin composition, said resin composition layer being provided on the support, wherein

said resin composition comprises:

(A) at least one epoxy resin;

(B) at least one curing agent; and

(C) at least one inorganic filler,

wherein

when said resin composition is cured at 180° C. for 1 hour, and then ground to form a ground surface having an arithmetic average roughness of 500 nm or less, a maximum depth of a depressed portion present on the ground surface is less than 10 μm,

when said resin composition is cured at 180° C. for 90 minutes to obtain a cured material, the cured material has a dielectric loss tangent of 0.008 or less measured at 60 GHZ,

the cured material has a tensile modulus of elasticity of 5 Gpa or more and 20 Gpa or less at 25° C., and

the (C) inorganic filler has been subjected to a surface treatment with an amino silane compound.

13. A resin composition, comprising:

(A) at least one epoxy resin;

(B) at least one curing agent; and

(C) at least one inorganic filler,

wherein said resin composition is a liquid resin composition,

wherein

when the resin composition is cured at 180° C. for 1 hour, and then ground to form a ground surface having an arithmetic average roughness of 500 nm or less, a maximum depth of a depressed portion present on the ground surface is less than 10 μm,

when said resin composition is cured at 180° C. for 90 minutes to obtain a cured material, the cured material has a dielectric loss tangent of 0.008 or less measured at 60 GHz,

the cured material has a tensile modulus of elasticity of 5 Gpa or more and 20 Gpa or less at 25° C., and

the (C) inorganic filler has been subjected to a surface treatment with an amino silane compound.

14. A resin composition for obtaining a cured product having a ground surface to form a rewiring layer thereon, wherein

the resin composition comprises:

(A) at least one epoxy resin;

(B) at least one curing agent; and

(C) at least one inorganic filler,

wherein

an average particle diameter of said component (C) is 0.5 μm to 20 μm,

said component (C) is treated with an amino silane compound,

said component (C) includes a hollow filler particle having a hollow portion formed inside thereof,

the hollow portion of the hollow filler particle included in said component (C) has a maximum long diameter of less than 5 μm,

when said resin composition is cured at 180° C. for 90 minutes to obtain a cured material, the cured material has a dielectric loss tangent of 0.008 or less measured at 60 GHZ, and

the cured material has a tensile modulus of elasticity of 5 Gpa or more and 20 Gpa or less at 25° C.

15. A cured product formed of a cured material obtained by curing a resin composition, comprising:

(A) at least one epoxy resin;

(B) at least one curing agent; and

(C) at least one inorganic filler,

wherein the cured product has a ground surface,

a maximum depth of a depressed portion present on the ground surface is less than 10 μm,

the cured material has a dielectric loss tangent of 0.008 or less measured at 60 GHZ,

the cured material has a tensile modulus of elasticity of 5 Gpa or more and 20 Gpa or less at 25° C.

the (C) inorganic filler has been subjected to a surface treatment with an amino silane compound, and

the cured product is included in a structural body in combination with a connection terminal portion having a surface portion that is flush with the ground surface, and the cured product is for formation of a rewiring layer on the ground surface.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 12, 2020
From: SAKAUCHI, HIROYUKI
To: AJINOMOTO CO., INC.
Reel/Frame 052927/0982 →
Priority Claims (1)
JP 2017-197132 · Oct 10, 2017 · national
Continuity (2)
Continuation PCTJP2018034632 · Sep 19, 2018
Related Publication 20200231786A1 · Jul 23, 2020
References Cited (42)
US 5461090A · Sweet · 1995 [cited by examiner]
US 20020082349A1 · Takahashi et al. · 2002 [cited by applicant]
US 20030216505A1 · Akiba · 2003 [cited by examiner]
US 20060223913A1 · Osada · 2006 [cited by examiner]
US 20090247032A1 · Mori · 2009 [cited by examiner]
US 20120123021A1 · Yano et al. · 2012 [cited by applicant]
US 20160244605A1 · Kim et al. · 2016 [cited by applicant]
US 20190284395A1 · Kasahara · 2019 [cited by examiner]
US 20200172724A1 · Fujii · 2020 [cited by examiner]
CN 106916400A · 2017 [cited by applicant]
JP 2000212759 · 2000 [cited by applicant]
JP 2001019834 · 2001 [cited by applicant]
JP 2001098174 · 2001 [cited by applicant]
JP 200346247A · 2003 [cited by applicant]
JP 2006093618 · 2006 [cited by applicant]
JP 2007056158 · 2007 [cited by applicant]
JP 2007161518 · 2007 [cited by applicant]
JP 2011021068 · 2011 [cited by applicant]
JP 2011021101 · 2011 [cited by applicant]
JP 2011225756 · 2011 [cited by applicant]
JP 2011225799A · 2011 [cited by applicant]
JP 2012057003 · 2012 [cited by applicant]
JP 2012074606 · 2012 [cited by applicant]
JP 2012136693 · 2012 [cited by applicant]
JP 2012167256 · 2012 [cited by applicant]
JP 2013077726A · 2013 [cited by examiner]
JP 2013115171A · 2013 [cited by applicant]
JP 2013173841 · 2013 [cited by applicant]
JP 2014015606 · 2014 [cited by applicant]
JP 201775221A · 2017 [cited by applicant]
JP 2017082201 · 2017 [cited by applicant]
JP 2017114687A · 2017 [cited by applicant]
TW 201731947A · 2017 [cited by applicant]
WO WO2018097010A1 · 2018 [cited by examiner]
WO WO2018225599A1 · 2018 [cited by applicant]
Partial machine translation of WO-2018097010-A1 (2018). [cited by examiner]
Partial machine translation of JP-2013077726-A (Year: 2013). [cited by examiner]
Combined Chinese Office Action and Search Report issued May 6, 2022 in Chinese Patent Application No. 201880065943.9 (with unedited computer generated English translation), 20 pages. [cited by applicant]
Japanese Office Action issued Mar. 8, 2022 in Japanese Patent Application No. 2019-547964 (with English translation), 6 pages. [cited by applicant]
International Search Report issued in Application No. PCT/JP2018/034632 issued Dec. 18, 2018. [cited by applicant]
Office Action issued Jun. 6, 2023, in corresponding Japanese Patent Application No. 2022-129399 (with English Translation), 6 pages. [cited by applicant]
Taiwanese Office Action issued on Jan. 15, 2024 in Taiwanese Patent Application No. 111136324 (with English translation), 17 pages. [cited by applicant]