Water-soluble packets
The disclosure provides a water soluble pouch including at least two sealed compartments, the pouch including outer walls including water soluble film including a water soluble resin, and an inner wall including water soluble film including a water soluble resin, the outer wall films being sealed to the inner wall film, the outer wall films being characterized by: a dissolution time of 300 seconds or less, the water soluble resin of the outer wall films having a viscosity in a range of 14.5 cP to 25 cP, and a pouch strength of at least 200 N, and the inner wall film being characterized by: a dissolution time of 300 seconds or less, the water soluble resin of the inner film having viscosity in a range of 12 cP to 14.5 cP, and a tackiness value of at least 1500 g/s.
1. A water soluble pouch comprising a sealed compartment, the pouch comprising
a first wall comprising a water soluble film comprising a water soluble resin;
and a second wall comprising a water soluble film comprising a water soluble resin;
the first wall film being sealed to the second wall film;
the first wall film being characterized by
a dissolution time of 300 seconds or less in water at a temperature of 20° C. for a first wall film having a thickness of about 76 micron in accordance with MonoSol Test Method MSTM-205;
the water soluble resin of the first wall film having a 4% solution viscosity at 20° C. in a range of 14.5 cP to 25 cP; and
a pouch strength of at least 200 N as measured by the first wall film sealed and tested according to the Pouch Strength Test; and
the second wall film being characterized by:
a dissolution time of 300 seconds or less in water at a temperature of 20° C. for a second wall film having a thickness of about 76 micron in accordance with MonoSol Test Method MSTM-205;
the water soluble resin of the second film having a 4% solution viscosity at 20° C. in a range of 12 cP to 14.5 cP; and
a tackiness value of at least 1500 g/s for a second film tested according to the Tackiness PA Test
wherein the water soluble resin of the first wall film comprises a blend of a polyvinyl alcohol homopolymer and a polyvinyl alcohol copolymer comprising an anionic monomer unit;
wherein the blend in the water soluble resin of the first wall film comprises from about 30 to 70 weight percent of the polyvinyl alcohol copolymer comprising an anionic monomer unit and from 30 to 70 weight percent of the polyvinyl alcohol homopolymer, based on the total weight of polyvinyl alcohol in the film;
wherein the first wall film is characterized by a pouch strength of less than 2000 N as measured by the first wall film sealed and tested according to the Pouch Strength Test;
wherein the water soluble resin of the second wall film comprises a blend of a polyvinyl alcohol homopolymer and a polyvinyl alcohol copolymer comprising an anionic monomer unit; and
wherein the pouch has a pouch strength of at least 200 N as measured by the Pouch Strength Test.
2. The water soluble pouch of claim 1 , wherein the anionic monomer unit of one or both of the films is selected from the group consisting of vinyl acetic acid, alkyl acrylates, maleic acid, monoalkyl maleate, dialkyl maleate, monomethyl maleate, dimethyl maleate, maleic anhydride, fumaric acid, monoalkyl fumarate, dialkyl fumarate, monomethyl fumarate, dimethyl fumarate, fumaric anhydride, itaconic acid, monomethyl itaconate, dimethyl itaconate, itaconic anhydride, citraconic acid, monoalkyl citraconate, dialkyl citraconate, citraconic anhydride, mesaconic acid, monoalkyl mesaconate, dialkyl mesaconate, mesaconic anhydride, glutaconic acid, monoalkyl glutaconate, dialkyl glutaconate, glutaconic anhydride, vinyl sulfonic acid, alkyl sulfonic acid, ethylene sulfonic acid, 2-acrylamido-1-methyl propane sulfonic acid, 2-acrylamide-2-methylpropanesulfonic acid, 2-methylacrylamido-2-methylpropanesulfonic acid, 2-sulfoethyl acrylate, alkali metal salts of the foregoing, esters of the foregoing, and combinations of the foregoing.
3. The water soluble pouch of claim 2 , wherein the anionic monomer unit of one or both of the films comprises one or more of maleic acid, monoalkyl maleate, dialkyl maleate maleic anhydride, alkali metal salts of the foregoing and combinations thereof.
4. The water soluble pouch of claim 2 , wherein the anionic monomer of one or both of the films is selected from the group consisting of maleic acid, monomethyl maleate, dimethyl maleate, maleic anhydride, alkali metal salts of the foregoing, esters of the foregoing, and combinations thereof.
5. The water soluble pouch of claim 1 , wherein the blend of one or both of the films comprises at least 65 weight percent of the polyvinyl alcohol copolymer comprising an anionic monomer based on the total weight of polyvinyl alcohol in the film.
6. The water soluble pouch of claim 1 , wherein the polyvinyl alcohol copolymer of one or both of the films comprises from 2 to 8 mol % of the anionic monomer unit.
7. The water soluble pouch of claim 1 , wherein the water soluble resin of one or both of the films comprises a degree of hydrolysis in a range of 87 to 93.
8. The water soluble pouch of claim 1 , wherein the water soluble resin of the first wall film has a 4% solution viscosity at 20° C. in a range of 14.5 cP to 21 cP.
9. The water soluble pouch of claim 1 , wherein one or both of the films further comprise a plasticizer.
10. The water soluble pouch of claim 9 , wherein the plasticizer is selected from the group consisting of glycerin, trimethylol propane, sorbitol, and combinations thereof.
11. The water soluble pouch of claim 1 , wherein one or both of the films further comprises a surfactant.
12. The water soluble pouch of claim 11 , wherein the surfactant is selected from the group consisting of polyoxyethylenated polyoxypropylene glycols, alcohol ethoxylates, alkylphenol ethoxylates, tertiary acetylenic glycols and alkanolamides, polyoxyethylenated amines, quaternary ammonium salts and quaternized polyoxyethylenated amines, and amine oxides, N-alkylbetaines, sulfobetaines, and combinations thereof.
13. The water soluble pouch of claim 1 , wherein the first wall film further comprises an aversive agent.
14. The water soluble pouch of claim 1 , wherein the thickness of the first wall film does not vary from the thickness of the second wall film by more than 10% for non-thermoformed films.
15. The water soluble pouch of claim 1 , wherein a composition is enclosed in the pouch.
16. The water soluble pouch of claim 15 , wherein the composition is a liquid.
17. The water soluble pouch of claim 15 , wherein the liquid composition is not a fabric or household care composition.
18. The water soluble pouch of claim 17 , wherein the liquid composition comprises a composition selected from the group consisting of agricultural compositions, aviation compositions, food and nutritive compositions, industrial compositions, livestock compositions, marine compositions, medical compositions, mercantile compositions, military and quasi-military compositions, office compositions, recreational and park compositions, pet compositions, water-treatment compositions, and combinations thereof.
19. The water soluble pouch of claim 1 , wherein the first wall water soluble resin is not the same as the second wall water soluble resin.
20. The water soluble pouch of claim 1 , wherein the pouch has a pouch strength of at least 300 N as measured by the Pouch Strength Test.
21. A water soluble pouch comprising a sealed compartment, the pouch comprising,
a first wall comprising a water soluble film comprising a water soluble resin comprising a blend of one or more polyvinyl alcohol homopolymers and a polyvinyl alcohol copolymer comprising an anionic monomer unit selected from the group consisting of, monomethyl maleate, dimethyl maleate, alkali metal salts of the foregoing, esters of the foregoing, and combinations thereof, wherein the blend comprises from about 30 to 70 weight percent of the polyvinyl alcohol copolymer comprising the anionic monomer unit and from 30 to 70 weight percent of the one or more polyvinyl alcohol homopolymers, based on the total weight of polyvinyl alcohol in the film, the water soluble film comprising a plasticizer and a surfactant;
the first wall film being characterized by:
a dissolution time of 300 seconds or less in water at a temperature of 20° C. for a first wall film having a thickness of about 76 micron in accordance with MonoSol Test Method MSTM-205;
the water soluble resin of the first wall film having a 4% solution viscosity at 20° C. in a range of 14.5 cP to 25 cP; and
a pouch strength of at least 200 N and less than 2000 N as measured by the first wall film sealed and tested according to the Pouch Strength Test;
and a second wall comprising a water soluble film comprising a water soluble resin comprising a blend of a polyvinyl alcohol homopolymer and polyvinyl alcohol copolymer; and the second wall film comprises a plasticizer and a surfactant;
the second wall film being characterized by:
a dissolution time of 300 seconds or less in water at a temperature of 20° C. for a second wall film having a thickness of about 76 micron in accordance with MonoSol Test Method MSTM-205;
the first wall film being sealed to the second wall film, a composition being enclosed in the pouch, and the pouch has a pouch strength of at least 200 N as measured by the Pouch Strength Test.
22. The water soluble pouch of claim 21 , wherein the water soluble resin of the first wall water soluble film comprises at least 65 weight percent by weight of the copolymer comprising an anionic monomer based on the total weight of polyvinyl alcohol resin and wherein the composition is a fabric or household care composition.
23. The water soluble pouch of claim 21 , wherein the first wall film is an outer film of the pouch, the pouch further comprises an additional outer film, and the second wall film is an inner film of the pouch, and wherein the composition is not a fabric or household care composition.