Granted Patent B2

US 12,351,730 · App. 17/625,291 · Granted Jul 8, 2025

Inventors: Yohei Yamaguchi (Otsu, JP); Kokichi Tokuo (Otsu, JP); Shotaro Nishio (Tsuruga, JP); Kiwamu Kawai (Tsuruga, JP)

Assignee: TOYOBO CO., LTD.

C09D167/02C09D7/61C09D7/63G02B1/14C08K2003/2241C08K2003/2244

Abstract

Claims (25)

1. A hard coating film for a foldable display, the hard coating film comprising

a polyester film being a polyethylene terephthalate film and having a thickness of 10 to 80 μm and a draw ratio of 1.2-fold to 2.0-fold in the longitudinal direction,

an easy-to-adhere resin layer, and

a hard coating layer, the easy-to-adhere resin layer and the hard coating layer being stacked in this order on at least one surface of the polyester film,

wherein

the easy-to-adhere resin layer is a cured product of a composition containing

at least one compound selected from the group consisting of titanium compounds and zirconium compounds, and

a polyester resin, which is formed from a dicarboxylic acid component and a diol component, containing a naphthalene dicarboxylic acid component as at least part of the dicarboxylic acid component, and

the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon satisfies the following conditions (1) to (4):

(1) the polyester film has a refractive index in the bending direction of 1.590 to 1.620,

(2) the polyester film has a refractive index in the direction of a folding portion of 1.670 to 1.700,

(3) the polyester film has a refractive index in the thickness direction of 1.520 or less, and

(4) the polyester film has a density of 1.380 g/cm 3 or more,

wherein the bending direction refers to a direction orthogonal to the folding portion of the polyester film to be folded.

2. The hard coating film for a foldable display according to claim 1 , wherein the easy-to-adhere resin layer has a refractive index lower than the refractive index in the bending direction and the refractive index in the direction of the folding portion of the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon, and the easy-to-adhere resin layer has a refractive index higher than the refractive index of the hard coating layer.

3. The hard coating film for a foldable display according to claim 1 , wherein the easy-to-adhere resin layer has a refractive index that satisfies the following conditions (5) and (6):

(5) the easy-to-adhere resin layer has a refractive index lower than the refractive index in the bending direction of the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon, and the difference in refractive index is more than 0 and 0.07 or less, and

(6) the easy-to-adhere resin layer has a refractive index lower than the refractive index in the direction of the folding portion of the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon, and the difference in refractive index is 0.080 or more and 0.150 or less.

4. The hard coating film for a foldable display according to claim 1 , wherein the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon has a total light transmittance of 85% or more, a haze of 3% or less, and a maximum heat shrinkage of 6% or less.

5. The hard coating film for a foldable display according to claim 1 , wherein the hard coating layer has a thickness of 1 to 50 μm.

6. A foldable display comprising the hard coating film for a foldable display of claim 5 ,

wherein

the hard coating film is disposed as a surface protection film such that the hard coating layer becomes the front surface, and

the hard coating film is a single continuous film placed through the folding portion of the foldable display.

7. A mobile device comprising the foldable display of claim 6 .

Assignments (1)

Priority Claims (1)

Continuity (1)

References Cited (273)