IP Library › Granted Patent US 12,480,435
Granted Patent B2
US 12,480,435 · App. 18/313,603 · Granted Nov 25, 2025

Systems, apparatus, and methods for inducing enhanced radical ignition in internal combustion engines using a radical chemicals generator

Inventors: Michael J. Manfredi (Vienna, VA); Daniel B. Olsen (Fort Collins, CO); Randall R. Raymer (Howard, OH); Michael P. Whelan (Naperville, IL)
Assignee: Radical Combustion Technologies, LLC
F02B19/12F02B19/18
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Quick Facts
Patent No.
US 12,480,435
App. No.
18/313,603
Granted
Nov 25, 2025
Kind
B2
Abstract

Systems, devices, and methods described herein provide one or more radical chemicals generators (RCGs) and/or mini-chambers (M-Cs) that can be used to provide enhanced radical ignition (ERI) in an internal combustion engine. RCGs as described herein can include quenching systems (QSs) that can be configured to quench a flame of combustion products to produce a jet of partial combustion products containing radical species (RS). The jet of partial combustion products can be injected to a main combustion chamber (MCC) of an engine to induce ERI. ERI can proceed under leaner fuel conditions and lower temperatures compared to those needed for conventional thermally induced, fuel oxidation chain initiation reaction processes.

Claims (43)

1 . An apparatus, comprising:

a housing defining a radical chemicals generator volume (RCGv);

a fuel delivery control device coupled to a passageway extending into the RCGv, the fuel delivery control device configured to control delivery of a portion of fuel into the RCGv via the passageway;

a spark device configured to ignite a mixture of air and the portion of fuel in the RCGv to generate a flame that produces combustion intermediates and combustion products; and

a quenching system (QS) including a plurality of orifices, the plurality of orifices having a predetermined length-to-diameter ratio of at least five such that the plurality of orifices is configured to quench the flame to produce a jet of partial combustion products containing radical species (RS),

the plurality of orifices further configured to inject the jet of partial combustion products into a main combustion chamber (MCC) of an engine containing a fuel-air charge to induce ignition of the fuel-air charge.

2 . The apparatus of claim 1 , wherein the predetermined length-to-diameter ratio of the plurality of orifices is at least ten.

3 . The apparatus of claim 1 , wherein each orifice from the plurality of orifices has a circular cross-sectional area with a cross-sectional diameter of between 0.5 mm and 5 mm.

4 . The apparatus of claim 1 , wherein each orifice from the plurality of orifices has a length of at least 10 mm.

5 . The apparatus of claim 1 , wherein the housing is configured to attach to the engine such that a longitudinal axis of the QS is angled relative to a centerline of the engine.

6 . The apparatus of claim 5 , wherein each orifice from the plurality of orifices has an end opening into the MCC that is angled with respect to the longitudinal axis of the QS.

7 . The apparatus of claim 1 , wherein each orifice set from the plurality of orifice sets includes a section that extends along a longitudinal axis of the QS toward a centerline of the engine, such that the jet of the partial combustion products can penetrate across the MCC when injected into the MCC.

8 . The apparatus of claim 1 , wherein the housing further includes a coolant jacket configured to cool the RCGv.

9 . The apparatus of claim 1 , wherein the housing further includes a threaded surface configured to attach to a threaded opening in a head of the engine.

10 . The apparatus of claim 1 , wherein the RS include at least one of: a hydroxyl radical (OH), a hydroperoxyl radical or perhydroxyl radical (HO2), formaldehyde (CH2O), hydrogen peroxide (H2O2), methyl radical (CH3), methylidyne radical (CH), monotomic oxygen radical (O), or monotomic hydrogen radical (H).

11 . The apparatus of claim 1 , further comprising a sleeve configured to fit within an opening in a head of the engine and to attach to the head of the engine, the sleeve defining an opening for receiving the housing.

12 . The apparatus of claim 1 , wherein the housing is configured to attach to the engine such that a longitudinal axis of the QS is angled relative to a centerline of the engine.

13 . The apparatus of claim 1 , wherein a first radical chemical generator (RCG) includes the housing, the fuel delivery control device, the spark device, and the QS, the apparatus further comprising a second RCG, each of the first and second RCGs configured to couple to a different opening in a head of the engine.

14 . The apparatus of claim 13 , wherein the second RCG includes a QS, the QSs of the first and second RCGs configured to inject jets of partial combustion products into the MCC of the engine at the same time to induce ignition of the fuel-air charge in the MCC.

15 . The apparatus of claim 14 , wherein the jets of partial combustion products are angled or offset from one another to avoid overlapping with one another and to increase volumetric distribution of RS within the MCC.

16 . The apparatus of claim 13 , wherein the QS of the second RCG is configured to inject a first set of jets of partial combustion products into the MCC before the QS of the first RCG injects a second set of partial combustion products into the MCC.

17 . The apparatus of claim 16 , wherein the QS of the second RCG is configured to inject the first set of jets of partial combustion products into the MCC to increase a quantity of RS in the MCC, and the QS of the first RCG is configured to inject the second set of jets of partial combustion products into the MCC to induce ignition of the fuel-air charge in the MCC.

18 . The apparatus of claim 13 , further comprising a plurality of mini-chambers (M-Cs) configured to:

receive a portion of gases from the MCC during a combustion event or a compression phase of a first combustion cycle from a plurality of combustion cycles;

allow generation and storage of RS in the portion of gases; and

release the portion of gases including the generated RS into the MCC during a second combustion cycle from the plurality of combustion cycles immediately subsequent to the first combustion cycle.

19 . An apparatus, comprising:

a housing defining a radical chemicals generator volume (RCGv);

a fuel delivery control device coupled to a passageway extending into the RCGv, the fuel delivery control device configured to control delivery of a portion of fuel into the RCGv via the passageway;

a spark device configured to ignite a mixture of air and the portion of fuel in the RCGv to generate a flame that produces combustion intermediates and combustion products; and

a quenching system (QS) coupled to a head of an engine, the QS including a plurality of orifices, the plurality of orifices having a predetermined length-to-diameter ratio of at least three such that the plurality of orifices is configured to quench the flame to produce a jet of partial combustion products containing radical species (RS),

the plurality of orifices further configured to inject the jet of partial combustion products into a main combustion chamber (MCC) of the engine containing a fuel-air charge to induce ignition of the fuel-air charge.

20 . The apparatus of claim 19 , wherein the predetermined length-to-diameter ratio of the plurality of orifices is at least ten.

21 . The apparatus of claim 19 , wherein each orifice from the plurality of orifices has a circular cross-sectional area with a cross-sectional diameter of between 0.5 mm and 5 mm.

22 . The apparatus of claim 19 , wherein the housing is configured to attach to the engine such that a longitudinal axis of the QS is angled relative to a centerline of the engine.

23 . The apparatus of claim 22 , wherein each orifice from the plurality of orifices has an end opening into the MCC that is angled with respect to the longitudinal axis of the QS.

24 . The apparatus of claim 19 , wherein each orifice set from the plurality of orifice sets includes a section that extends along a longitudinal axis of the QS toward a centerline of the engine, such that the jet of the partial combustion products can penetrate across the MCC when injected into the MCC.

25 . The apparatus of claim 19 , wherein the housing further includes a coolant jacket configured to cool the RCGv.

26 . The apparatus of claim 19 , wherein the housing further includes a threaded surface configured to attach to a threaded opening in the head of the engine.

27 . The apparatus of claim 19 , wherein the RS include at least one of: a hydroxyl radical (OH), a hydroperoxyl radical or perhydroxyl radical (HO2), formaldehyde (CH2O), hydrogen peroxide (H2O2), methyl radical (CH3), methylidyne radical (CH), monotomic oxygen radical (O), or monotomic hydrogen radical (H).

28 . The apparatus of claim 19 , further comprising a sleeve configured to fit within an opening in the head of the engine and to attach to the head of the engine, the sleeve defining an opening for receiving the housing.

29 . The apparatus of claim 19 , wherein the housing is configured to attach to the engine such that a longitudinal axis of the QS is angled relative to a centerline of the engine.

30 . The apparatus of claim 19 , wherein a first radical chemical generator (RCG) includes the housing, the fuel delivery control device, the spark device, and the QS, the apparatus further comprising a second RCG, each of the first and second RCGs configured to couple to a different opening in a head of the engine.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 7, 2023
From: MANFREDI, MICHAEL J.; OLSEN, DANIEL B.; RAYMER, RANDALL R.; WHELAN, MICHAEL P.
To: RADICAL COMBUSTION TECHNOLOGIES, LLC
Reel/Frame 065792/0962 →
Continuity (5)
Division 17962660 · Oct 10, 2022
Division 17680074 · Feb 24, 2022
Continuation In Part PCTUS2021013624 · Jan 15, 2021
Provisional Application 62961515 · Jan 15, 2020
Related Publication 20240044282A1 · Feb 8, 2024
References Cited (95)
US 3820523A · Showalter et al. · 1974 [cited by applicant]
US 4404931A · Smith et al. · 1983 [cited by applicant]
US 4594976A · Gonzalez · 1986 [cited by applicant]
US 4711208A · Sander et al. · 1987 [cited by applicant]
US 4738227A · Kamo et al. · 1988 [cited by applicant]
US 4765293A · Gonzalez · 1988 [cited by applicant]
US 4798770A · Donomoto et al. · 1989 [cited by applicant]
US 4862865A · Dahlen et al. · 1989 [cited by applicant]
US 5146883A · Reipert et al. · 1992 [cited by applicant]
US 5186137A · Salzmann · 1993 [cited by applicant]
US 5211145A · Ichikawa et al. · 1993 [cited by applicant]
US 5307772A · Rao et al. · 1994 [cited by applicant]
US 5322042A · di Priolo et al. · 1994 [cited by applicant]
US 5417059A · Hartel et al. · 1995 [cited by applicant]
US 5611307A · Watson · 1997 [cited by applicant]
US 5662082A · Black et al. · 1997 [cited by applicant]
US 5778849A · Regueiro · 1998 [cited by applicant]
US 5855192A · McCowan et al. · 1999 [cited by applicant]
US 5862788A · Pouring et al. · 1999 [cited by applicant]
US 5915351A · Regueiro · 1999 [cited by applicant]
US 6178942B1 · di Priolo et al. · 2001 [cited by applicant]
US 7055491B2 · Linderyd et al. · 2006 [cited by applicant]
US 7451942B2 · Borissov · 2008 [cited by applicant]
US 7493886B2 · Blank · 2009 [cited by applicant]
US 7832372B2 · Blank · 2010 [cited by applicant]
US 8567369B2 · Johnson · 2013 [cited by applicant]
US 8844498B2 · Patterson · 2014 [cited by applicant]
US 8857405B2 · Attard · 2014 [cited by applicant]
US 8875678B2 · Johnson · 2014 [cited by applicant]
US 9010293B2 · Blank · 2015 [cited by applicant]
US 9353674B2 · Bunce et al. · 2016 [cited by applicant]
US 9567896B2 · Pouring et al. · 2017 [cited by applicant]
US 9567939B2 · Pouring et al. · 2017 [cited by applicant]
US 9631591B2 · Patterson · 2017 [cited by applicant]
US 9638093B2 · Blank · 2017 [cited by applicant]
US 9670827B2 · Taliaferro · 2017 [cited by applicant]
US 9677459B2 · Mcclendon et al. · 2017 [cited by applicant]
US 10941727B2 · Suzuki et al. · 2021 [cited by applicant]
US 10961899B2 · Suzuki · 2021 [cited by applicant]
US 11466608B2 · Manfredi et al. · 2022 [cited by applicant]
US 20030196547A1 · Bischofberger et al. · 2003 [cited by applicant]
US 20060144362A1 · Robinet et al. · 2006 [cited by applicant]
US 20100043430A1 · Dehart · 2010 [cited by applicant]
US 20100077986A1 · Chen · 2010 [cited by applicant]
US 20100257848A1 · Birkby · 2010 [cited by applicant]
US 20110088655A1 · Ancimer et al. · 2011 [cited by applicant]
US 20110108012A1 · Bryant et al. · 2011 [cited by applicant]
US 20120082841A1 · Kadoshima et al. · 2012 [cited by applicant]
US 20120103302A1 · Attard · 2012 [cited by applicant]
US 20120118262A1 · Johnson · 2012 [cited by applicant]
US 20140026846A1 · Johnson · 2014 [cited by applicant]
US 20140209057A1 · Pouring et al. · 2014 [cited by applicant]
US 20150068489A1 · Bunce et al. · 2015 [cited by applicant]
US 20150198070A1 · Record et al. · 2015 [cited by applicant]
US 20150204233A1 · Nanba et al. · 2015 [cited by applicant]
US 20150247445A1 · Blank · 2015 [cited by applicant]
US 20160025035A1 · Kadoshima et al. · 2016 [cited by applicant]
US 20160053670A1 · Tozzi et al. · 2016 [cited by applicant]
US 20160053671A1 · Sotiropoulou et al. · 2016 [cited by applicant]
US 20160053673A1 · Sotiropoulou · 2016 [cited by examiner]
US 20160169185A1 · Iwasaki et al. · 2016 [cited by applicant]
US 20160230645A1 · Schock et al. · 2016 [cited by applicant]
US 20170138251A1 · Watanabe et al. · 2017 [cited by applicant]
US 20170145900A1 · Singh · 2017 [cited by applicant]
US 20170218878A1 · Hussain · 2017 [cited by applicant]
US 20170284334A1 · Lineton et al. · 2017 [cited by applicant]
US 20170314456A1 · Blaxill et al. · 2017 [cited by applicant]
US 20180094603A1 · Taguchi et al. · 2018 [cited by applicant]
US 20180128166A1 · Lineton · 2018 [cited by applicant]
US 20190032544A1 · Vattaneo · 2019 [cited by examiner]
US 20190195120A1 · Suzuki · 2019 [cited by applicant]
US 20210131336A1 · Raymer et al. · 2021 [cited by applicant]
US 20220112834A1 · Cambal · 2022 [cited by applicant]
US 20220178300A1 · Manfredi et al. · 2022 [cited by applicant]
US 20230042331A1 · Manfredi et al. · 2023 [cited by applicant]
CA 2049400C · 1995 [cited by applicant]
CA 3168145A1 · 2021 [cited by applicant]
DE 202019105016U1 · 2019 [cited by applicant]
EP 3181855A1 · 2017 [cited by applicant]
WO WO0058610A1 · 2000 [cited by applicant]
WO WO2004106728A1 · 2004 [cited by applicant]
WO WO2019040432A1 · 2019 [cited by applicant]
WO WO2020014636A1 · 2020 [cited by applicant]
WO WO2021146550A1 · 2021 [cited by applicant]
WO WO2024076879A2 · 2024 [cited by applicant]
International preliminary report on patentability for PCT Application No. PCT/US2023/063248 mailed Sep. 6, 2024, 15 pages. [cited by applicant]
Office Action for European Application No. 21705716.5 mailed Apr. 23, 2024, 4 pages. [cited by applicant]
International Search Report and Written Opinion for International Application No. PCT/US2021/013624 dated Apr. 1, 2021, 10 pages. [cited by applicant]
International Search Report and Written Opinion for PCT Application No. PCT/US2023/063248 dated Jul. 28, 2023, 22 pages. [cited by applicant]
International Search Report and Written Opinion mailed on Nov. 6, 2019, for International Application No. PCT/US2019/041646, 11 pages. [cited by applicant]
Invitation to Pay Additional Fees for International Application No. PCT/US2023/063248 dated Jun. 7, 2023, 18 pages. [cited by applicant]
Notice of Allowance for U.S. Appl. No. 17/962,660 mailed Feb. 6, 2023, 7 pages. [cited by applicant]
Olsen et al., “Prechamber NOx formation in low BMEP 2-stroke cycle natural gas engines,” Applied Thermal Engineering, vol. 29, Issue 4, 2009, pp. 687-694. [cited by applicant]
Walker, “Free Radicals in Combustion Chemistry,” Science Progress, vol. 74, No. 2 (294), 1990, pp. 163-187. [cited by applicant]
Office Action for Mexican Application No. MX/a/2022/008696 mailed Sep. 4, 2025, with English translation, 14 pages. [cited by applicant]