Granted Patent B2

US 12,548,760 · App. 18/370,255 · Granted Feb 10, 2026

Inventors: Benjamin Yong Park (Mission Viejo, CA); Jill R. Pestana (Huntington Beach, CA); Xiaohua Liu (Irvine, CA); Frederic Bonhomme (Foothill Ranch, CA)

Assignee: ENEVATE CORPORATION

H01M4/134C01B33/021H01M4/0471H01M4/386H01M4/625H01M10/0525H01M10/0562H01M2004/027H01M2004/028

Abstract

Claims (38)

1 . An electrode for a battery, the electrode comprising:

a current collector; and

an active material layer on the current collector, the active material layer comprising a carbon structure and silicon particles;

wherein the carbon structure holds the silicon particles of the active material layer together; and

wherein, one or more of the silicon particles, each comprises:

a concentration of aluminum in an outer region of the respective silicon particle that differs from a concentration of aluminum in an inner region of the respective silicon particle; and

a coating layer that coats an outer surface of the respective silicon particle.

2 . The electrode of claim 1 , wherein the coating layer of the respective silicon particle comprises silicon carbide.

3 . The electrode of claim 1 , wherein the coating layer of the respective silicon particle comprises carbon and silicon carbide.

4 . The electrode of claim 1 , wherein the coating layer of the respective silicon particle comprises carbon, silicon carbide, and one or more silicon oxides.

5 . The electrode of claim 1 , wherein the coating layer is configured to constrain outward expansion of its respective silicon particle during lithiation.

6 . The electrode of claim 1 , wherein the coating layer provides its respective silicon particle with an expansion buffer.

7 . The electrode of claim 1 , wherein the coating layer is continuous and conformal to its respective silicon particle.

8 . The electrode of claim 1 , wherein the carbon structure comprises one or more types of carbon phases that are electrochemically active.

9 . The electrode of claim 1 , wherein the carbon structure comprises one or more types of carbon phases that are electrically conductive.

10 . The electrode of claim 1 , wherein, at least 50% of the silicon particles, each comprise the coating layer that coats the outer surface of the respective silicon particle.

11 . The electrode of claim 1 , wherein, at least 70% of the silicon particles, each comprise the coating layer that coats the outer surface of the respective silicon particle.

12 . The electrode of claim 1 , wherein, at least 90% of the silicon particles, each comprise the coating layer that coats the outer surface of the respective silicon particle.

13 . The electrode of claim 1 , wherein the concentration of aluminum in the outer region of the respective silicon particle is greater than the concentration of aluminum in the inner region of the respective silicon particle.

14 . The electrode of claim 1 , wherein the silicon particles are distributed throughout the carbon structure.

15 . An electrochemical cell, comprising:

a first electrode;

a second electrode; and

a separator between the first electrode and the second electrode;

wherein the first electrode comprises a current collector and an active material layer on the current collector;

wherein the active material layer comprises a carbon structure and silicon particles distributed throughout the carbon structure; and

wherein, one or more of the silicon particles, each comprises:

a concentration of aluminum in an outer region of the respective silicon particle that differs from a concentration of aluminum in an inner region of the respective silicon particle; and

a coating layer that coats an outer surface of the respective silicon particle.

16 . The electrochemical cell of claim 15 , wherein the coating layer of the respective silicon particle comprises silicon carbide.

17 . The electrochemical cell of claim 15 , wherein the coating layer of the respective silicon particle comprises carbon and silicon carbide.

18 . The electrochemical cell of claim 15 , wherein the coating layer of the respective silicon particle comprises carbon, silicon carbide, and one or more silicon oxides.

19 . The electrochemical cell of claim 15 , wherein the coating layer is configured to constrain outward expansion of its respective silicon particle during lithiation.

20 . The electrochemical cell of claim 15 , wherein the coating layer provides its respective silicon particle with an expansion buffer.

21 . The electrochemical cell of claim 15 , wherein the coating layer is continuous and conformal to its respective silicon particle.

22 . The electrochemical cell of claim 15 , wherein the carbon structure comprises one or more types of carbon phases that are electrochemically active and electrically conductive.

23 . The electrochemical cell of claim 15 , wherein, at least 50% of the silicon particles, each comprise the coating layer that coats the outer surface of the respective silicon particle.

24 . The electrochemical cell of claim 15 , wherein the concentration of aluminum in the outer region of the respective silicon particle is greater than the concentration of aluminum in the inner region of the respective silicon particle.

Assignments (2)

Continuity (15)

References Cited (209)