IP Library › Granted Patent US 8,476,743
Granted Patent B2
US 8,476,743 · App. 13/228,857 · Granted Jul 2, 2013

C-rich carbon boron nitride dielectric films for use in electronic devices

Inventors: Son Van Nguyen (Schenectady, NY); Alfred Grill (White Plains, NY); Thomas J. Haigh, Jr. (Claverack, NY); Sanjay Mehta (Niskayuna, NY)
Assignee: International Business Machines Corporation
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Quick Facts
Patent No.
US 8,476,743
App. No.
13/228,857
Filed
Sep 9, 2011
Granted
Jul 2, 2013
Kind
B2
Art Unit
2898
USPC
257/649
Abstract

A carbon-rich carbon boron nitride dielectric film having a dielectric constant of equal to, or less than 3.6 is provided that can be used as a component in various electronic devices. The carbon-rich carbon boron nitride dielectric film has a formula of C x B y N z wherein x is 35 atomic percent or greater, y is from 6 atomic percent to 32 atomic percent and z is from 8 atomic percent to 33 atomic percent.

Claims (18)

1. A dielectric film having a formula of C x B y N z wherein x is 35 atomic percent or greater, y is from 6 atomic percent to 32 atomic percent and z is from 8 atomic percent to 33 atomic percent, wherein said nitrogen is uniformly distributed throughout the dielectric film.

2. The dielectric film of claim 1 , wherein said dielectric film has a dielectric constant of equal to, or less than 3.6.

3. The dielectric film of claim 2 , wherein said dielectric constant is from 2.5 to 3.2.

4. The dielectric film of claim 1 , wherein x is from 35 atomic percent to 70 atomic percent, y is from 15 atomic percent to 32 atomic percent, and z is from 15 atomic percent to 33 atomic percent.

5. A dielectric film having a formula of C x B y N z wherein x is 35 atomic percent or greater, y is from 6 atomic percent to 32 atomic percent and z is from 8 atomic percent to 33 atomic percent, wherein said nitrogen is provided in selected regions within a depth of the dielectric film providing a graded film.

6. An electronic device comprising:

a substrate; and

a dielectric film located on a surface of said substrate, wherein said dielectric film has a formula of C x B y N z wherein x is 35 atomic percent or greater, y is from 6 atomic percent to 32 atomic percent and z is from 8 atomic percent to 33 atomic percent, wherein said nitrogen is uniformly distributed throughout the dielectric film or is provided in selected regions within the depth of the dielectric film providing a graded film.

7. The electronic device of claim 6 , wherein said substrate is an interconnect dielectric material having at least one conductive material located therein, and wherein said dielectric film is located on at least an exposed surface of the at least one conductive material.

8. The electronic device of claim 6 , wherein said substrate is a patterned gate stack, and said dielectric film is located on sidewalls of said patterned gate stack.

9. The electronic device of claim 6 , wherein said substrate is a carbon-based material.

10. The electronic device of claim 9 , wherein said carbon-based material is selected from the group consisting of graphene, graphite and a carbon nanotube.

11. The electronic device of claim 9 , further comprising at least one layer of a dielectric material and at least one layer of a conductive material located atop the dielectric film.

12. The electronic device of claim 6 , wherein said dielectric film has a dielectric constant of equal to, or less than 3.6.

13. The electronic device of claim 6 , wherein x is from 35 atomic percent to 70 atomic percent, y is from 15 atomic percent to 32 atomic percent, and z is from 15 atomic percent to 33 atomic percent.

14. The dielectric film of claim 5 , wherein said dielectric film has a dielectric constant of equal to, or less than 3.6.

15. The dielectric film of claim 14 , wherein said dielectric constant is from 2.5 to 3.2.

16. The dielectric film of claim 5 , wherein x is from 35 atomic percent to 70 atomic percent, y is from 15 atomic percent to 32 atomic percent, and z is from 15 atomic percent to 33 atomic percent.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded May 12, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 056987/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 20, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES INC.
Reel/Frame 054636/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2020
From: GLOBALFOUNDRIES INC.
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 054633/0001 →
SECURITY AGREEMENT Recorded Nov 29, 2018
From: GLOBALFOUNDRIES INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 049490/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2015
From: GLOBALFOUNDRIES U.S. 2 LLC; GLOBALFOUNDRIES U.S. INC.
To: GLOBALFOUNDRIES INC.
Reel/Frame 036779/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2015
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: GLOBALFOUNDRIES U.S. 2 LLC
Reel/Frame 036550/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 9, 2011
From: NGUYEN, SON VAN; GRILL, ALFRED; HAIGH, THOMAS J., JR.; MEHTA, SANJAY
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 026880/0624 →
Continuity (1)
Related Publication 20130062753A1 · Mar 14, 2013