IP Library Granted Patent US 8,624,104
Granted Patent B2
US 8,624,104 · App. 13/179,731 · Granted Jan 7, 2014

Heterojunction III-V solar cell performance

Inventors: Stephen W. Bedell (Wappingers Falls, NY); Bahman Hekmatshoartabari (Mount Kisco, NY); Devendra K. Sadana (Pleasantville, NY); Ghavam G. Shahidi (Pound Ridge, NY); Davood Shahrjerdi (Ossining, NY)
Assignee: International Business Machines Corporation
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Quick Facts
Patent No.
US 8,624,104
App. No.
13/179,731
Granted
Jan 7, 2014
Kind
B2
Abstract

An In x Ga 1-x As interlayer is provided between a III-V base and an intrinsic amorphous semiconductor layer of a heterojunction III-V solar cell structure. Improved surface passivation and open circuit voltage may be obtained through the incorporation of the interlayer within the structure.

Claims (38)

1. A heterojunction III-V solar cell structure comprising:

a base layer comprising In y Ga 1-y As;

an intrinsic semiconductor layer;

an epitaxial In x Ga 1-x As interlayer between and interfacing with the base layer and the intrinsic semiconductor layer, wherein 0.01<x<1.0 and 0<y<x;

the base layer and the interlayer having the same doping type;

a doped hydrogenated amorphous silicon layer on the intrinsic semiconductor layer;

and a transparent conductive layer on the doped hydrogenated amorphous silicon layer.

2. The heterojunction III-V solar cell structure of claim 1 , wherein 0.05≦x≦0.8.

3. The heterojunction III-V solar cell structure of claim 1 , wherein the intrinsic semiconductor layer comprises intrinsic hydrogenated amorphous silicon, and wherein the intrinsic hydrogenated amorphous silicon includes germanium and carbon atoms.

4. The heterojunction III-V solar cell structure of claim 1 , wherein the In x Ga 1-x As interlayer has a thickness between 5-50 nm.

5. The heterojunction III-V solar cell structure of claim 1 , wherein the hydrogenated amorphous silicon layer has a doping type opposite to the doping type of the base layer.

6. A heterojunction III-V solar cell structure, comprising:

a base layer comprising gallium arsenide;

an intrinsic semiconductor layer comprising hydrogenated amorphous silicon;

an epitaxial In x Ga 1-x As interlayer between and interfacing with the base layer and the intrinsic semiconductor layer, wherein 0.01<x<1.0;

a doped hydrogenated amorphous silicon layer on the intrinsic semiconductor layer, and

a transparent conductive layer above the hydrogenated amorphous silicon layer,

the base layer and the In x Ga 1-x As interlayer having a first doping type, the doped hydrogenated amorphous silicon layer having a second doping type opposite from the first doping type.

7. The heterojunction III-V solar cell structure of claim 6 , wherein 0.05≦x≦0.8.

8. The heterojunction III-V solar cell structure of claim 6 , wherein the In x Ga 1-x As interlayer has a thickness between 5-50 nm.

9. A heterojunction III-V solar cell structure, comprising: an intrinsic semiconductor layer comprising hydrogenated amorphous silicon; an epitaxial In x Ga 1-x As interlayer; a base layer comprising one of GaAs and In y Ga 1-y As where 0<y<x; the epitaxial In x Ga 1-x As interlayer being between and interfacing with the base layer and the intrinsic semiconductor layer, wherein 0.05<x<0.8; the base layer and the In x Ga 1-x As interlayer having the same doping type; a doped hydrogenated amorphous silicon layer on the intrinsic semiconductor layer, and a transparent conductive layer on the doped hydrogenated amorphous silicon layer.

10. A heterojunction III-V solar cell structure, comprising: an intrinsic semiconductor layer comprising a plurality of hydrogenated amorphous silicon layers; an epitaxial In x Ga 1-x As interlayer; a base layer comprising one of GaAs and In y Ga 1-y As where 0<y<x; the epitaxial In x Ga 1-x As interlayer being between and interfacing with the base layer and the intrinsic semiconductor layer, wherein 0.05<x<0.8; the base layer and the In x Ga 1-x As interlayer having the same doping type; a doped hydrogenated amorphous silicon layer on the intrinsic semiconductor layer, and a transparent conductive layer on the doped hydrogenated amorphous silicon layer.

11. A heterojunction III-V solar cell structure, comprising:

a base layer comprising GaAs;

an intrinsic semiconductor layer comprising hydrogenated amorphous silicon;

an epitaxial In x Ga 1-x As interlayer between and interfacing with the base layer and the intrinsic semiconductor layer, wherein 0.01<x<1.0, the base layer and the In x Ga 1-x As interlayer having the same doping type;

a doped hydrogenated amorphous silicon layer on the intrinsic semiconductor layer, and

a transparent conductive layer on the doped hydrogenated amorphous silicon layer.

12. A method comprising: obtaining a base layer comprising In y Ga 1-y As;

forming an intrinsic semiconductor layer;

forming an epitaxial In x Ga 1-x As interlayer between and interfacing with the base layer and the intrinsic semiconductor layer, wherein 0.01<x<1.0 and 0<y<x;

the base layer and the interlayer having the same doping type;

forming a doped hydrogenated amorphous silicon layer on the intrinsic semiconductor layer;

and forming a transparent conductive layer on the doped hydrogenated amorphous silicon layer.

13. The method of claim 12 , wherein 0.05<x<0.8.

14. The method of claim 12 , wherein the intrinsic semiconductor layer comprises intrinsic hydrogenated amorphous silicon.

15. The method of claim 14 , wherein the intrinsic hydrogenated amorphous silicon further includes germanium and carbon atoms.

16. The method of claim 14 , wherein 0.05<x<0.8.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded May 12, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 056987/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 20, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES INC.
Reel/Frame 054636/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2020
From: GLOBALFOUNDRIES INC.
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 054633/0001 →
SECURITY AGREEMENT Recorded Nov 29, 2018
From: GLOBALFOUNDRIES INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 049490/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2015
From: GLOBALFOUNDRIES U.S. 2 LLC; GLOBALFOUNDRIES U.S. INC.
To: GLOBALFOUNDRIES INC.
Reel/Frame 036779/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2015
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: GLOBALFOUNDRIES U.S. 2 LLC
Reel/Frame 036550/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 11, 2011
From: BEDELL, STEPHEN W.; HEKMATSHOARTABARI, BAHMAN; SADANA, DEVENDRA K.; SHAHIDI, GHAVAM G.; SHAHRJERDI, DAVOOD
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 026569/0823 →
Continuity (1)
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