IP Library › Granted Patent US 8,753,936
Granted Patent B2
US 8,753,936 · App. 12/190,220 · Granted Jun 17, 2014

Changing effective work function using ion implantation during dual work function metal gate integration

Inventors: Michael P. Chudzik (Danbury, CT); Martin M. Frank (Dobbs Ferry, NY); Herbert L. Ho (New Windsor, NY); Mark J. Hurley (Poughkeepsie, NY); Rashmi Jha (Toledo, OH); Naim Moumen (Walden, NY); Vijay Narayanan (New York, NY); Dae-Gyu Park (Poughquag, NY); Vamsi K. Paruchuri (Albany, NY)
Assignee: International Business Machines Corporation
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Quick Facts
Patent No.
US 8,753,936
App. No.
12/190,220
Granted
Jun 17, 2014
Kind
B2
Abstract

Ion implantation to change an effective work function for dual work function metal gate integration is presented. One method may include forming a high dielectric constant (high-k) layer over a first-type field effect transistor (FET) region and a second-type FET region; forming a metal layer having a first effective work function compatible for a first-type FET over the first-type FET region and the second-type FET region; and changing the first effective work function to a second, different effective work function over the second-type FET region by implanting a species into the metal layer over the second-type FET region.

Claims (20)

1. A method comprising:

forming a high dielectric constant (high-k) layer over a first-type field effect transistor (FET) region and a second-type FET region;

forming a single metal layer having a first effective work function compatible for a first-type FET over the first-type FET region and the second-type FET region; and

changing the first effective work function to a second, different effective work function over the second-type FET region by implanting an aluminum (Al) species into the single metal layer over the second-type FET region, wherein the changing results in a greater than 50 milli-Volt shift in a threshold voltage of the second-type FET and wherein the aluminum species diffuses into the high dielectric constant layer.

2. The method of claim 1 , further comprising forming the first-type FET over the first-type FET region and a second-type FET over the second-type FET region.

3. The method of claim 1 , further comprising forming a silicon layer over the metal layer prior to the changing, wherein the implanting includes implanting the aluminum species into the silicon.

4. The method of claim 1 , wherein the metal layer is selected from the group consisting of: tungsten (W), tantalum (Ta), aluminum (Al), ruthenium (Ru), platinum (Pt), titanium nitride (TiN), tantalum nitride (TaN), nickel silicide (NiSi), nickel-platinum silicide (NiPtSi), titanium carbide (TiC), tantalum carbide (TaC), tantalum carbide oxynitride (TaCNO), ruthenium oxide (RuO 2 ), and mixtures and multi-layers thereof.

5. The method of claim 1 , wherein the changing includes masking the first-type FET region.

6. The method of claim 1 , wherein the changing further includes annealing.

7. The method of claim 6 , wherein the annealing is part of a source/drain region forming for the first-type and second-type FETs.

8. The method of claim 1 , further comprising forming a gate dielectric layer prior to forming the high-k layer.

9. A method comprising:

forming a high dielectric constant (high-k) layer and a single metal layer over the high-k layer, the single metal layer having a first effective work function;

changing the first effective work function to a second, different effective work function in a region by implanting an aluminum (Al) species into the single metal layer over the region; and

forming a first-type FET compatible with the first effective work function over an area outside the region and forming a second-type FET compatible with the second effective work function over the region, wherein the changing results in a greater than 50 milli-Volt shift in a threshold voltage of the second-type FET and wherein the aluminum species diffuses into the high dielectric constant layer.

10. The method of claim 9 , further comprising forming a polysilicon layer over the metal layer prior to the changing, wherein the implanting includes implanting the aluminum species into the polysilicon.

11. The method of claim 9 , wherein the metal layer is selected from the group consisting of: tungsten (W), tantalum (Ta), aluminum (Al), ruthenium (Ru), platinum (Pt), titanium nitride (TiN), tantalum nitride (TaN), nickel silicide (NiSi), nickel-platinum silicide (NiPtSi), titanium carbide (TiC), tantalum carbide (TaC), tantalum carbide oxynitride (TaCNO), ruthenium oxide (RuO 2 ), and mixtures and multi-layers thereof.

12. The method of claim 9 , wherein the changing includes masking the area outside of the region.

13. The method of claim 9 , wherein the first-type and second-type FET formings include annealing.

14. The method of claim 13 , wherein the annealing is part of a source/drain region forming for the first-type and second-type FETs.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded May 12, 2021
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 056987/0001 →
RELEASE OF SECURITY INTEREST Recorded Nov 20, 2020
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: GLOBALFOUNDRIES INC.
Reel/Frame 054636/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 2, 2020
From: GLOBALFOUNDRIES INC.
To: GLOBALFOUNDRIES U.S. INC.
Reel/Frame 054633/0001 →
SECURITY AGREEMENT Recorded Nov 29, 2018
From: GLOBALFOUNDRIES INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 049490/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 5, 2015
From: GLOBALFOUNDRIES U.S. 2 LLC; GLOBALFOUNDRIES U.S. INC.
To: GLOBALFOUNDRIES INC.
Reel/Frame 036779/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2015
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: GLOBALFOUNDRIES U.S. 2 LLC
Reel/Frame 036550/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 14, 2008
From: CHUDZIK, MICHAEL P; FRANK, MARTIN M; HO, HERBERT L; HURLEY, MARK J; JHA, RASHMI; MOUMEN, NAIM; NARAYANAN, VIJAY; PARK, DAE-GYU; PARUCHURI, VAMSI K
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 021384/0869 →
Continuity (1)
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