IP Library › Granted Patent US 10,782,623
Granted Patent B2
US 10,782,623 · App. 16/047,413 · Granted Sep 22, 2020

Toner

Inventors: Daisuke Yoshiba (Suntou-gun, JP); Shohei Tsuda (Suntou-gun, JP); Mariko Yamashita (Suntou-gun, JP); Kozue Uratani (Mishima, JP); Ryo Nagata (Mishima, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/08G03G9/0821G03G9/0827G03G9/08711G03G9/08755G03G9/0904G03G9/09716G03G9/09725G03G9/09733
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Quick Facts
Patent No.
US 10,782,623
App. No.
16/047,413
Granted
Sep 22, 2020
Kind
B2
Abstract

A toner comprising: a toner particle that contains a binder resin and a colorant: and an external additive, wherein (1) the average circularity of the toner is at least 0.960; (2) the fixing ratio of the external additive on the toner particle is from 75% to 100%; and (3) in a differential curve obtained by the differentiation, by load, of a load-displacement curve where the horizontal axis is load (mN) and the vertical axis is displacement (μm), the load-displacement curve being provided by measurement of the strength of the toner by a nanoindentation procedure, a load A that provides a maximum value in the differential curve in a load region from 0.20 mN to 2.30 mN is from 1.15 mN to 1.50 mN.

Claims (15)

1. A toner, comprising:

a toner particle containing a binder resin and a colorant; and

an external additive, a fixing ratio of the external additive on the toner particle being from 75 to 100%, wherein

the average circularity of the toner is at least 0.960, and

a load A that provides a maximum value in a load region from 0.20 to 2.30 mN is from 1.15 to 1.50 mN in a differential curve obtained by the differentiation, by load, of a load-displacement curve where the horizontal axis is load (mN) and the vertical axis is displacement (μm), the load-displacement curve being provided by measurement of the strength of the toner by a nanoindentation procedure.

2. The toner according to claim 1 , wherein a coverage ratio X1 of the surface of the toner particle by the external additive is from 40.0 to 80.0 area % as measured with an x-ray photoelectron spectrometer.

3. The toner according to claim 2 , wherein a diffusion index indicated by the formula Diffusion index=X1/X2 satisfies the formula

Diffusion index≥−0.0042×X1+0.62

where X2 is a theoretical coverage ratio of the surface of the toner particle by the external additive.

4. The toner according to claim 1 , wherein the Total Energy is from 200 to 400 mJ when the surface of a powder layer of the toner produced in a measurement vessel by application of a vertical load of 0.88 kPa is penetrated by a propeller-type blade while rotating the propeller-type blade at a peripheral velocity of 10 mm/second at the outermost edge thereof using a powder flowability measuring apparatus.

5. The toner according to claim 1 , wherein the external additive contains an external additive having a number-average particle diameter of from 40 to 200 nm.

6. The toner according to claim 1 , wherein the methanol concentration at a transmittance of 40% is from 40 to 62 volume % when the wettability of the toner relative to a methanol/water mixed solvent is measured using the transmittance of light having a wavelength of 780 nm.

7. The toner according to claim 1 , wherein the external additive contains at least one selected member from the group consisting of silica fine particles and organic/inorganic composite fine particles.

8. The toner according to claim 1 , wherein the fixing ratio of the external additive on the toner particle is from 80 to 100%.

9. The toner according to claim 1 , wherein the fixing ratio of the external additive on the toner particle is from 80.2 to 100%.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 30, 2018
From: YOSHIBA, DAISUKE; TSUDA, SHOHEI; YAMASHITA, MARIKO; URATANI, KOZUE; NAGATA, RYO
To: CANON KABUSHIKI KAISHA
Reel/Frame 047906/0257 →
Priority Claims (1)
JP 2017-151621 · Aug 4, 2017 · national
Continuity (1)
Related Publication 20190041762A1 · Feb 7, 2019
Cited By (37)
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