IP Library Granted Patent US 12,283,633
Granted Patent B2
US 12,283,633 · App. 18/540,987 · Granted Apr 22, 2025

Composite and transistor

Inventor: Shunpei Yamazaki (Setagaya, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L29/7869H01L23/5226H01L23/544H01L29/78648H01L29/78696H01L2223/5446
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Quick Facts
Patent No.
US 12,283,633
App. No.
18/540,987
Granted
Apr 22, 2025
Kind
B2
Abstract

A novel material is provided. A composite oxide semiconductor in which a first region and a plurality of second regions are mixed is provided. Note that the first region contains at least indium, an element M (the element M is one or more of Al, Ga, Y, and Sn), and zinc, and the plurality of second regions contain indium and zinc. Since the plurality of second regions have a higher concentration of indium than the first region, the plurality of second regions have a higher conductivity than the first region. An end portion of one of the plurality of second regions overlaps with an end portion of another one of the plurality of second regions. The plurality of second regions are three-dimensionally surrounded with the first region.

Claims (67)

1. A semiconductor device comprising:

a transistor comprising:

a gate electrode;

a gate insulating film; and

an oxide semiconductor layer comprising indium, an element M, and zinc,

wherein the element M is one or more of Al, Ga, Y and Sn,

wherein the oxide semiconductor layer comprises a first region and a second region and a third region,

wherein an atomic ratio of In to the element M in the second region is greater than an atomic ratio of In to the element M in the first region,

wherein an atomic ratio of In to the element M in the third region is greater than the atomic ratio of In to the element M in the first region, and

wherein the second region and the third region are surrounded with the first region.

2. The semiconductor device according to claim 1 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) is 5:1:6 in the oxide semiconductor layer.

3. The semiconductor device according to claim 1 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the first region is 4:2:3.

4. The semiconductor device according to claim 1 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the second region is 2:0:3.

5. The semiconductor device according to claim 1 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) is 4:2:3 in the oxide semiconductor layer.

6. The semiconductor device according to claim 1 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the first region is 1:1:1.

7. The semiconductor device according to claim 1 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the second region is 2:0:1.

8. The semiconductor device according to claim 1 ,

wherein the first region is non-single-crystal, and

wherein the second region is non-single-crystal.

9. The semiconductor device according to claim 1 , wherein the second region has a higher conductivity than the first region.

10. The semiconductor device according to claim 1 , wherein the atomic ratio of In to the element M in the second region is 1.1 to 10 times as high as the atomic ratio of In to the element M in the first region.

11. The semiconductor device according to claim 1 , wherein the atomic ratio of In to the element M in the second region is 2 to 10 times as high as the atomic ratio of In to the element M in the first region.

12. A semiconductor device comprising:

a transistor comprising:

a gate electrode;

a gate insulating film; and

an oxide semiconductor layer comprising indium, an element M, and zinc,

wherein the element M is one or more of Al, Ga, Y and Sn,

wherein the oxide semiconductor layer comprises a first region and a plurality of second regions,

wherein an atomic ratio of In to the element M in each of the second regions is greater than an atomic ratio of In to the element M in the first region,

wherein the first region and the plurality of the second regions are mixed, and

wherein the plurality of the second regions are enclosed by the first region.

13. The semiconductor device according to claim 12 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) is 5:1:6 in the oxide semiconductor layer.

14. The semiconductor device according to claim 12 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the first region is 4:2:3.

15. The semiconductor device according to claim 12 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in one of the plurality of second regions is 2:0:3.

16. The semiconductor device according to claim 12 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) is 4:2:3 in the oxide semiconductor layer.

17. The semiconductor device according to claim 12 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the first region is 1:1:1.

18. The semiconductor device according to claim 12 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in one of the plurality of second regions is 2:0:1.

19. The semiconductor device according to claim 12 ,

wherein the first region is non-single-crystal, and

wherein each of the plurality of second regions is non-single-crystal.

20. The semiconductor device according to claim 12 , wherein each of the plurality of second regions has a higher conductivity than the first region.

21. The semiconductor device according to claim 12 , wherein the atomic ratio of In to the element M in each of the plurality of second regions is 1.1 to 10 times as high as the atomic ratio of In to the element M in the first region.

22. The semiconductor device according to claim 12 , wherein the atomic ratio of In to the element M in each of the plurality of second regions is 2 to 10 times as high as the atomic ratio of In to the element M in the first region.

23. A semiconductor device comprising:

a transistor comprising:

a gate electrode;

a gate insulating film; and

an oxide semiconductor layer comprising indium, an element M, and zinc,

wherein the element M is one or more of Al, Ga, Y and Sn,

wherein the oxide semiconductor layer comprises a first region and a plurality of second regions,

wherein an atomic ratio of In to the element M in each of the second regions is greater than an atomic ratio of In to the element M in the first region,

wherein the first region and the plurality of the second regions are mixed,

wherein one of the second regions and another of the second regions are connected, and

wherein all the plurality of the second regions are not connected.

24. The semiconductor device according to claim 23 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) is 5:1:6 in the oxide semiconductor layer.

25. The semiconductor device according to claim 23 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the first region is 4:2:3.

26. The semiconductor device according to claim 23 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in one of the plurality of second regions is 2:0:3.

27. The semiconductor device according to claim 23 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) is 4:2:3 in the oxide semiconductor layer.

28. The semiconductor device according to claim 23 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in the first region is 1:1:1.

29. The semiconductor device according to claim 23 , wherein an atomic ratio of indium to the element M and zinc (In:M:Zn) in one of the plurality of second regions is 2:0:1.

30. The semiconductor device according to claim 23 ,

wherein the first region is non-single-crystal, and

wherein each of the plurality of second regions is non-single-crystal.

31. The semiconductor device according to claim 23 , wherein each of the plurality of second regions has a higher conductivity than the first region.

32. The semiconductor device according to claim 23 , wherein the atomic ratio of In to the element M in each of the plurality of second regions is 1.1 to 10 times as high as the atomic ratio of In to the element M in the first region.

33. The semiconductor device according to claim 23 , wherein the atomic ratio of In to the element M in each of the plurality of second regions is 2 to 10 times as high as the atomic ratio of In to the element M in the first region.

Priority Claims (1)
JP 2016-048802 · Mar 11, 2016 · national
Continuity (4)
Continuation 17884717 · Aug 10, 2022
Continuation 16690755 · Nov 21, 2019
Continuation 15443052 · Feb 27, 2017
Related Publication 20240113231A1 · Apr 4, 2024
References Cited (75)
US 8431927B2 · Kim et al. · 2013 [cited by applicant]
US 8952381B2 · Yamazaki · 2015 [cited by applicant]
US 9219161B2 · Yamazaki · 2015 [cited by applicant]
US 9406760B2 · Shimomura et al. · 2016 [cited by applicant]
US 9461179B2 · Kobayashi et al. · 2016 [cited by applicant]
US 9530894B2 · Koezuka et al. · 2016 [cited by applicant]
US 9559174B2 · Shimomura et al. · 2017 [cited by applicant]
US 9666721B2 · Yamazaki · 2017 [cited by applicant]
US 9786793B2 · Tezuka · 2017 [cited by applicant]
US 9799775B2 · Kobayashi et al. · 2017 [cited by applicant]
US 9806201B2 · Yamazaki et al. · 2017 [cited by applicant]
US 9847358B2 · Koezuka et al. · 2017 [cited by applicant]
US 10032928B2 · Shimomura et al. · 2018 [cited by applicant]
US 10367013B2 · Koezuka et al. · 2019 [cited by applicant]
US 10424673B2 · Yamazaki · 2019 [cited by applicant]
US 10516060B2 · Yamazaki · 2019 [cited by examiner]
US 10763282B2 · Koezuka et al. · 2020 [cited by applicant]
US 11355529B2 · Koezuka et al. · 2022 [cited by applicant]
US 11417771B2 · Yamazaki · 2022 [cited by examiner]
US 12057459B2 · Koezuka et al. · 2024 [cited by applicant]
US 20100224873A1 · Sakata et al. · 2010 [cited by applicant]
US 20130341180A1 · Yamazaki · 2013 [cited by applicant]
US 20140034946A1 · Yamazaki et al. · 2014 [cited by applicant]
US 20140084287A1 · Yamazaki · 2014 [cited by applicant]
US 20140103339A1 · Yamazaki et al. · 2014 [cited by applicant]
US 20140110706A1 · Yamazaki · 2014 [cited by applicant]
US 20150103977A1 · Ono et al. · 2015 [cited by applicant]
US 20150243738A1 · Shimomura et al. · 2015 [cited by applicant]
US 20150255029A1 · Niikura et al. · 2015 [cited by applicant]
US 20150318171A1 · Yamazaki · 2015 [cited by applicant]
US 20150325708A1 · Yakubo. et al. · 2015 [cited by applicant]
US 20150340505A1 · Yamazaki et al. · 2015 [cited by applicant]
US 20150349127A1 · Kurata et al. · 2015 [cited by applicant]
US 20160349557A1 · Shishido et al. · 2016 [cited by applicant]
US 20160349558A1 · Shishido et al. · 2016 [cited by applicant]
US 20160356645A1 · Yoneda et al. · 2016 [cited by applicant]
US 20160365367A1 · Kimura et al. · 2016 [cited by applicant]
US 20160372606A1 · Ito et al. · 2016 [cited by applicant]
US 20160381266A1 · Ohmaru · 2016 [cited by applicant]
US 20170076943A1 · Nakayama et al. · 2017 [cited by applicant]
US 20170077243A1 · Nakayama et al. · 2017 [cited by applicant]
US 20170263783A1 · Yamazaki et al. · 2017 [cited by applicant]
CN 102097486A · 2011 [cited by applicant]
CN 104867981A · 2015 [cited by applicant]
CN 105960712A · 2016 [cited by applicant]
DE 112014006711 · 2017 [cited by applicant]
JP 2007096055A · 2007 [cited by applicant]
JP 2013105814A · 2013 [cited by applicant]
JP 2013236061A · 2013 [cited by applicant]
JP 2014030001A · 2014 [cited by applicant]
JP 2014103388A · 2014 [cited by applicant]
JP 2015181161A · 2015 [cited by applicant]
JP 2016006855A · 2016 [cited by applicant]
JP 2016027619A · 2016 [cited by applicant]
JP 2016028423A · 2016 [cited by applicant]
KR 20150126272A · 2015 [cited by applicant]
KR 20170015292A · 2017 [cited by applicant]
TW 201538432 · 2015 [cited by applicant]
TW 201545351 · 2015 [cited by applicant]
WO WO2013081128 · 2013 [cited by applicant]
WO WO2013191266 · 2013 [cited by applicant]
WO WO2014065343 · 2014 [cited by applicant]
WO WO2014112376 · 2014 [cited by applicant]
WO WO2015118472 · 2015 [cited by applicant]
WO WO2015132697 · 2015 [cited by applicant]
WO WO2015182000 · 2015 [cited by applicant]
Nakamura.M et al., “The phase relations in the In2O3—Ga2ZnO4—ZnO system at 1350° C.”, Journal of Solid State Chemistry, Aug. 1, 1991, vol. 93, No. 2, pp. 298-315, Elsevier. [cited by applicant]
Kang.S et al., “Surface-chemistry-sensitive spectral features of In—Ga—Zn—O thin film: Cleaned, air-passivated, and sputter-phase-separated surfaces”, Chem. Phys. Lett. (Chemical Physics Letters), Jul. 15, 2011, vol. 51… [cited by applicant]
Park.J et al., “Improvements in the Device Characteristics of Amorphous Indium Gallium Zinc Oxide Thin-Film Transistors by Ar Plasma Treatment”, Appl. Phys. Lett. (Applied Physics Letters), Jun. 26, 2007, vol. 90, No. 2… [cited by applicant]
Lee.M et al., “Sputtering Effect on Amorphous Ga—In—Zn—O Thin-Film Surface: Occurrence of Subgap and Metallic States”, Electrochemical and Solid-State Letters, Sep. 30, 2010, vol. 13, No. 12, pp. H454-H456. [cited by applicant]
International Search Report (Application No. PCT/IB2017/051114) Dated May 30, 2017. [cited by applicant]
Written Opinion (Application No. PCT/IB2017/051114) Dated May 30, 2017. [cited by applicant]
Chinese Office Action (Application No. 201780016678.0) Dated Apr. 26, 2021. [cited by applicant]
Taiwanese Office Action (Application No. 106107851) Dated Nov. 3, 2021. [cited by applicant]
Chinese Office Action (Application No. 202210549677.5) Dated Nov. 11, 2024. [cited by applicant]