IP Library Granted Patent US 12,378,153
Granted Patent B2
US 12,378,153 · App. 18/212,993 · Granted Aug 5, 2025

Ion exchangeable glass with high crack initiation threshold

Inventor: Timothy Michael Gross (Corning, NY)
Assignee: CORNING INCORPORATED
C03C3/097C03C3/083C03C3/085C03C3/087C03C21/002C03C3/04C03C3/062C03C3/064C03C3/091C03C3/093C03C4/18C03C21/00C03C2204/00Y10T428/265Y10T428/315
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Quick Facts
Patent No.
US 12,378,153
App. No.
18/212,993
Granted
Aug 5, 2025
Kind
B2
Abstract

Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P 2 O 5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.

Claims (38)

1. An alkali aluminosilicate glass comprising:

from 40 mol % to 70 mol % SiO 2 ;

from 11 mol % to 25 mol % Al 2 O 3 ;

from 4 mol % to 15 mol % P 2 O 5 ;

from 13 mol % to 20 mol % Na 2 O;

Li 2 O; and

less than or equal to 4 mol % B 2 O 3 ,

wherein 1.3<[(P 2 O 5 +R 2 O)/M 2 O 3 ]≤2.3, where M 2 O 3 =Al 2 O 3 +B 2 O 3 , and R 2 O is a sum of monovalent cation oxides present in the alkali aluminosilicate glass.

2. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass comprises from 55 mol % to 65 mol % SiO 2 .

3. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass comprises from 14 mol % to 20 mol % Al 2 O 3 .

4. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass comprises from 5 mol % to 15 mol % P 2 O 5 .

5. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass comprises less than 1 mol % K 2 O.

6. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass is free of K 2 O.

7. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass comprise less than 1 mol % B 2 O 3 .

8. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass is free of B 2 O 3 .

9. The alkali aluminosilicate glass of claim 1 , wherein 1.5<[(P 2 O 5 +R 2 O)/M 2 O 3 ]≤2.0.

10. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass has a potassium/sodium interdiffusion coefficient of at least 2.4×10 −10 cm 2 /s at 410° C.

11. The alkali aluminosilicate glass of claim 10 , wherein the potassium/sodium interdiffusion coefficient is in a range from 2.4×10 −10 cm 2 /s up to 1.5×10 −9 cm 2 /s at 410° C.

12. The alkali aluminosilicate glass of claim 1 , wherein the alkali aluminosilicate glass is ion exchanged to a depth of layer of at least 10 μm.

13. The alkali aluminosilicate glass of claim 12 , wherein the depth of layer is at least 30 μm.

14. The alkali aluminosilicate glass of claim 12 , wherein the alkali aluminosilicate glass has a compressive layer extending from a surface of the alkali aluminosilicate glass to the depth of layer, and wherein the compressive layer is under a compressive stress of at least 300 MPa.

15. The alkali aluminosilicate glass of claim 14 , wherein the compressive stress is at least 500 MPa.

16. The alkali aluminosilicate glass of claim 12 , wherein the alkali aluminosilicate glass has a Vickers indentation crack initiation load of at least 7 kgf.

17. The alkali aluminosilicate glass of claim 16 , wherein the Vickers indentation crack initiation load is at least 12 kgf.

18. A method of forming an ion-exchanged alkali aluminosilicate glass, the method comprising:

a. providing a non-ion exchanged alkali aluminosilicate precursor glass comprising:

from 40 mol % to 70 mol % SiO 2 ;

from 11 mol % to 25 mol % Al 2 O 3 ;

from 4 mol % to 15 mol % P 2 O 5 ;

from 13 mol % to 20 mol % Na 2 O;

Li 2 O; and

less than or equal to 4 mol % B 2 O 3 ,

wherein 1.3<[(P 2 O 5 +R 2 O)/M 2 O 3 ]≤2.3, where M 2 O 3 =Al 2 O 3 +B 2 O 3 , and R 2 O is a sum of monovalent cation oxides present in the non-ion exchanged alkali aluminosilicate precursor glass; and

b. immersing the non-ion exchanged alkali aluminosilicate precursor glass in an ion exchange bath for a time period of up to 24 hours to form a compressive layer extending from a surface of the ion-exchanged alkali aluminosilicate glass to a depth of layer of at least 10 μm.

19. The method of claim 18 , wherein the non-ion exchanged alkali aluminosilicate precursor glass comprises:

from 55 mol % to 65 mol % SiO 2 ; and

from 5 mol % to 15 mol % P 2 O 5 .

20. The method of claim 18 , wherein the compressive layer is under a compressive stress of at least 300 MPa, and the ion-exchanged alkali aluminosilicate glass has a Vickers indentation crack initiation load of at least 7 kgf.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 22, 2023
From: GROSS, TIMOTHY MICHAEL
To: CORNING INCORPORATED
Reel/Frame 064031/0901 →
Continuity (6)
Continuation 16793398 · Feb 18, 2020
Continuation 15696831 · Sep 6, 2017
Continuation 14842122 · Sep 1, 2015
Continuation 13678013 · Nov 15, 2012
Provisional Application 61560434 · Nov 16, 2011
Related Publication 20230339802A1 · Oct 26, 2023
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