Super absorbent polymer
The present disclosure relates to a super absorbent polymer exhibiting an improved absorption rate and improved absorption performance.
1. A super absorbent polymer that is a polyacrylic acid or salt thereof—based super absorbent polymer,
wherein for all particles, an average value of circularity, which is calculated according to Expression 1 below, is approximately 0.90 or less,
an average value of an aspect ratio (A/R), which means a ratio of a shortest diameter of a particle to a longest diameter of the particle, is approximately 0.70 or more, and
an absorbency under pressure (AUP), which is measured at 2.07 kPa (0.3 psi) according to EDANA method WSP 242.3, is approximately 25 g/g or more:
circularity=perimeter of circle equivalent (CE) particle/perimeter of actual particle <Expression 1>
in Expression 1 above,
the perimeter of the CE particle means a perimeter length of a circle that has the same area as a two-dimensional image of a three-dimensional particle to be measured, and
the perimeter of the actual particle means a perimeter length of the two-dimensional image of the three-dimensional particle to be measured.
2. The super absorbent polymer according to claim 1 , wherein for all the particles, the average value of the circularity is approximately 0.70 to approximately 0.90.
3. The super absorbent polymer according to claim 1 , wherein for all the particles, the average value of the aspect ratio is approximately 0.70 to approximately 0.85.
4. The super absorbent polymer according to claim 1 ,
wherein for all particles, an average value of high sensitivity (HS) circularity, which is calculated according to Expression 2 below, is approximately 0.80 or less:
HS circularity=(perimeter of CE particle) 2 /(perimeter of actual particle) 2 . <Expression 2>
5. The super absorbent polymer according to claim 4 , wherein for all the particles, the average value of the HS circularity is approximately 0.50 to approximately 0.80.
6. The super absorbent polymer according to claim 1 , wherein a ratio of a circularity of particles having a particle diameter of approximately 300 μm to approximately 600 μm to a circularity of all the particles of the super absorbent polymer is approximately 0.9 to approximately 1.1.
7. The super absorbent polymer according to claim 1 , wherein an average value of CE diameters of the super absorbent polymer is approximately 220 μm to approximately 400 μm.
8. The super absorbent polymer according to claim 1 , wherein the super absorbent polymer has a water retention capacity (CRC) of approximately 33 g/g or more, where the water retention capacity (CRC) is measured according to EDANA method WSP 241.3.
9. The super absorbent polymer according to claim 1 ,
wherein the super absorbent polymer has an effective absorption capacity (EFFC) of approximately 30 g/g or more, where the effective absorption capacity (EFFC) is calculated according to Expression 3 below:
effective absorption capacity(EFFC){water retention capacity(CRC)+absorbency under pressure(AUP) at 2.07 kPa(0.3 psi)}/2 <Expression 3>.
10. The super absorbent polymer according to claim 1 , wherein a vortex time is approximately 40 seconds or less, where the vortex time is measured by a vortex measuring method at 24.0° C.
11. The super absorbent polymer according to claim 1 , wherein when 1 g of the super absorbent polymer is swollen with water having an electrical conductivity value of 110 μS/cm for 1 minute, a maximum capacity (free swell capacity) of water that is retainable in the super absorbent polymer is approximately 170 g or more.
12. The super absorbent polymer according to claim 1 , wherein the absorbency under pressure (AUP), which is measured at 2.07 kPa (0.3 psi) according to EDANA method WSP 242.3, is from 29 g/g to 45 g/g.
13. The super absorbent polymer according to claim 1 , wherein:
the absorbency under pressure (AUP), which is measured at 2.07 kPa (0.3 psi) according to EDANA method WSP 242.3, is from 29 g/g to 45 g/g;
the super absorbent polymer has a water retention capacity (CRC) from 33 g/g to 50 g/g, where the water retention capacity (CRC) is measured according to EDANA method WSP 241.3;
a vortex time is 33 seconds or less, where the vortex time is measured by a vortex measuring method at 24.0° C.; and
a maximum capacity (free swell capacity) of water that is retainable in the super absorbent polymer is from 170 g to 230 g, when 1 g of the super absorbent polymer is swollen with water having an electrical conductivity value of 110 μS/cm for 1 minute.