IP Library Granted Patent US 12,439,916
Granted Patent B2
US 12,439,916 · App. 18/317,768 · Granted Oct 14, 2025

Generation of peroxyformic acid through polyhydric alcohol formate

Inventors: Junzhong Li (Saint Paul, MN); Allison Brewster (Saint Paul, MN); Richard Staub (Saint Paul, MN); Steven J. Lange (Saint Paul, MN); Taz Cheritu (Saint Paul, MN); Jonathan P. Fast (Saint Paul, MN); Catherine Hanson (Saint Paul, MN)
Assignee: ECOLAB USA INC.
A01N37/16A01N37/00A61K8/38A61L2/00A61L2/16A61Q17/005C07C407/00C07C409/24C11D3/00C11D3/3947C11D3/48C12P7/40
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Quick Facts
Patent No.
US 12,439,916
App. No.
18/317,768
Granted
Oct 14, 2025
Kind
B2
Abstract

The present invention relates generally to peroxyformic acid forming compositions, methods for forming peroxyformic acid, preferably in situ, using the peroxyformic acid forming compositions. The present invention also relates to the peroxyformic acid formed by the above compositions and methods. The present invention further relates to the uses of the peroxyformic acid, preferably in situ, for treating a surface or a target. The present invention further relates to methods for treating a biofilm using peroxyformic acid, including peroxyformic acid generated in situ.

Claims (23)

1. A wipe saturated with a peroxyformic acid forming composition comprising:

a wipe; and

a peroxyformic acid-forming composition comprising: (i) a first reagent comprising an ester of a polyhydric alcohol and formic acid; (ii) a second reagent comprising hydrogen peroxide or a substance that generates hydrogen peroxide when in contact with a liquid; and (iii) a formed liquid comprising peroxyformic acid and having a pH of 8 or less without requiring an additional acidulant.

2. The wipe of claim 1 , wherein the wipe is comprised of a woven fabric, a nonwoven fabric, a microfiber product, paper, fiber, or a combination thereof.

3. The wipe of claim 1 , wherein the ester of a polyhydric alcohol and formic acid is derived from a sugar alcohol and formic acid.

4. The wipe of claim 3 , wherein the sugar alcohol is ethylene glycol, methylene glycol, propylene glycol, or a combination thereof.

5. The wipe of claim 1 , wherein the ester of a polyhydric alcohol and formic acid comprises glycerol formate, pentaerythritol formate, mannitol formate, propylene glycol formate, sorbitol formate, sugar formate, or a combination thereof.

6. The wipe of claim 5 , wherein the sugar formates comprise sucrose formates, dextrin formates, maltodextrin formates, starch formates, or a combination thereof.

7. The wipe of claim 1 , wherein the first reagent, the second reagent, and/or the peroxyformic acid composition further comprise a pH buffering agent, a stabilizing agent, acidulant, or a combination thereof.

8. The wipe of claim 7 , wherein the pH buffering agent comprises a carbonate salt, phosphate salt, sodium bicarbonate, organic amine, or a combination thereof.

9. The wipe of claim 7 , wherein the stabilizing agent comprises a phosphonate, phosphonate salt, heterocyclic dicarboxylic acid, or a combination thereof.

10. A method for treating a target comprising:

contacting a wipe with a first reagent comprising an ester of a polyhydric alcohol and formic acid; (ii) a second reagent comprising hydrogen peroxide or a substance that generates hydrogen peroxide when in contact with a liquid; and (iii) a formed liquid comprising peroxyformic acid and having a pH of 8 or less without requiring an additional acidulant to form a saturated wipe, wherein the first reagent reacts with the second reagent to generate the formed liquid comprising peroxyformic acid; and

contacting a target with the saturated wipe to form a treated target composition;

wherein the treated target composition comprises from about 0.1 ppm to about 10,000 ppm peroxyformic acid; and

wherein the contacting the target lasts for at least 10 seconds to reduce a microbial population in and/or on the target.

11. The method of claim 10 , wherein the contacting of the target lasts for between 10 seconds to about 10 hours.

12. The method of claim 10 , wherein the microbial population is reduced by at least one log 10 5 minutes after the contacting of the target.

13. The method of claim 11 , wherein the target is at least a portion of a medium, a surface, a container, an equipment, or a system in a health care facility.

14. The method of claim 13 , wherein the surface in a health care facility is an instrument, device, cart, cage, furniture, structure, or building employed as part of a health care activity.

15. The method of claim 14 , wherein the instrument employed as part of a health care activity is a medical or dental instrument, device, tool, appliance, apparatus, or patient-care equipment.

16. The method of claim 13 , wherein the surface in a health care facility is a hard surface comprising a wall, floor, bed-pan, or a combination thereof.

17. The method of claim 13 , wherein the surface in a health care facility is a soft surface comprising a fabric, linen, garment, skin, or a combination thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 16, 2023
From: LI, JUNZHONG; BREWSTER, ALLISON; STAUB, RICHARD; LANGE, STEVEN J.; CHERITU, TAZ; FAST, JONATHAN P.
To: ECOLAB USA INC.
Reel/Frame 063654/0649 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 16, 2023
From: HANSON, CATHERINE
To: ECOLAB USA INC.
Reel/Frame 063655/0308 →
Continuity (6)
Continuation 16949008 · Oct 9, 2020
Continuation 16552323 · Aug 27, 2019
Continuation 15345263 · Nov 7, 2016
Continuation 14973389 · Dec 17, 2015
Provisional Application 62094048 · Dec 18, 2014
Related Publication 20230329235A1 · Oct 19, 2023
References Cited (352)
US 598218A · Going · 1898 [cited by applicant]
US 2448252A · Cornthwaite et al. · 1948 [cited by applicant]
US 2955905A · Davies et al. · 1960 [cited by applicant]
US 2995524A · Wylie et al. · 1961 [cited by applicant]
US 3169986A · Webb et al. · 1965 [cited by applicant]
US 3256198A · Matzner · 1966 [cited by applicant]
US 3272750A · Chase · 1966 [cited by applicant]
US 3432546A · Oringer et al. · 1969 [cited by applicant]
US 3847830A · Williams et al. · 1974 [cited by applicant]
US 3925234A · Hachmann et al. · 1975 [cited by applicant]
US 4003841A · Hachmann et al. · 1977 [cited by applicant]
US 4051058A · Böwing et al. · 1977 [cited by applicant]
US 4126573A · Johnston · 1978 [cited by applicant]
US 4170453A · Kitko · 1979 [cited by applicant]
US 4233235A · Camden et al. · 1980 [cited by applicant]
US 4370251A · Liao et al. · 1983 [cited by applicant]
US 4412934A · Chung et al. · 1983 [cited by applicant]
US 4483778A · Thompson et al. · 1984 [cited by applicant]
US 4486327A · Murphy et al. · 1984 [cited by applicant]
US 4550026A · Ando · 1985 [cited by applicant]
US 4617090A · Chum et al. · 1986 [cited by applicant]
US 4655781A · Hsieh et al. · 1987 [cited by applicant]
US 4778618A · Fong et al. · 1988 [cited by applicant]
US 4964870A · Fong et al. · 1990 [cited by applicant]
US 5030240A · Wiersema et al. · 1991 [cited by applicant]
US 5063249A · Andrews · 1991 [cited by applicant]
US 5139788A · Schmidt · 1992 [cited by applicant]
US 5143641A · Nunn · 1992 [cited by applicant]
US 5200189A · Oakes et al. · 1993 [cited by applicant]
US 5246620A · Gethoffer et al. · 1993 [cited by applicant]
US 5266587A · Sankey et al. · 1993 [cited by applicant]
US 5314687A · Oakes et al. · 1994 [cited by applicant]
US 5374433A · Bowling et al. · 1994 [cited by applicant]
US 5391324A · Reinhardt et al. · 1995 [cited by applicant]
US 5422028A · Oakes et al. · 1995 [cited by applicant]
US 5431849A · Damhus et al. · 1995 [cited by applicant]
US 5463112A · Sankey et al. · 1995 [cited by applicant]
US 5466825A · Carr et al. · 1995 [cited by applicant]
US 5503765A · Schepers et al. · 1996 [cited by applicant]
US 5505740A · Kong et al. · 1996 [cited by applicant]
US 5576282A · Miracle et al. · 1996 [cited by applicant]
US 5589507A · Hall, II et al. · 1996 [cited by applicant]
US 5616281A · Hardy et al. · 1997 [cited by applicant]
US 5616335A · Nicolle et al. · 1997 [cited by applicant]
US 5635195A · Hall, II et al. · 1997 [cited by applicant]
US 5637755A · Nagumo et al. · 1997 [cited by applicant]
US 5681805A · Scheuing et al. · 1997 [cited by applicant]
US 5716923A · MacBeath · 1998 [cited by applicant]
US 5718910A · Oakes et al. · 1998 [cited by applicant]
US 5817614A · Miracle et al. · 1998 [cited by applicant]
US 5827447A · Tamura et al. · 1998 [cited by applicant]
US 5827808A · Appleby et al. · 1998 [cited by applicant]
US 5840343A · Hall, II et al. · 1998 [cited by applicant]
US 5914303A · Sankey et al. · 1999 [cited by applicant]
US 5928382A · Reinhardt et al. · 1999 [cited by applicant]
US 5977403A · Byers · 1999 [cited by applicant]
US 5998350A · Burns et al. · 1999 [cited by applicant]
US 6022381A · Dias et al. · 2000 [cited by applicant]
US 6068815A · Oberleitner et al. · 2000 [cited by applicant]
US 6156156A · Rousu et al. · 2000 [cited by applicant]
US 6177393B1 · McGregor et al. · 2001 [cited by applicant]
US 6207632B1 · Brooker et al. · 2001 [cited by applicant]
US 6210678B1 · Richards · 2001 [cited by applicant]
US 6211237B1 · Huss et al. · 2001 [cited by applicant]
US 6221341B1 · Montgomery · 2001 [cited by applicant]
US 6254801B1 · Reinold et al. · 2001 [cited by applicant]
US 6262013B1 · Smith et al. · 2001 [cited by applicant]
US 6274542B1 · Carr et al. · 2001 [cited by applicant]
US 6284719B1 · Simms · 2001 [cited by applicant]
US 6284793B1 · Fuchs et al. · 2001 [cited by applicant]
US 6379685B1 · Richter et al. · 2002 [cited by applicant]
US 6399564B1 · Speed et al. · 2002 [cited by applicant]
US 6537958B1 · diCapua et al. · 2003 [cited by applicant]
US 6548467B2 · Baker et al. · 2003 [cited by applicant]
US 6548470B1 · deBuzzaccarini et al. · 2003 [cited by applicant]
US 6569286B1 · Withenshaw et al. · 2003 [cited by applicant]
US 6585934B1 · Oberleitner et al. · 2003 [cited by applicant]
US 6599871B2 · Smith · 2003 [cited by applicant]
US 6602845B2 · Connor et al. · 2003 [cited by applicant]
US 6627657B1 · Hilgren et al. · 2003 [cited by applicant]
US 6649140B2 · Paparatto et al. · 2003 [cited by applicant]
US 6689732B1 · Guedira et al. · 2004 [cited by applicant]
US 6693069B2 · Körber et al. · 2004 [cited by applicant]
US 6802061B1 · Parthasarathy et al. · 2004 [cited by applicant]
US 6841090B1 · Serego Allighieri et al. · 2005 [cited by applicant]
US 7012154B2 · Vineyard et al. · 2006 [cited by applicant]
US 7061597B2 · Oberleitner et al. · 2006 [cited by applicant]
US 7189385B2 · Montgomery · 2007 [cited by applicant]
US 7217295B2 · Samain et al. · 2007 [cited by applicant]
US 7494963B2 · Ahmed et al. · 2009 [cited by applicant]
US 7550420B2 · DiCosimo et al. · 2009 [cited by applicant]
US 7569232B2 · Man et al. · 2009 [cited by applicant]
US 7598218B2 · Stolte et al. · 2009 [cited by applicant]
US 7612030B2 · DiCosimo et al. · 2009 [cited by applicant]
US 7682403B2 · Gohl et al. · 2010 [cited by applicant]
US 7723083B2 · DiCosimo et al. · 2010 [cited by applicant]
US 7754460B2 · Amin et al. · 2010 [cited by applicant]
US 7807425B2 · DiCosimo et al. · 2010 [cited by applicant]
US 7829315B2 · DiCosimo et al. · 2010 [cited by applicant]
US 7915445B2 · Maatta et al. · 2011 [cited by applicant]
US 7919122B2 · Okano et al. · 2011 [cited by applicant]
US 7951566B2 · DiCosimo et al. · 2011 [cited by applicant]
US 7964378B2 · DiCosimo et al. · 2011 [cited by applicant]
US 8110603B2 · Kawabata et al. · 2012 [cited by applicant]
US 8129153B2 · DiCosimo et al. · 2012 [cited by applicant]
US 8153613B2 · Ahmed et al. · 2012 [cited by applicant]
US 8168676B2 · DiCosimo et al. · 2012 [cited by applicant]
US 8178581B2 · DiCosimo et al. · 2012 [cited by applicant]
US 8293792B2 · DiCosimo et al. · 2012 [cited by applicant]
US 8367728B2 · DiCosimo et al. · 2013 [cited by applicant]
US 8389575B2 · DiCosimo et al. · 2013 [cited by applicant]
US 8426634B2 · Neas et al. · 2013 [cited by applicant]
US 8486679B2 · DiCosimo et al. · 2013 [cited by applicant]
US 8518675B2 · DiCosimo et al. · 2013 [cited by applicant]
US 8729296B2 · Fast et al. · 2014 [cited by applicant]
US 8802061B2 · Tichy et al. · 2014 [cited by applicant]
US 8841098B2 · Payne et al. · 2014 [cited by applicant]
US 8858895B2 · Kraus · 2014 [cited by examiner]
US 8865436B2 · Payne et al. · 2014 [cited by applicant]
US 8877354B2 · Horiuchi et al. · 2014 [cited by applicant]
US 8883485B2 · Barnett et al. · 2014 [cited by applicant]
US 8889900B2 · Kraus · 2014 [cited by examiner]
US 9012504B2 · Olson et al. · 2015 [cited by applicant]
US 9034390B2 · Kielbania, Jr. · 2015 [cited by applicant]
US 9040023B2 · Durham et al. · 2015 [cited by applicant]
US 9044403B2 · Schultz · 2015 [cited by applicant]
US 9192909B2 · Kraus · 2015 [cited by examiner]
US 9282746B2 · Amin et al. · 2016 [cited by applicant]
US 9288992B2 · Li et al. · 2016 [cited by applicant]
US 9321664B2 · Li et al. · 2016 [cited by applicant]
US 9505715B2 · Kraus · 2016 [cited by examiner]
US 9518013B2 · Li · 2016 [cited by examiner]
US 9585397B2 · Li et al. · 2017 [cited by applicant]
US 9676711B2 · Junzhong et al. · 2017 [cited by applicant]
US 9701931B2 · Moore · 2017 [cited by applicant]
US 9750755B2 · Ahmed et al. · 2017 [cited by applicant]
US 9752105B2 · Stokes et al. · 2017 [cited by applicant]
US 9820489B2 · Lohrmann et al. · 2017 [cited by applicant]
US 9861101B2 · Kraus · 2018 [cited by examiner]
US 9883672B2 · Kraus · 2018 [cited by examiner]
US 10010075B2 · Herdt et al. · 2018 [cited by applicant]
US 10172351B2 · Kraus et al. · 2019 [cited by applicant]
US 10201156B2 · Kraus · 2019 [cited by examiner]
US 10433547B2 · Li et al. · 2019 [cited by applicant]
US 10542751B2 · Li · 2020 [cited by examiner]
US 10555523B2 · McSherry · 2020 [cited by examiner]
US 10590282B2 · Balasubramanian · 2020 [cited by examiner]
US 10709131B2 · Li · 2020 [cited by examiner]
US 10834924B2 · Li · 2020 [cited by examiner]
US 11040902B2 · Balasubramanian · 2021 [cited by examiner]
US 11260040B2 · Li · 2022 [cited by examiner]
US 11684067B2 · Li · 2023 [cited by examiner]
US 11771673B2 · Li · 2023 [cited by examiner]
US 20020016278A1 · Barbeau et al. · 2002 [cited by applicant]
US 20020128312A1 · Hei et al. · 2002 [cited by applicant]
US 20020161258A1 · Miracle et al. · 2002 [cited by applicant]
US 20030047087A1 · Phebus et al. · 2003 [cited by applicant]
US 20030100469A1 · Connor et al. · 2003 [cited by applicant]
US 20030180247A1 · Morelli et al. · 2003 [cited by applicant]
US 20040035537A1 · Delmas et al. · 2004 [cited by applicant]
US 20040091448A1 · Kross · 2004 [cited by applicant]
US 20040097410A1 · Zheng et al. · 2004 [cited by applicant]
US 20040143133A1 · Smith et al. · 2004 [cited by applicant]
US 20050008526A1 · Bianchetti et al. · 2005 [cited by applicant]
US 20050109981A1 · Tucker et al. · 2005 [cited by applicant]
US 20050118940A1 · Hilgren et al. · 2005 [cited by applicant]
US 20060177518A1 · Stevenson et al. · 2006 [cited by applicant]
US 20070082832A1 · DiCosimo et al. · 2007 [cited by applicant]
US 20070093407A1 · Bianchetti et al. · 2007 [cited by applicant]
US 20070100204A1 · Feld et al. · 2007 [cited by applicant]
US 20070184999A1 · DiCosimo et al. · 2007 [cited by applicant]
US 20070249712A1 · Dee et al. · 2007 [cited by applicant]
US 20070274857A1 · Okano et al. · 2007 [cited by applicant]
US 20080029130A1 · Concar et al. · 2008 [cited by applicant]
US 20080176299A1 · Dicosimo et al. · 2008 [cited by applicant]
US 20080176784A1 · Clowes et al. · 2008 [cited by applicant]
US 20080275132A1 · McSherry · 2008 [cited by examiner]
US 20090018049A1 · Stolte et al. · 2009 [cited by applicant]
US 20090221704A1 · Aksela et al. · 2009 [cited by applicant]
US 20090285871A1 · Cunningham · 2009 [cited by examiner]
US 20090312279A1 · Mookerjee et al. · 2009 [cited by applicant]
US 20100048448A1 · DiCosimo et al. · 2010 [cited by applicant]
US 20100084603A1 · Narayan et al. · 2010 [cited by applicant]
US 20100119669A1 · Ben Yehuda et al. · 2010 [cited by applicant]
US 20100159028A1 · Shultz · 2010 [cited by applicant]
US 20100189707A1 · Barnett · 2010 [cited by applicant]
US 20100286017A1 · Righetto · 2010 [cited by applicant]
US 20110081693A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110136907A1 · Dicosimo et al. · 2011 [cited by applicant]
US 20110136908A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110152368A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110152369A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110152370A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110168567A1 · Smith et al. · 2011 [cited by applicant]
US 20110169270A1 · Todorof · 2011 [cited by applicant]
US 20110171062A1 · Wolfe · 2011 [cited by applicant]
US 20110173897A1 · Schneider · 2011 [cited by applicant]
US 20110177145A1 · Erkenbrecher, Jr. et al. · 2011 [cited by applicant]
US 20110177148A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110236335A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110236336A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110236337A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110236338A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110236339A1 · DiCosimo et al. · 2011 [cited by applicant]
US 20110300201A1 · Becker et al. · 2011 [cited by applicant]
US 20120021486A1 · Dinu et al. · 2012 [cited by applicant]
US 20120036649A1 · Auterinen et al. · 2012 [cited by applicant]
US 20120136588A1 · Kubach · 2012 [cited by applicant]
US 20120156155A1 · DiCosimo et al. · 2012 [cited by applicant]
US 20120156156A1 · DiCosimo et al. · 2012 [cited by applicant]
US 20120156157A1 · DiCosimo et al. · 2012 [cited by applicant]
US 20120156158A1 · DiCosimo et al. · 2012 [cited by applicant]
US 20120156159A1 · DiCosimo et al. · 2012 [cited by applicant]
US 20120164236A1 · Iwasa et al. · 2012 [cited by applicant]
US 20120171155A1 · Cunningham et al. · 2012 [cited by applicant]
US 20120172441A1 · Li · 2012 [cited by examiner]
US 20120322872A1 · Kraus · 2012 [cited by examiner]
US 20130111674A1 · Yoon · 2013 [cited by applicant]
US 20130158117A1 · DiCosimo et al. · 2013 [cited by applicant]
US 20130171217A1 · Chisholm et al. · 2013 [cited by applicant]
US 20130203849A1 · Ben Yehuda · 2013 [cited by applicant]
US 20130247308A1 · Duerrschmidt et al. · 2013 [cited by applicant]
US 20130261182A1 · Payne et al. · 2013 [cited by applicant]
US 20130289113A1 · Payne et al. · 2013 [cited by applicant]
US 20130289114A1 · Payne et al. · 2013 [cited by applicant]
US 20130289115A1 · Payne et al. · 2013 [cited by applicant]
US 20130303844A1 · Grudo et al. · 2013 [cited by applicant]
US 20140113966A1 · DiCosimo et al. · 2014 [cited by applicant]
US 20140120179A1 · Smith et al. · 2014 [cited by applicant]
US 20140121272A1 · Smith et al. · 2014 [cited by applicant]
US 20140127318A1 · Larose · 2014 [cited by applicant]
US 20140314829A1 · Boyd et al. · 2014 [cited by applicant]
US 20140338688A1 · Boyd et al. · 2014 [cited by applicant]
US 20150018319A1 · Larson et al. · 2015 [cited by applicant]
US 20150118167A1 · Boyd et al. · 2015 [cited by applicant]
US 20150182586A1 · Baldridge et al. · 2015 [cited by applicant]
US 20150265511A1 · Boyd et al. · 2015 [cited by applicant]
US 20160058005A1 · Hazenkamp et al. · 2016 [cited by applicant]
US 20160074549A1 · Lei et al. · 2016 [cited by applicant]
US 20160176815A1 · Li et al. · 2016 [cited by applicant]
US 20160205946A1 · Stauffer et al. · 2016 [cited by applicant]
US 20170020130A1 · Buschmann et al. · 2017 [cited by applicant]
US 20170064949A1 · Kraus et al. · 2017 [cited by applicant]
US 20170071200A1 · McSherry et al. · 2017 [cited by applicant]
US 20170081617A1 · Allesen-Holm · 2017 [cited by applicant]
US 20170081618A1 · Gohl et al. · 2017 [cited by applicant]
US 20170118989A1 · Oppong et al. · 2017 [cited by applicant]
US 20170156321A1 · Li et al. · 2017 [cited by applicant]
US 20170354116A1 · Gradle et al. · 2017 [cited by applicant]
US 20180177189A1 · Kleine et al. · 2018 [cited by applicant]
US 20180242578A1 · Li et al. · 2018 [cited by applicant]
CA 2266523A1 · 1999 [cited by applicant]
CA 2475361A1 · 2003 [cited by applicant]
CN 100581361C · 2010 [cited by applicant]
DE 3504394A1 · 1985 [cited by applicant]
DE 102015209819A1 · 2016 [cited by applicant]
EP 0125781A1 · 1984 [cited by applicant]
EP 0231632A2 · 1987 [cited by applicant]
EP 0233731A2 · 1987 [cited by applicant]
EP 0267047A2 · 1988 [cited by applicant]
EP 0751933B1 · 1997 [cited by applicant]
EP 0863098B1 · 1998 [cited by applicant]
EP 1022946B1 · 1998 [cited by applicant]
EP 1125497A2 · 2003 [cited by applicant]
EP 1618786A1 · 2004 [cited by applicant]
EP 1114137B1 · 2004 [cited by applicant]
EP 1131016B1 · 2005 [cited by applicant]
EP 1129171B1 · 2005 [cited by applicant]
EP 2064385B1 · 2007 [cited by applicant]
EP 1926808B1 · 2011 [cited by applicant]
EP 2470666B1 · 2014 [cited by applicant]
EP 2471941B1 · 2015 [cited by applicant]
EP 2714877B1 · 2017 [cited by applicant]
EP 2566943B1 · 2017 [cited by applicant]
EP 3169844B1 · 2018 [cited by applicant]
JP 62155203A · 1987 [cited by applicant]
JP 5186989A · 1993 [cited by applicant]
JP 6305920A · 1994 [cited by applicant]
JP 9510232A · 1997 [cited by applicant]
JP 2008100161A · 2008 [cited by applicant]
WO 9115474A1 · 1991 [cited by applicant]
WO 9403395A1 · 1994 [cited by applicant]
WO 9420424A1 · 1994 [cited by applicant]
WO 9424869A1 · 1994 [cited by applicant]
WO 9504128A1 · 1995 [cited by applicant]
WO 9524388A1 · 1995 [cited by applicant]
WO 9532625A1 · 1995 [cited by applicant]
WO 9533816A1 · 1995 [cited by applicant]
WO 9614384A1 · 1996 [cited by applicant]
WO 9616148A1 · 1996 [cited by applicant]
WO 9623858A1 · 1996 [cited by applicant]
WO 9719594A1 · 1997 [cited by applicant]
WO 9803513A1 · 1998 [cited by applicant]
WO 9804659A3 · 1998 [cited by applicant]
WO 9856988A1 · 1998 [cited by applicant]
WO 1999031215A1 · 1999 [cited by applicant]
WO 0018228A1 · 2000 [cited by applicant]
WO 0018521A1 · 2000 [cited by applicant]
WO 0045639A1 · 2000 [cited by applicant]
WO 0170030A2 · 2001 [cited by applicant]
WO 03092919A1 · 2003 [cited by applicant]
WO 2007031596A2 · 2007 [cited by applicant]
WO 2008088873A1 · 2008 [cited by applicant]
WO 2009117581A2 · 2009 [cited by applicant]
WO 2010050634A1 · 2010 [cited by applicant]
WO 2011073115A1 · 2011 [cited by applicant]
WO 2011089313A2 · 2011 [cited by applicant]
WO 2011090980A1 · 2011 [cited by applicant]
WO 2012037294A2 · 2012 [cited by applicant]
WO 2012084426A1 · 2012 [cited by applicant]
WO 2012090124A2 · 2012 [cited by applicant]
WO 2013052431A1 · 2013 [cited by applicant]
WO 2013148187A1 · 2013 [cited by applicant]
WO 2013184605A1 · 2013 [cited by applicant]
WO 2015118357A2 · 2015 [cited by applicant]
WO 2015181287A1 · 2015 [cited by applicant]
WO 2016100694A1 · 2016 [cited by applicant]
WO 2016100700A1 · 2016 [cited by applicant]
WO 2016135351A1 · 2016 [cited by applicant]
WO 2016162067A1 · 2016 [cited by applicant]
WO 2017007416A1 · 2017 [cited by applicant]
WO 2017044806A1 · 2017 [cited by applicant]
WO 2018175305A1 · 2018 [cited by applicant]
WO 2018208210A1 · 2018 [cited by applicant]
Israel Patent Office, “Written Opinion of the International Searching Authority”, issued in connection to International Application No. PCT/US2015/066427, filed Dec. 17, 2015, 8 pages, mailed Apr. 19, 2016. [cited by applicant]
International Searching Authority, PCT/IB2011/055830 filed Dec. 20, 2011, “The International Search Report and The Written Opinion of the International Searching Authority, of the Declaration”, 8 pages, mailed Aug. 24, … [cited by applicant]
Ecolab USA Inc., PCT/IB2011/055832 filed Dec. 20, 2011, “The International Search Report and The Written Opinion of the International Searching Authority, or the Declaration” 14 pages, mailed Aug. 14, 2012. [cited by applicant]
Carboni-Oerlemans, et al., “Hydrolase-Catalysed Synthesis of Peroxycarboxylic Acids: Biocatalytic Promiscuity for Practical Applications”, ScienceDirect, Journal of Biotechnology 126, pp. 140-151. Apr. 7, 2006. [cited by applicant]
Dannacher, Josef J., “Catalytic Bleach: Most Valuable Applications for Smart Oxidation Chemistry”, Journal of Molecular Catalysis A: Chemical 251, pp. 159-176. Mar. 20, 2006. [cited by applicant]
Effkemann et al., “Peroxide Analysis in Laundry Detergents Using Liquid Chromatography”, Analytica Chimica Acta 363, pp. 97-103. Jan. 2, 1998. [cited by applicant]
Leveneur, et al., “Synthesis of Peroxypropionic Acid From Propionic Acid and Hydrogen Peroxide over Hetrogeneous Catalysts”, Chemical Engineering Journal 147, pp. 323-329. Dec. 31, 2009. [cited by applicant]
Maeda, et al., “Assessment of Acyl Groups and Reaction Conditions in the Competition between Perhydrolysis and Hydrolysis of Acyl Resorufins for Developing an Indicator Reaction for Fluorometric Analysis of Hydrogen Per… [cited by applicant]
Muurinen, et al., “Organosolv Pulping: A review and distillation study related to peroxyacid pulping”, Department of Process Engineering, University of Oulu, 75 pages. May 16, 2000. [cited by applicant]
Ogata, et al., “The Formation of Peracids by the Perhydrolysis with Alkaline Hydrogen Peroxide”, Tetrochem, vol. 23, pp. 3327-3332. Dec. 31, 1967. [cited by applicant]
Rusch, et al., “Biocatalytic Peroxy Acid Formation for Disinfection”, Journal of Molecular Catalysis B: Enzymatic 19-20, pp. 499-505. May 16, 2002. [cited by applicant]
Rusch, et al., “Lipase-Catalyzed Conversions of Trimethylsilyl Ethers: Deprotection, Acetylation, Epoxidation and One-Pot-Multi-Step Reactions”, Journal of Molecular Catalysis B: Enzymatic 7, pp. 283-289. Feb. 26, 1999. [cited by applicant]
Rusch, et al., “Lipase-Catalyzed Preparation of Peroxy Acids and their use for Epoxidation”, Journal of Molecular Catalysis A: Chemical 117, pp. 311-319. Dec. 31, 1997. [cited by applicant]
Tsunokawa et al., “A Versatile Method for Preparation of O-Alkylperoxycarbonic Acids: Epoxidation with Alkyloxycarbonylimidazoles and Hydrogen Peroxide”, Tetrahedron Letters, vol. 23, No. 20, pp. 2113-2116. Dec. 31, 198… [cited by applicant]
Yin, et al., “Switching Catalysis From Hydrolysis to Perhydrolysis in Pseudomonas Fluorescnes Esterase”, Biochemistry, 49, pp. 1931-1942. Dec. 31, 2010. [cited by applicant]
Ullman's, et al., “Peroxy Compounds, Organic”, Ullmannn's Encyclopedia of Industrial Chemistry, pp. 325-354. Feb. 1, 2018. [cited by applicant]
Tao, Weiyi et al., “Efficient Production of Peracetic Acid in Aqueous Solution with Cephalosporin-Deacetylating Acetyl Kylan Esterase from Bacillus Subtilis”, Process Biochemistry, 50, pp. 2121-2127 available online Oct… [cited by applicant]
Yin (Tyler) DeLu et al., “New Structural Motif for Carboxylic Acid Perhydrolases”, Chemistry, vol. 19(9), pp. 3037-3046, manuscript available Feb. 25, 2014. [cited by applicant]
Jakob, “Peroxo Compounds, Inorganic”, Ullmannn's Encyclopedia of Industrial Chemistry, pp. 293-324, 2007. [cited by applicant]
Hilal, S.H., “Estimation of Hydrolysis Rate Constants of Carboxylic Acid Ester and Phosphate Ester Compounds in Aqueous Systems from Molecular Structure by SPARC”, EPA Research and Development, 55 pages, Sep. 2006. [cited by applicant]
Safety Data Sheet, “Glyceryl triacetate”, Santa Cruz Biotechnology, Inc., 6 pages, Nov. 6, 2018. [cited by applicant]
Safety Data Sheet, “Glycerol Triformate, Technical Grade” Santa Cruz Biotechnology, Inc., 5 pages, Jul. 24, 2017. [cited by applicant]
Humphreys et al., “Rate Measurements on Fast Reactions in the Stirred Flow Reactor; the Alkaline Hydrolysis of Methyl and Ethyl Formate”, Contribution from the Dept of Chemistry, Columbia University, 4 pages, Aug. 29, 1… [cited by applicant]
Sunburg and Panten, “2 Individual Fragrance and Flavor Materials”, Common Fragrance and Flavor Materials, 5th Ed, p. 7-175, 2006. [cited by applicant]
Shekhar, “Facile N-Formylation of amines using Lewis acids as novel catalysts”, Tetrahedron Letters, 50, p. 7099-7101, 2009. [cited by applicant]
Sugar alcohol: https://en.wikipedia.org/wiki/Sugar_alcohol, downloaded Jun. 22, 2021. [cited by applicant]
The Merck Veterinary Manual, Eleventh Edition, Merck & Co., Inc., Kenilworth, New Jersey, pp. 1358-1368, 2016. [cited by applicant]
Ansel et al., “Pharmaceutical Dosage Forms and Drug Delivery Systems”, Lippincott Williams & Wilkins, Ch. 3, pp. 95-100, 1999. [cited by applicant]