IP Library Granted Patent US 12,464,751
Granted Patent B2
US 12,464,751 · App. 18/504,745 · Granted Nov 4, 2025

Contact plugs and methods forming same

Inventors: Kuo-Hua Pan (Hsinchu, TW); Je-Wei Hsu (Hsinchu, TW); Hua Feng Chen (Hsinchu, TW); Jyun-Ming Lin (Hsinchu, TW); Chen-Huang Peng (Hsinchu, TW); Min-Yann Hsieh (Kaohsiung, TW); Java Wu (Hsinchu, TW)
Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
H10D30/0212H01L21/31144H01L21/76831H01L23/485H10D30/024H10D30/6211H10D30/6219H10D62/151H10D64/017H10D64/021H10D64/62H01L21/28518
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Quick Facts
Patent No.
US 12,464,751
App. No.
18/504,745
Granted
Nov 4, 2025
Kind
B2
Abstract

A method includes forming a transistor, which includes forming a dummy gate stack over a semiconductor region, and forming an Inter-Layer Dielectric (ILD). The dummy gate stack is in the ILD, and the ILD covers a source/drain region in the semiconductor region. The method further includes removing the dummy gate stack to form a trench in the first ILD, forming a low-k gate spacer in the trench, forming a replacement gate dielectric extending into the trench, forming a metal layer to fill the trench, and performing a planarization to remove excess portions of the replacement gate dielectric and the metal layer to form a gate dielectric and a metal gate, respectively. A source region and a drain region are then formed on opposite sides of the metal gate.

Claims (46)

1 . A device comprising:

a substrate;

two conductive features positioned apart from each other over the substrate;

a graded porous dielectric structure positioned between the two conductive features, wherein the graded porous dielectric structure comprises:

a first portion having a first porosity; and

a second portion having a second porosity, wherein the second porosity is higher than the first porosity; and

a dielectric layer positioned between one of the two conductive features and the graded porous dielectric structure, wherein the dielectric layer comprises a gate spacer, and the gate spacer comprises:

an L-shaped layer comprising a horizontal leg and a vertical leg connecting to the horizontal leg, wherein the vertical leg contacts the graded porous dielectric structure; and

an outer spacer overlapping the horizontal leg, wherein the outer spacer contacts the vertical leg to form a vertical interface.

2 . The device of claim 1 , wherein the one of the two conductive features comprises a contact plug.

3 . The device of claim 1 , wherein the two conductive features comprise a gate structure.

4 . The device of claim 3 , wherein the two conductive features further comprise a source/drain region.

5 . The device of claim 4 , wherein the first portion of the graded porous dielectric structure is positioned between the second portion and the gate structure.

6 . The device of claim 4 , wherein the second portion of the graded porous dielectric structure is positioned between the first portion and the gate structure.

7 . The device of claim 1 , wherein the graded porous dielectric structure comprises silicon, carbon, and nitrogen.

8 . The device of claim 1 , wherein the one of the two conductive features comprises a gate structure, and the device further comprises a fin positioned between the gate structure and the substrate.

9 . The device of claim 8 further comprising:

a dielectric hard mask over the gate structure, wherein the dielectric hard mask is formed of a same dielectric material as the graded porous dielectric structure, with the graded porous dielectric structure being more porous than the dielectric hard mask; and

an inter-layer dielectric over the dielectric hard mask.

10 . The device of claim 8 further comprising:

a source/drain region adjacent to the gate structure;

a source/drain contact plug over and electrically coupling to the source/drain region;

a high-k dielectric contact spacer encircling the source/drain contact plug; and

a source/drain silicide region between the source/drain region and the source/drain contact plug, wherein the high-k dielectric contact spacer extends lower than a top surface of the source/drain silicide region.

11 . The device of claim 10 , wherein the high-k dielectric contact spacer has a first edge contacting a second edge of the source/drain silicide region.

12 . A device comprising:

a semiconductor fin;

a gate stack on the semiconductor fin, wherein the gate stack comprises:

a gate electrode;

a gate dielectric comprising a bottom portion overlapped by the gate electrode, and sidewall portions contacting sidewalls of the gate electrode;

a graded porous dielectric spacer on a first sidewall of the gate stack, wherein the graded porous dielectric spacer physically contacts the semiconductor fin, and wherein the graded porous dielectric spacer comprises:

a first layer having a first porosity; and

a second layer on a second sidewall of the first layer, the second layer having a second porosity greater than the first porosity; and

a source/drain region on a side of the gate stack, wherein the graded porous dielectric spacer is laterally between the gate stack and the source/drain region.

13 . The device of claim 12 , wherein both of the first layer and the second layer comprise silicon oxynitride.

14 . The device of claim 13 , wherein both of the first layer and the second layer comprise silicon oxy carbo-nitride.

15 . The device of claim 12 , wherein the second layer that has greater porosity than the first layer is spaced apart from the gate electrode by the first layer.

16 . The device of claim 12 , wherein the sidewall portions of the gate dielectric form vertical interfaces with the gate electrode.

17 . The device of claim 12 , wherein both of the first layer and the second layer of the graded porous dielectric spacer are in physical contact with the semiconductor fin.

18 . A device comprising:

a semiconductor region;

a gate stack on the semiconductor region;

a source/drain region adjacent to the gate stack and extending into the semiconductor region; and

a gate spacer on a sidewall of the gate stack, wherein the gate spacer comprises a first portion and a second portion formed of low-k dielectric materials, and wherein the first portion and the second portion are formed of a same dielectric material, and have different porosity values.

19 . The device of claim 18 , wherein the same dielectric material comprises SiON.

20 . The device of claim 18 , wherein the first portion and the second portion have a vertical interface in between.

Continuity (5)
Continuation 17181607 · Feb 22, 2021
Continuation 16206071 · Nov 30, 2018
Division 15610981 · Jun 1, 2017
Provisional Application 62443885 · Jan 9, 2017
Related Publication 20240072155A1 · Feb 29, 2024
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