IP Library Granted Patent US 12,492,445
Granted Patent B2
US 12,492,445 · App. 18/480,354 · Granted Dec 9, 2025

Systems and methods for subsurface metal recovery

Inventors: Casey J. Clayton (Ariquipa, PE); Richard Melecio Sanchez (Central, AZ); Raquel Crossman (Mesa, AZ); Luciano Kiniti Issoe (Sao Paulo, BR); Tianfang Ni (Boston, MA); Oleksandr Klesov (Lexington, MA); Luke Gerdes (Framingham, MA); Muneeb Alam (Alexandria, VA); Joanna M Robertson (Thatcher, AZ); Chase Zenner (Tucson, AZ); John Warren Dean, Jr. (Thatcher, AZ)
Assignee: FREEPORT MINERALS CORPORATION
C22B7/007C22B3/04C22B15/0065G01F1/363G01F1/42G01F15/003G01F15/005G01F15/066G05D16/20G08B21/182C22B3/02C22B3/22C22B3/44E21B43/28E21C2100/00G01F1/34G01F1/74G01F15/006G05D16/101G05D16/2024Y02P10/20Y10T137/86574
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Quick Facts
Patent No.
US 12,492,445
App. No.
18/480,354
Granted
Dec 9, 2025
Kind
B2
Abstract

The present disclosure provides a method comprising determining an ore map for a heap to identify a location of a recoverable metal value in the heap, delivering a leaching solution from a leaching solution source to a leaching solution regulating system, regulating at least one of a pressure, a mass flow rate, or a volumetric flow rate of the leaching solution to achieve a first target operational condition, wherein the first target operational condition is selected to optimize a set of operational parameters to maximize recovery of the recoverable metal value, delivering the leaching solution at the first target operational condition from the leaching solution regulating system to a subsurface leaching distribution system, and delivering the leaching solution at the first target operational condition from the subsurface leaching distribution system to the location of the recoverable metal value under a surface of the heap to leach and recover at least one metal value.

Claims (26)

1 . A method, comprising:

regulating a pressure, a mass flow rate, and a volumetric flow rate of a leaching solution to achieve a first target operational condition, wherein the first target operational condition is selected to optimize a set of operational parameters for preventing plugging of a subsurface leaching distribution system, minimizing locking up of the leaching solution in the heap and maximizing recovery of a recoverable metal;

delivering the leaching solution at the first target operational condition from the leaching solution regulating system to a subsurface leaching distribution system; and

delivering the leaching solution at the first target operational condition from the subsurface leaching distribution system to a location of the recoverable metal under a surface of a heap to leach and to recover the recoverable metal.

2 . The method of claim 1 , wherein the leaching solution regulating system comprises a plurality of leaching solution regulating modules.

3 . The method of claim 2 , wherein each leaching solution regulating module comprises a meter configured to detect the pressure, the mass flow rate and the volumetric flow rate of the leaching solution.

4 . The method of claim 2 , wherein each leaching solution regulating module comprises a regulator configured to set the pressure, the mass flow rate and the volumetric flow rate of the leaching solution to the first target operational condition.

5 . The method of claim 4 , wherein the regulator comprises a 3-way valve comprising a vent configured to prevent a pressure drop of the leaching solution.

6 . The method of claim 1 , wherein the set of operational parameters comprises at least one of minerology, chemistry, permeability or remaining recoverable metals.

7 . The method of claim 1 , further comprising transmitting the pressure, the mass flow rate and the volumetric flow rate of the leaching solution between the leaching solution regulating system and the subsurface leaching distribution system.

8 . The method of claim 1 , further comprising determining x,y,z coordinates for the location of the recoverable metal in the heap.

9 . The method of claim 1 , further comprising regulating at least one of the pressure, the mass flow rate, or the volumetric flow rate of the leaching solution to achieve a second target operational condition, wherein the second target operational condition is selected to maximize recovery of the recoverable metal in accordance with variations in at least one of physical characteristics and chemical characteristics of the location, in response to evaluating leach cycle data.

10 . A system, comprising:

a recoverable metal in a heap;

a leaching solution regulating system configured to detect and regulate a pressure, a mass flow rate and a volumetric flow rate of a leaching solution to a target operational condition, wherein the target operational condition is selected to optimize a set of operational parameters for preventing plugging of a subsurface leaching distribution system, minimizing locking up of the leaching solution in the heap and maximizing recovery of the recoverable metal; and

a subsurface leaching solution distribution system fluidly coupled to the leaching solution regulating system, the subsurface leaching solution distribution system comprising a subsurface injector configured to deliver leaching solution to the recoverable metal under the surface of the heap to leach and recover the recoverable metal.

11 . The system of claim 10 , wherein the set of operational parameters comprises at least one of minerology, chemistry, permeability or remaining recoverable metals.

12 . The system of claim 10 , wherein the subsurface injector comprises a metal or thermoplastic material.

13 . The system of claim 10 , wherein the subsurface leaching solution distribution system comprises a first subsurface injector and a second subsurface injector, the first subsurface injector extending into the heap a greater distance than the second subsurface injector.

14 . The system of claim 10 , wherein the subsurface injector comprises a slotted portion comprising at least one slot configured to deliver the leaching solution to the heap.

15 . The system of claim 10 , wherein the subsurface injector is fluidly coupled to a primary pipe and a secondary pipe, the primary pipe fluidly coupled to the subsurface leaching solution distribution system.

16 . The system of claim 10 , wherein the subsurface injector is inserted into a bore formed in the heap, the bore filled with at least one material configured to provide stability and sealing for the subsurface injector.

17 . The system of claim 10 , further comprising a plurality of sensors distributed along a length of the subsurface injector, wherein the plurality of sensors are configured to monitor a flow condition of the leaching solution from the subsurface injector.

18 . The system of claim 10 , wherein the leaching solution regulating system transmits the pressure, the mass flow rate and the volumetric flow rate of the leaching solution between the leaching solution regulating system and the subsurface leaching distribution system.

19 . The system of claim 10 , further comprising an ore map determined by adding flow data, irrigation data and a remaining mineral prediction from a machine learning model to obtain information by section and by data for the heap.

20 . The system of claim 10 , wherein a location of the recoverable metal in the heap is in x,y,z coordinates of the heap.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2024
From: CLAYTON, CASEY J.; SANCHEZ, RICHARD MELECIO; CROSSMAN, RAQUEL; ISSOE, LUCIANO KINITI; NI, TIANFANG; KLESOV, OLEKSANDR; GERDES, LUKE; ALAM, MUNEEB; ROBERTSON, JOANNA M.; ZENNER, CHASE; DEAN, JOHN WARREN, JR.
To: FREEPORT MINERALS CORPORATION
Reel/Frame 067566/0197 →
Continuity (8)
Continuation In Part 18124333 · Mar 21, 2023
Continuation 17733171 · Apr 29, 2022
Continuation 17223404 · Apr 6, 2021
Continuation 16223760 · Dec 18, 2018
Continuation 15989614 · May 25, 2018
Continuation 15539328
Provisional Application 62097458 · Dec 29, 2014
Related Publication 20240026492A1 · Jan 25, 2024
References Cited (76)
US 3587620A · Berthold · 1971 [cited by applicant]
US 3993293A · Mukae et al. · 1976 [cited by applicant]
US 4045084A · Hsueh et al. · 1977 [cited by applicant]
US 4168295A · Sawyer · 1979 [cited by applicant]
US 4175789A · Kube et al. · 1979 [cited by applicant]
US 4180088A · Mallett · 1979 [cited by applicant]
US 4369100A · Sawyer · 1983 [cited by applicant]
US 4739973A · Herndon · 1988 [cited by applicant]
US 4807854A · Mitchell · 1989 [cited by applicant]
US 4974816A · Emmett, Jr. et al. · 1990 [cited by applicant]
US 5313982A · Ohmi et al. · 1994 [cited by applicant]
US 5329463A · Sierk et al. · 1994 [cited by applicant]
US 5598838A · Servidio et al. · 1997 [cited by applicant]
US 6030048A · Hsu · 2000 [cited by applicant]
US 6498031B1 · Carter · 2002 [cited by applicant]
US 9181603B2 · Boudreault et al. · 2015 [cited by applicant]
US 9945009B2 · Boudreault et al. · 2018 [cited by applicant]
US 9982321B2 · Dean, Jr. et al. · 2018 [cited by applicant]
US 10190190B2 · Dean, Jr. et al. · 2019 [cited by applicant]
US 10975455B2 · Dean, Jr. et al. · 2021 [cited by applicant]
US 11332808B2 · Dean, Jr. et al. · 2022 [cited by applicant]
US 11521138B1 · Geislinger · 2022 [cited by examiner]
US 11639539B2 · Dean, Jr. et al. · 2023 [cited by applicant]
US 20020179451A1 · Weldon et al. · 2002 [cited by applicant]
US 20040113333A1 · Podznoev et al. · 2004 [cited by applicant]
US 20040173057A1 · Fairbourn · 2004 [cited by examiner]
US 20050016593A1 · Ephrat et al. · 2005 [cited by applicant]
US 20060054214A1 · Caamano et al. · 2006 [cited by applicant]
US 20080102514A1 · Coallao Olivares et al. · 2008 [cited by applicant]
US 20080210017A1 · Igarashi et al. · 2008 [cited by applicant]
US 20080286180A1 · Jones · 2008 [cited by applicant]
US 20090087892A1 · Champion · 2009 [cited by examiner]
US 20090230207A1 · Guzman · 2009 [cited by examiner]
US 20090293679A1 · Singh et al. · 2009 [cited by applicant]
US 20110178644A1 · Picton · 2011 [cited by applicant]
US 20110286542A1 · Shelburne · 2011 [cited by applicant]
US 20110303051A1 · Gonzalez et al. · 2011 [cited by applicant]
US 20120161374A1 · Nakai et al. · 2012 [cited by applicant]
US 20120297928A1 · Lang et al. · 2012 [cited by applicant]
US 20130008856A1 · Megaw · 2013 [cited by applicant]
US 20130032737A1 · Neilson et al. · 2013 [cited by applicant]
US 20140369904A1 · Boudreault et al. · 2014 [cited by applicant]
US 20140369907A1 · Boudreault et al. · 2014 [cited by applicant]
US 20150225808A1 · Boudreault et al. · 2015 [cited by applicant]
US 20170356065A1 · Dean, Jr. · 2017 [cited by examiner]
US 20180274057A1 · Dean, Jr. et al. · 2018 [cited by applicant]
US 20190119781A1 · Dean, Jr. et al. · 2019 [cited by applicant]
US 20190356065A1 · Watkins et al. · 2019 [cited by applicant]
US 20200224290A1 · Oraby et al. · 2020 [cited by applicant]
US 20200340077A1 · Lizama · 2020 [cited by examiner]
US 20210238708A1 · Dean, Jr. et al. · 2021 [cited by applicant]
US 20220259695A1 · Dean, Jr. et al. · 2022 [cited by applicant]
US 20230227934A1 · Dean, Jr. et al. · 2023 [cited by applicant]
US 20240026493A1 · Lyons · 2024 [cited by examiner]
GB 1404243 · 1975 [cited by applicant]
International Search Report and Written Opinion dated Jan. 19, 2016 from corresponding International Application PCT/US2015/050015. [cited by applicant]
International Preliminary Report on Patentability dated Feb. 3, 2017 from corresponding International Application PCT/US2015/050015. [cited by applicant]
Notice of Allowance and Examiner's Amendment from U.S. Appl. No. 15/539,328 dated Jan. 30, 2018. [cited by applicant]
Supplemental Notice of Allowability from U.S. Appl. No. 15/539,328 dated Apr. 26, 2018. [cited by applicant]
Notice of Allowance and Examiner's Amendment from U.S. Appl. No. 15/989,614 dated Sep. 27, 2018. [cited by applicant]
Examination Report dated Dec. 10, 2018 from corresponding Chilean Patent Application No. 2017-01732 with machine translation of same in English. [cited by applicant]
Non-Final Office Action from U.S. Appl. No. 16/223,760 dated Jan. 16, 2020. [cited by applicant]
Non-Final Office Action from U.S. Appl. No. 16/223,760 dated Aug. 7, 2020. [cited by applicant]
Notice of Allowance and Examiner's Interview Summary from U.S. Appl. No. 16/223,760 dated Dec. 23, 2020. [cited by applicant]
Notice of Allowance and Examiner's Interview Summary from U.S. Appl. No. 17/223,404 dated Jan. 25, 2022. [cited by applicant]
Non-Final Office Action from U.S. Appl. No. 17/733,171 dated Nov. 9, 2022. [cited by applicant]
Notice of Allowance and Examiner's Interview Summary from U.S. Appl. No. 17/733,171 dated Dec. 21, 2022. [cited by applicant]
PCT Corrected International Preliminary Report on Patentability in PCT/US2024/049581 dated Mar. 20, 2025. [cited by applicant]
USPTO Non Final Office Action in U.S. Appl. No. 18/480,377 dated Mar. 10, 2025. [cited by applicant]
Response to Non Final Office Action in U.S. Appl. No. 18/480,377 dated Apr. 14, 2025. [cited by applicant]
PCT International Search Report and Written Opinion of the International Searching Authority in PCT/US2024/049548 dated Dec. 10, 2024. [cited by applicant]
PCT International Search Report and Written Opinion of the International Searching Authority in PCT/US2024/049581 dated Dec. 18, 2024. [cited by applicant]
Reply to Written Opinion, PCT Demand and Letter Accompanying Article 19 Amendments in PCT/US2024/049548 dated Dec. 23, 2024. [cited by applicant]
Reply to Written Opinion, PCT Demand and Letter Accompanying Article 19 Amendments in PCT/US2024/049581 dated Feb. 14, 2025. [cited by applicant]
PCT International Preliminary Report on Patentability in PCT/US2024/049548 dated Feb. 27, 2025. [cited by applicant]
IP Australia Examination Report No. 1 from Australian Application 2024220174 dated Oct. 15, 2025. [cited by applicant]