IP Library › Granted Patent US 12,600,862
Granted Patent B2
US 12,600,862 · App. 17/819,544 · Granted Apr 14, 2026

Protein polyurethane alloys and layered materials including the same

Inventors: Samuel Broadbent (Hazlet, NJ); Dale L. Handlin, Jr. (Clifton, NJ); Shaobo Cai (Oradell, NJ); Zhe Tan (Secaucus, NJ); Casey Crownhart (Hoboken, NJ); Nicholas Yaraghi (Hoboken, NJ); David Williamson (Towaco, NJ); Alexander Iain Norman (Somerville, NJ); Lixin Dai (Livingston, NJ)
Assignee: Modern Meadow, Inc.
C08L89/06C08L75/04C08L2201/10
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Quick Facts
Patent No.
US 12,600,862
App. No.
17/819,544
Granted
Apr 14, 2026
Kind
B2
Abstract

Protein polyurethane alloys including one or more proteins dissolved within one or more polyurethanes. The protein polyurethane alloy may have one or more mechanical properties that are superior to the polyurethane in the absence of protein. The protein polyurethane alloys may be incorporated into a layered material including one or more protein polyurethane alloy layers.

Claims (26)

1 . An aqueous protein polyurethane alloy formulation, comprising:

water;

a polyurethane;

a protein dissolved within at least the polyurethane; and

a foam stabilizer selected from the group consisting of: a nonionic surfactant, an anionic surfactant, a hydrophobically-modified ethylene oxide urethane, and a non-ionic silicone dispersion,

wherein the formulation comprises about 5 wt % to about 60 wt % of the protein and about 10 wt % to about 85 wt % of the polyurethane, based on the weight of protein and polyurethane.

2 . The aqueous protein polyurethane alloy formulation of claim 1 , wherein the foam stabilizer comprises a nonionic surfactant.

3 . The aqueous protein polyurethane alloy formulation of claim 1 , wherein the concentration of the protein in the formulation ranges from about 10 g/L to about 300 g/L.

4 . The aqueous protein polyurethane alloy formulation of claim 1 , comprising about 0.1 wt % to about 10 wt % of the foam stabilizer.

5 . The aqueous protein polyurethane alloy formulation of claim 1 , further comprising one or more colored dyes.

6 . The aqueous protein polyurethane alloy formulation of claim 5 , wherein the formulation comprises about 0.1 wt % to about 2 wt % of the one or more colored dyes.

7 . The aqueous protein polyurethane alloy formulation of claim 5 , wherein the one or more colored dyes are selected from the group consisting of: a fiber reactive dye and an acid dye.

8 . The aqueous protein polyurethane alloy formulation of claim 1 , further comprising a cross-linker selected from the group consisting of: an epoxy-based cross-linker, an isocyanate-based cross-linker, and a carbodiimide-based cross-linker.

9 . The aqueous protein polyurethane alloy formulation of claim 8 , wherein the cross-linker is a carbodiimide-based cross-linker.

10 . The aqueous protein polyurethane alloy formulation of claim 1 , wherein the formulation is a foamed formulation having a liquid density ranging from about 300 g/L to about 900 g/L.

11 . A method of making a material, the method comprising:

applying the aqueous protein polyurethane alloy formulation of claim 1 to a textile such that the protein polyurethane alloy formulation is integrated into the textile; and

drying the textile comprising the integrated protein polyurethane alloy formulation.

12 . The method of claim 11 , wherein the aqueous protein polyurethane alloy formulation is foamed before applying the formulation to the textile.

13 . The aqueous protein polyurethane alloy formulation of claim 1 , wherein the polyurethane is a waterborne polyurethane dispersion.

14 . An aqueous protein polyurethane alloy formulation, comprising:

water;

a polyurethane;

a protein dissolved within at least the polyurethane;

a foam stabilizer; and

a carbodiimide-based cross-linker.

Continuity (4)
Continuation 17246044 · Apr 30, 2021
Provisional Application 63110760 · Nov 6, 2020
Provisional Application 63018891 · May 1, 2020
Related Publication 20230033725A1 · Feb 2, 2023
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