Multilayer ceramic capacitor
A multilayer ceramic capacitor includes dielectric layers made of a ceramic material and inner electrode layers that are laminated. Each of the inner electrode layers includes a first metal as a main component, and dielectric coupling portions penetrating through in a lamination direction, filled with a portion of adjacent dielectric layers, and coupling the adjacent dielectric layers to each other. A solid-dissolved layer, in which a second metal different from the first metal is solid-dissolved, is provided at an interface between the dielectric coupling portions and the inner electrode layers. A content of the second metal in the solid-dissolved layer is about 0.1 mol % or more and about 10 mol % or less in 100 mol of the first metal.
1 . A multilayer ceramic capacitor comprising:
dielectric layers made of a ceramic material; and
inner electrode layers; wherein
the dielectric layers and the inner electrode layers are laminated;
the inner electrode layers include a first metal as a main component;
the inner electrode layers include dielectric coupling portions penetrating through in a lamination direction, filled with a portion of adjacent dielectric layers of the dielectric layers, and coupling the adjacent dielectric layers;
a dielectric coupling interface solid-dissolved layer, in which a second metal different from the first metal is solid-dissolved, is provided at an interface between the dielectric coupling portions and the inner electrode layers;
a dielectric layer interface solid-dissolved layer, in which a second metal different from the first metal is solid-dissolved, is provided at an interface between the dielectric layer and the inner electrode layer; and
a highest content of the second metal in the dielectric coupling interface solid-dissolved layer is larger than a highest content of the second metal in the dielectric layer interface solid-dissolved layer.
2 . The multilayer ceramic capacitor according to claim 1 , wherein a content of the second metal in the dielectric layer interface solid-dissolved layer is about 0.1 mol or more and about 10 mol or less in 100 mol of the first metal.
3 . The multilayer ceramic capacitor according to claim 1 , wherein one or more of the dielectric coupling portions is provided per about 100 μm in each of the inner electrode layers.
4 . The multilayer ceramic capacitor according to claim 1 , wherein the dielectric coupling interface solid-dissolved layer covers at least about 75% or more of a periphery of the dielectric coupling portion.
5 . The multilayer ceramic capacitor according to a claim 1 , wherein each of the inner electrode layers has a thickness of about 0.30 μm or more and about 0.40 μm or less; and
each of the dielectric layers has a thickness of about 0.40 μm or more and about 0.50 μm or less.
6 . The multilayer ceramic capacitor according to claim 1 , wherein
the dielectric layers include a dielectric grain; and
the second metal is solid-dissolved in an interface of the dielectric grain.
7 . The multilayer ceramic capacitor according to claim 1 , wherein the first metal is Ni.
8 . The multilayer ceramic capacitor according to claim 1 , wherein the second metal is at least one of Sn, In, Ga, Zn, Bi, Pb, Fe, V, Y, or Cu.
9 . The multilayer ceramic capacitor according to claim 1 , wherein the solid-dissolved layer has a thickness of about 1 nm or more and about 20 nm or less.
10 . The multilayer ceramic capacitor according to claim 1 , wherein each of the dielectric layers includes BaTiO 3 , CaTiO 3 , SrTiO 3 , or CaZrO 3 as a main component.
11 . The multilayer ceramic capacitor according to claim 10 , wherein each of the dielectric layers includes a Mn compound, an Fe compound, a Cr compound, a Co compound, or a Ni compound as a secondary component.
12 . The multilayer ceramic capacitor according to claim 1 , wherein each of the dielectric layers has a thickness of about 0.40 μm or more and about 0.45 μm or less.
13 . The multilayer ceramic capacitor according to claim 1 , wherein a number of the dielectric layers is 100 or more and 2000 or less.
14 . The multilayer ceramic capacitor according to claim 1 , wherein a thickness of each of the inner electrode layers is about 0.30 μm or more and about 0.40 μm or less.
15 . The multilayer ceramic capacitor according to claim 1 , wherein a thickness of each of the inner electrode layers is about 0.30 μm or more and about 0.35 μm or less.
16 . The multilayer ceramic capacitor according to claim 1 , wherein a number of the inner electrode layers is 10 or more and 1000 or less.
17 . The multilayer ceramic capacitor according to claim 1 , wherein
the dielectric layers and the inner electrode layers define a multilayer body; and
the multilayer body has a dimension in a length direction of about 0.05 mm or more and about 1.00 mm or less, a dimension in a width direction of about 0.10 mm or more and about 0.50 mm or less, and a dimension in a lamination direction of about 0.10 mm or more and about 0.50 mm or less.
18 . The multilayer ceramic capacitor according to claim 1 , wherein the dielectric layers and the inner electrode layers define a multilayer body; and
outer electrodes are provided on end surfaces of the multilayer body and coupled to the inner electrode layers.
19 . The multilayer ceramic capacitor according to claim 18 , wherein each of the outer electrodes includes an underlying electrode layer and a plating layer.
20 . The multilayer ceramic capacitor according to claim 19 , wherein the underlying electrode layer includes metal and glass.