IP Library Granted Patent US 12,637,753
Granted Patent B2
US 12,637,753 · App. 18/604,125 · Granted May 26, 2026

Method for producing transparent conductive coatings for emi protection using HiPIMS

Inventors: Ralph Korenstein (Natick, MA); Troy R. Taylor (Windham, NH)
Assignee: Raytheon Company
C23C14/0629C23C14/0084C23C14/14C23C14/3485C23C14/352H01J37/3426H01J37/3467C23C14/35
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Quick Facts
Patent No.
US 12,637,753
App. No.
18/604,125
Granted
May 26, 2026
Kind
B2
Abstract

A method for forming a coating on a substrate formed from zinc sulfide (ZnS) is provided. A ZnS film is grown on the substrate with a radio frequency sputtering process and metal dopants are sputtered on the substrate with a high-power impulse magnetron sputtering process. The metal dopants can be molybdenum or tungsten and simultaneously sputtered while growing the ZnS film. The sputtering ionizes the coating where the coating has a sheet resistance that is less than 50 ohm/square and the metal dopants form n-type dopants in the ZnS film. The metal dopants can be formed at a concentration that varies with a thickness of the ZnS film. At a first thickness, the concentration is at a first concentration and at a second thickness greater than the first thickness, the concentration is at a second concentration less than the first concentration.

Claims (17)

1 . A method for forming a coating on a substrate, the method comprising:

growing a zinc sulfide (ZnS) film on a surface of the substrate with a radio frequency (RF) sputtering process; and

sputtering metal dopants on the substrate at concentrations between 1×10 16 cm −3 and 1×10 20 cm −3 with a high-power impulse magnetron sputtering (HiPIMS) process, wherein:

the metal dopants are ionized and one of molybdenum or tungsten;

the metal dopants are simultaneously sputtered with a RF sputtering process while growing the ZnS film, wherein:

the RF sputtering process and HiPIMS process are simultaneously performed such that the ZnS film is grown on the substrate during the RF sputtering process; and

the HiPIMS process is performed such that the ionized metals dopants are interspersed in the ZnS film as the ZnS film is grown on the substrate;

the sputtering the metal dopants ionizes the coating on the substrate such that the coating has a sheet resistance that is less than 50 ohm/square and the metal dopants form n-type dopants in the ZnS film; and

the concentrations at which the metal dopants are sputtered varies with a thickness of the ZnS film such that at a first ZnS film thickness, there is a first concentration and at a second ZnS film thickness that is greater than the first ZnS film thickness, there is a second concentration that is less than the first concentration where the second ZnS film thickness is separate from the first ZnS film thickness, wherein:

the ZnS film is formed in a stepwise fashion to achieve the first and second film thicknesses with corresponding gradient concentrations of the metal dopants distributed throughout the coating; and

the greater thickness of the second ZnS film dilutes the metal dopants throughout the coating thereby allowing for a lower concentration of the metal dopants.

2 . The method of claim 1 , wherein the first concentration of metals of the metal dopants is in a range between 1×10 18 cm −3 and 1×10 20 cm −3 when the first ZnS film thickness is less than 1 micron.

3 . The method of claim 1 , wherein the second concentration of metals of the metal dopants is in a range between 1×10 16 cm −3 and 1×10 18 cm −3 when the second ZnS film thickness is greater than 1 micron.

4 . The method of claim 1 , wherein the coating is a transparent coating and is configured to allow detection of infrared signatures through the coating and the substrate.

5 . The method of claim 4 , wherein the coating and the substrate form a window for a vehicle having a detector that allows for the detection of optical signals and thermal signatures through the window and into an interior of the vehicle.

6 . The method of claim 1 , further comprising adding a p-type conductive coating on the coating of the substrate.

7 . The method of claim 6 , wherein the p-type conductive coating is barium copper sulfur fluoride.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 13, 2025
From: KORENSTEIN, RALPH; TAYLOR, TROY R.
To: RAYTHEON COMPANY
Reel/Frame 071409/0629 →
Continuity (1)
Related Publication 20250294715A1 · Sep 18, 2025
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